#METABOLOMICS WORKBENCH tkind_20141110_9719851_mwtab.txt DATATRACK_ID:176 STUDY_ID:ST000117 ANALYSIS_ID:AN000198 PROJECT_ID:PR000106
VERSION             	1
CREATED_ON          	2016-09-17
#PROJECT
PR:PROJECT_TITLE                 	Metabolomics analysis of multiple metabolic functions in the YjgF/YER057c/UK114
PR:PROJECT_TITLE                 	protein family
PR:PROJECT_SUMMARY               	-
PR:INSTITUTE                     	University of California, Davis
PR:DEPARTMENT                    	Genome Center
PR:LABORATORY                    	Fiehn Laboratory
PR:LAST_NAME                     	Fiehn
PR:FIRST_NAME                    	Oliver
PR:ADDRESS                       	451 Health Sciences Drive, Davis, California 95616, USA
PR:EMAIL                         	ofiehn@ucdavis.edu
PR:PHONE                         	-
PR:FUNDING_SOURCE                	U.S. National Science Foundation award MCB-1153413
#STUDY
ST:STUDY_TITLE                   	Metabolomics analysis of multiple metabolic functions in the YjgF/YER057c/UK114
ST:STUDY_TITLE                   	protein family GC-MS (Part 1)
ST:STUDY_TYPE                    	wildtype vs knock-out
ST:STUDY_SUMMARY                 	Metabolomics analysis of wild-type S. enterica, single RidA knock-out and
ST:STUDY_SUMMARY                 	Rid (ridA Rid2 Rid7) knock-out S.enterica cells
ST:INSTITUTE                     	University of California, Davis
ST:DEPARTMENT                    	Genome Center
ST:LABORATORY                    	Fiehn Laboratory
ST:LAST_NAME                     	ElBadawi-Sidhu
ST:FIRST_NAME                    	Mona
ST:ADDRESS                       	451 Health Sciences Drive, Davis, California 95616, USA
ST:EMAIL                         	mmelbadawi@ucdavis.edu
ST:PHONE                         	-
ST:NUM_GROUPS                    	3
ST:TOTAL_SUBJECTS                	6
#SUBJECT
SU:SUBJECT_TYPE                  	Bacterial cells
SU:SUBJECT_SPECIES               	Salmonella enterica;Escherichia coli
SU:GENOTYPE_STRAIN               	DM3480|DM14100|Salmonella enterica subsp.enterica serovar Typhimurium
SU:GENOTYPE_STRAIN               	|yjeF::kan
SU:SPECIES_GROUP                 	Microorganism
#SUBJECT_SAMPLE_FACTORS:         	SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Additional sample data
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa03_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa06_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa07_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa09_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa10_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa16_1	genotype:single RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa01_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa04_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa05_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa15_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa17_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa18_1	genotype:triple RidA knockout	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa02_1	genotype:Wild Type	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa08_1	genotype:Wild Type	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa11_1	genotype:Wild Type	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa12_1	genotype:Wild Type	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa13_1	genotype:Wild Type	
SUBJECT_SAMPLE_FACTORS           	-	140826bmssa14_1	genotype:Wild Type	
#COLLECTION
CO:COLLECTION_SUMMARY            	-
CO:SAMPLE_TYPE                   	Bacterial Cells
CO:COLLECTION_METHOD             	6 independent colonies of each cell line were grown in M9 minimal medium at 37C
CO:COLLECTION_METHOD             	OD600 reached 1.5-2.0. An equivalent of 1 mL at OD 2.0 was placed into a 1.5 mL
CO:COLLECTION_METHOD             	tube and spun for 15 sec. After removal of a 0.5 mL medium aliquot, remaining
CO:COLLECTION_METHOD             	was removed and cell pellet was frozen in liquid nitrogen.
CO:COLLECTION_LOCATION           	University of Florida, Gainesville
CO:COLLECTION_VIALS              	1.5 mL eppendorf tube
CO:STORAGE_VIALS                 	1.5 mL eppendorf tube
#TREATMENT
TR:TREATMENT_SUMMARY             	-
#SAMPLEPREP
SP:SAMPLEPREP_SUMMARY            	-
SP:EXTRACTION_METHOD             	1 mL of cold, degassed extraction solvent (3:3:2 acetonitrile:isopropanol:water
SP:EXTRACTION_METHOD             	was added to each sample, vortexed for 10 seconds, then shaken at 4C for 4 min.
