Metabolite_name	RefMet_name	Enzyme assay_Apple pear hybrid_HybASR1	Enzyme assay_Apple pear hybrid_HybASR2	Enzyme assay_Apple pear hybrid_HybASR3	Enzyme assay_Malus domestica_MdAS1R1	Enzyme assay_Malus domestica_MdAS1R2	Enzyme assay_Malus domestica_MdAS1R3	Enzyme assay_Malus domestica_MdAS2R1	Enzyme assay_Malus domestica_MdAS2R2	Enzyme assay_Malus domestica_MdAS2R3	Enzyme assay_Pyrus communis_PcASR1	Enzyme assay_Pyrus communis_PcASR2	Enzyme assay_Pyrus communis_PcASR3	Fruit_Apple pear hybrid_FR1	Fruit_Apple pear hybrid_FR2	Fruit_Apple pear hybrid_FR3	Fruit_Malus domestica_FR1	Fruit_Malus domestica_FR2	Fruit_Malus domestica_FR3	Fruit_Pyrus communis_FR1	Fruit_Pyrus communis_FR2	Fruit_Pyrus communis_FR3	Old Leaf_Apple pear hybrid_OLR1	Old Leaf_Apple pear hybrid_OLR2	Old Leaf_Apple pear hybrid_OLR3	Old Leaf_Malus domestica_OLR1	Old Leaf_Malus domestica_OLR2	Old Leaf_Malus domestica_OLR3	Old Leaf_Pyrus communis_OLR1	Old Leaf_Pyrus communis_OLR2	Old Leaf_Pyrus communis_OLR3	Young Leaf_Apple pear hybrid_YLR1	Young Leaf_Apple pear hybrid_YLR2	Young Leaf_Apple pear hybrid_YLR3	Young Leaf_Malus domestica_YLR1	Young Leaf_Malus domestica_YLR2	Young Leaf_Malus domestica_YLR3	Young Leaf_Pyrus communis_YLR1	Young Leaf_Pyrus communis_YLR2	Young Leaf_Pyrus communis_YLR3
Factors	-	Sample source:Enzyme assay | Genotype:Apple pear hybrid | Treatment:5ug	Sample source:Enzyme assay | Genotype:Apple pear hybrid | Treatment:5ug	Sample source:Enzyme assay | Genotype:Apple pear hybrid | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Malus domestica | Treatment:5ug	Sample source:Enzyme assay | Genotype:Pyrus communis | Treatment:5ug	Sample source:Enzyme assay | Genotype:Pyrus communis | Treatment:5ug	Sample source:Enzyme assay | Genotype:Pyrus communis | Treatment:5ug	Sample source:Fruit | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Fruit | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Fruit | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Fruit | Genotype:Malus domestica | Treatment:Control	Sample source:Fruit | Genotype:Malus domestica | Treatment:Control	Sample source:Fruit | Genotype:Malus domestica | Treatment:Control	Sample source:Fruit | Genotype:Pyrus communis | Treatment:Control	Sample source:Fruit | Genotype:Pyrus communis | Treatment:Control	Sample source:Fruit | Genotype:Pyrus communis | Treatment:Control	Sample source:Old Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Old Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Old Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Old Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Old Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Old Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Old Leaf | Genotype:Pyrus communis | Treatment:Control	Sample source:Old Leaf | Genotype:Pyrus communis | Treatment:Control	Sample source:Old Leaf | Genotype:Pyrus communis | Treatment:Control	Sample source:Young Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Young Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Young Leaf | Genotype:Apple pear hybrid | Treatment:Control	Sample source:Young Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Young Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Young Leaf | Genotype:Malus domestica | Treatment:Control	Sample source:Young Leaf | Genotype:Pyrus communis | Treatment:Control	Sample source:Young Leaf | Genotype:Pyrus communis | Treatment:Control	Sample source:Young Leaf | Genotype:Pyrus communis | Treatment:Control
Arbutin	Arbutin	7.5700	6.6700	8.3900	7.1300	7.0600	7.1900	0.1300	0.0700	0.4400	4.4700	5.2500	6.1100	0.1500	0.2100	0.1700				0.5300	0.5200	0.4600	28.9900	31.2100	30.7500	0.1300	0.1200	0.1900	129.5600	124.0200	108.7800	45.7800	48.3600	53.1400		0.1300	0.0600	145.5000	145.5000	150.2200
Catechin	Catechin													0.2900	0.3100	0.3000	0.0800	0.0500	0.0200	0.0700	0.0700	0.0700	7.7500	8.2000	8.0600	0.0400	0.0300		3.1500	2.9500	2.8100	7.3100	7.9800	8.4500	0.2200	0.1800	0.1500	4.8500	4.9600	4.9400
Chlorogenic acid	Chlorogenic acid													0.5500	0.6500	0.5800	0.3800	0.3400	0.3900	0.4400	0.4000	0.4300	35.2500	38.8500	40.5800	0.7200	0.6900	0.8000	52.6400	50.9300	45.8200	30.1500	32.6300	33.0700	0.1200	0.1400	0.1100	66.3600	66.2700	69.7600
Cryptochlorogenic acid	Cryptochlorogenic acid													0.0700	0.0100	0.0600	0.0200	0.0100	0.0100	0.0100	0.0100		0.3500	0.4200	0.4400	0.0600	0.0600	0.0300	1.6400	1.6500	1.7100	0.3200	0.3100	0.3400	0.0700	0.1200	0.1100	0.0700	0.0600	0.0700
Ellagic acid	Ellagic acid													0.0100	0.0100	0.0100				0.0100			0.2100		0.1700	0.1900	0.4300	0.3100		0.1800	0.0200	0.3300	0.2400	0.0500	0.4600	0.4300	0.3500	0.2400	0.2900	0.3100
Epicatechin	Epicatechin													0.8800	0.8000	0.8400	0.9000	0.8000	0.7900	0.2400	0.2500	0.2400	4.3200	4.8600	5.0900	1.9700	1.5800	1.7400	10.6300	11.1200	10.1200	1.4800	1.7000	2.4400	0.6300	0.6900	0.7400	6.1600	5.9500	6.1600
Epicatechin gallate	Epicatechin 3-O-gallate													0.0100	0.0100			0.0100		0.0100	0.0100			0.0300	0.0300				0.0300				0.0300	0.0300	0.0300	0.0200	0.0200			
Epigallocatechin	Epigallocatechin													0.0100	0.0100		0.0100	0.0100	0.0100	0.0100	0.0100	0.0100	0.0300	0.0400	0.0300	0.0600		0.0700	0.0400	0.0400	0.0300	0.0500	0.0600							0.0500
Epigallocatechin gallate	Epigallocatechin 3-O-gallate													0.0400		0.0400	0.0400		0.0400	0.0400	0.0400		0.1900	0.1800		0.1900	0.1900	0.1600				0.1800	0.2000			0.1700	0.1700	0.1900	0.1900	0.2000
Eriodictyol	Eriodictyol													0.0300	0.0300	0.0300	0.0300	0.0300	0.0300	0.0300	0.0300	0.0300	0.1400	0.1400	0.2800	0.1400	0.1500	0.2400	0.1700	0.1400	0.1200		0.1600	0.2000	0.4800	0.2400	0.1600	0.1400	0.1400	0.1500
Gallocatechin																									0.0100							0.2000	0.2300	0.1300	0.1600	0.1900	0.1700	0.2800	0.2600	0.1900
Gallocatechin gallate	Gallocatechin 3-O-gallate															0.0100	0.0100	0.0100	0.0100	0.0100	0.0100		0.0300	0.0300		0.0300	0.0300	0.0300				0.0300	0.0400			0.0300	0.0300	0.0300	0.0400	0.0400
Naringenin	Naringenin																					0.0200													0.0100	0.0200	0.0100			
Neochlorogenic acid																							1.3200	1.5900	1.7100				11.7700	12.0300	11.9300	0.3600	0.4000	0.4000				1.6600	1.5600	1.7100
Phloretin	Phloretin																						0.3300	0.5200	0.5700	0.2700	0.2900	0.2700				0.9100	0.7100	0.8200	0.0400	0.0200	0.0200			
Phloridzin	Phlorizin													0.0200	0.0200	0.0200	0.1200	0.1000	0.1000				24.4600	25.1800	25.4400	54.0800	56.1100	49.3800				39.8800	46.3200	45.4000	67.7000	60.1600	61.5700			
Procyanidin B1	Procyanidin B1													2.6300						0.0500	0.1000	0.1300	8.7100		0.1100	0.3500	2.2300	1.6300	0.1800	1.0100	0.9000	1.0500	1.2400	1.3500	1.3300	0.3300	0.3100	0.7800	0.6900	0.2700
Procyanidin B2+B4	Procyanidin B2													1.5100	1.4800	1.5200	0.9700	0.7300	0.9000	0.1200	0.1400	0.1700	0.6800	1.0700	0.9500	0.5800	0.5500	0.6400	4.4600	4.9300	4.1900	0.4600	0.5600	0.4400	0.3100	0.2100	0.2000	1.5900	1.5100	1.6200
Procyanidin B3	Procyanidin B3													0.8500	0.8300	0.0500	0.1700	0.1300	0.1300	0.0800	0.0700	0.0700	1.5700	0.2500	0.2200	0.1000	0.1800	0.0800	0.1900	1.8100	2.3000	0.2800	0.2000	0.2500	0.0800	0.0700	0.0700	0.6900	0.5700	0.4900