SP:EXTRACTION_METHOD             	were spun down using a centrifuge at 14 rcf for 2 min. Aliquots (450 uL) were
SP:EXTRACTION_METHOD             	to 1.5 mL eppendorf tubes and dried down using a Labconco centrivap evaporator.
SP:EXTRACT_STORAGE               	-80C
SP:SAMPLE_DERIVATIZATION         	10 uL of 40 mg/mL methoxyamine hydrochloride in pyridine was added to room
SP:SAMPLE_DERIVATIZATION         	samples and shaken for 90 min at 30C. 91 uL of silyating agent (MSTFA)
SP:SAMPLE_DERIVATIZATION         	a set of 13 C8 - C30 fatty acid methyl ester internal standards was added and
SP:SAMPLE_DERIVATIZATION         	were shaken for 30 min at 37C. Derivatized samples were transferred to glass
SP:SAMPLE_DERIVATIZATION         	with inserts for analysis.
SP:SAMPLE_SPIKING                	Set of 13 C8 - C30 fatty acid methyl esters (FAMES)
#CHROMATOGRAPHY
CH:CHROMATOGRAPHY_SUMMARY        	Untargeted GC MS
CH:CHROMATOGRAPHY_TYPE           	GC
CH:INSTRUMENT_NAME               	Agilent 6890N
CH:COLUMN_NAME                   	Restek corporation Rtx-5Sil MS
CH:METHODS_FILENAME              	Data_Dictionary_Fiehn_laboratory_GCTOF_MS_primary_metabolism_09-27-2013_general.pdf
CH:COLUMN_TEMPERATURE            	50-330oC
CH:FLOW_RATE                     	1ml/min
CH:INTERNAL_STANDARD             	fatty acid methyl esters
CH:SAMPLE_INJECTION              	0.5uL
CH:OVEN_TEMPERATURE              	50C for 1 min, then ramped at 20C min-1 to 330C, held constant for 5 min
CH:TRANSFERLINE_TEMPERATURE      	280C
CH:WASHING_BUFFER                	Ethyl Acetate
CH:SAMPLE_LOOP_SIZE              	30 m length x 0.25 mm internal diameter
CH:RANDOMIZATION_ORDER           	Excel generated
#ANALYSIS
AN:ANALYSIS_TYPE                 	MS
AN:LABORATORY_NAME               	Fiehn Laboratory
AN:ACQUISITION_DATE              	07/2014 and 08/2014
AN:ACQUISITION_PARAMETERS_FILE   	Data_Dictionary_Fiehn_laboratory_GCTOF_MS_primary_metabolism_09-27-2013_general.pdf
AN:SOFTWARE_VERSION              	ChromaTOF
AN:PROCESSING_PARAMETERS_FILE    	Data_Dictionary_Fiehn_laboratory_GCTOF_MS_primary_metabolism_09-27-2013_general.pdf
AN:DETECTOR_TYPE                 	TOF
AN:DATA_FORMAT                   	.peg, .txt, .cdf
#MS
MS:INSTRUMENT_NAME               	Leco Pegasus III GC TOF
MS:INSTRUMENT_TYPE               	GC-TOF
MS:MS_TYPE                       	EI
MS:ION_MODE                      	POSITIVE
MS:ION_SOURCE_TEMPERATURE        	250°C
MS:IONIZATION                    	Electron Ionization (EI)
MS:IONIZATION_ENERGY             	-70eV
MS:MASS_ACCURACY                 	Nominal
MS:SCANNING_RANGE                	85-500 Da
MS:MS_COMMENTS                   	GCMS
#MS_METABOLITE_DATA
MS_METABOLITE_DATA:UNITS         	Peak area
MS_METABOLITE_DATA_START
Samples	140826bmssa03_1	140826bmssa06_1	140826bmssa07_1	140826bmssa09_1	140826bmssa10_1	140826bmssa16_1	140826bmssa01_1	140826bmssa04_1	140826bmssa05_1	140826bmssa15_1	140826bmssa17_1	140826bmssa18_1	140826bmssa02_1	140826bmssa08_1	140826bmssa11_1	140826bmssa12_1	140826bmssa13_1	140826bmssa14_1
Factors	genotype:single RidA knockout	genotype:single RidA knockout	genotype:single RidA knockout	genotype:single RidA knockout	genotype:single RidA knockout	genotype:single RidA knockout	genotype:triple RidA knockout	genotype:triple RidA knockout	genotype:triple RidA knockout	genotype:triple RidA knockout	genotype:triple RidA knockout	genotype:triple RidA knockout	genotype:Wild Type	genotype:Wild Type	genotype:Wild Type	genotype:Wild Type	genotype:Wild Type	genotype:Wild Type
2_5-dihydroxypyrazine NIST	3129.6597	10025.2888	11194.3064	10790.2459	11018.3879	11686.7095	4337.2937	5266.0649	6300.0512	7988.8374	7774.6226	4788.6260	7990.0746	11338.0308	6073.8634	7971.9646	12043.0479	10956.3583
2^-deoxyguanosine	129.4092	248.1351	225.3449	149.6819	275.3278	171.3398	148.4951	155.6281	151.4766	280.3518	223.2308	199.4891	199.0237	224.5486	159.2463	162.0200	121.3222	141.3590
2-hydroxyglutaric acid	629.3374	3749.3634	5887.2711	3912.9686	5762.8964	11110.3847	3827.8731	2673.8848	1167.5505	4855.0749	2122.5686	3182.0734	1159.1919	1237.8104	771.9986	617.0341	1028.6468	1738.9230
2-hydroxyhexanoic acid	273.1216	382.7168	643.3760	555.2390	515.8441	287.0498	377.4250	301.5294	286.2318	305.2983	354.5431	328.9354	89.3180	140.7618	83.0851	118.3619	92.2879	104.9798
2-isopropylmalic acid	267.6727	1084.0139	1171.3579	1108.4553	1125.5740	1401.8711	994.0920	828.7195	450.4955	932.5260	565.5806	637.4786	300.9627	421.1684	278.6811	258.0677	391.9642	349.2398
3-phosphoglycerate	5138.9080	17344.2228	12211.0799	11612.4851	14307.5534	14390.3180	18792.8769	16923.5801	23503.4697	23977.2037	18805.7888	16864.3685	7742.5085	11861.9777	7345.2378	8197.0462	9850.9519	10104.0469
adenine	570.7627	2792.5713	3543.4666	2818.6724	3356.6788	2409.8832	2309.9234	1362.7183	1220.6657	2848.6591	1793.3500	1884.0641	2205.7654	2941.4755	1017.7919	1725.9493	2012.7050	1716.0561
adenosine	399.8064	1419.4169	2001.9770	1866.9785	1689.9433	1143.7488	1424.1090	553.4523	668.8579	1850.7968	983.9039	980.5999	1071.8156	1124.9775	773.7295	974.0602	892.8073	966.6458
adenosine-5-monophosphate	9782.6555	27710.1716	25762.2543	22694.0040	25821.7424	28832.9280	23039.4236	23855.8380	24074.9497	39493.9613	22929.9312	17047.0119	19570.3432	29523.1196	18089.1734	21902.7714	23177.7343	27516.1438
alanine	138788.6583	298723.1149	321789.2254	271600.8770	289822.1063	326451.2728	355673.5504	292512.6873	289235.7927	436565.9110	270250.9099	238158.1140	322566.0111	437188.3913	333648.7921	309855.9150	365729.5494	447333.5249
alanine-alanine	992.3643	14078.5125	18039.5654	16825.0568	18228.6016	1006.8995	5934.6470	1667.1657	16464.7239	11452.8449	1130.2232	4952.6504	3248.4556	23196.6570	556.4967	2772.7729	2535.3239	881.4146
alpha-ketoglutarate	55.8503	285.9862	144.7868	165.8637	231.0222	100.1336	400.1117	216.9066	291.1499	471.6087	157.5747	487.6401	99.0264	111.7157	101.2599	116.4215	131.6917	93.5464
aspartic acid	7906.9030	33539.2435	8879.8947	19808.5816	17591.4444	3024.0362	7430.9411	3573.6096	8390.2321	10171.0671	2708.7839	2119.0180	11993.8496	20831.6347	7072.6149	9929.7867	10988.4776	9124.9283
benzoic acid	854.1008	1251.1897	1624.2249	1216.6713	1277.4790	1455.2757	1400.3911	1299.4944	1180.3375	1527.6795	553.3873	1161.4701	1477.6298	1350.6433	1542.2663	1185.5593	1380.1702	1277.4276
beta-alanine	192.0705	353.2771	391.9041	265.9888	342.8412	378.2827	288.7404	268.4584	343.2815	508.4346	337.6600	274.8517	117.4725	170.9251	175.6903	121.2724	201.1668	222.4325
cholesterol	154.6100	255.4950	434.3604	267.0002	383.9821	168.0020	319.6769	352.1085	246.8873	608.2208	474.6000	384.7924	267.9539	225.6658	168.7665	203.7377	298.6394	249.4570
citric acid	200.9248	686.5772	522.5389	538.0458	577.0281	639.7428	560.9814	457.1575	369.8391	620.1001	328.2806	752.7390	1158.2210	1298.1369	919.1284	1266.0842	1336.6186	1174.5266
cysteine	69.4723	329.0944	242.7628	332.7389	415.6290	182.4658	854.8779	1036.8720	3023.6311	934.9019	397.6885	481.4338	87.3763	263.6492	54.5246	93.1372	103.6942	129.9255
cysteine-glycine	647.7272	4639.9160	4578.7467	4236.6051	5046.6221	3439.0346	6948.3321	4104.6904	5736.4401	20373.0204	4278.9032	7066.3486	2940.6970	5633.8250	1992.3103	3412.1211	2859.8869	2909.2920
cytidine-5-monophosphate	196.8382	529.9156	534.5137	499.6140	551.7106	786.6054	621.8231	506.7639	487.8728	1069.1381	675.3201	452.1754	512.6075	539.5870	611.8868	861.5194	880.3640	743.1739
cytosin	156.6533	342.7629	141.5209	236.6593	34.8116	226.9696	217.5865	193.5624	293.1171	157.9949	252.3071	179.9835	232.0325	197.7369	433.6001	402.6245	345.3018	328.4517
fructose	155.9722	124.0675	174.1796	224.5229	228.9124	364.9315	241.3045	206.2072	147.5422	345.6880	184.7751	428.2367	271.8373	277.0550	445.7167	284.2626	155.5413	373.1461
fructose-1_6-bisphosphate	512.8692	1272.2181	2136.9662	1765.8421	1564.4107	1507.5677	1977.8719	2923.8624	2426.5771	1225.9450	1890.8963	1536.5097	3786.3051	4165.8801	1260.9887	2192.6056	1750.3586	1914.5823
fructose-1-phosphate	133.4958	322.7859	550.8430	475.3412	404.0251	399.4220	512.5143	536.9168	446.5610	509.6225	434.2683	454.8352	656.2929	860.2112	629.1962	581.1375	563.0597	657.9428
fructose-6-phosphate	232.2555	871.6271	1165.9148	960.7961	894.5517	1290.6115	1289.0198	1501.8109	1617.0623	1463.5313	1238.0868	1423.0225	1838.7851	2283.4698	1967.2117	2114.9912	1903.8261	2273.1767
fumaric acid	4191.4964	6377.9131	6430.4938	7506.3460	6430.6456	4597.2471	5660.3436	8128.6487	4738.0713	5352.8181	4520.8929	4236.2627	5788.1926	5686.3314	1640.9298	3427.6440	5865.9826	6745.7324
glucose	288.1058	341.7115	2069.4716	783.8073	750.0310	6981.5405	4628.0965	19713.2133	7177.4354	5408.6508	10553.7524	20114.7116	21596.5018	18083.4274	15806.0654	6405.1248	21372.4178	41134.4159
glucose-1-phosphate	303.0900	709.7084	897.0250	735.2619	890.3322	1030.2640	1201.3664	1106.9047	943.2864	1379.1881	953.8896	997.4457	982.4976	792.0646	807.4828	1001.2252	1338.6925	1017.5766
glucose-6-phosphate	681.1011	2235.3187	2637.7326	2143.0810	2243.7636	3664.8916	3212.2372	3702.9754	3753.4731	3658.8282	3148.6800	3631.5890	4691.1349	5605.8960	4802.4890	5399.0487	4893.3307	5753.1015
glutamic acid	68033.8296	193980.6640	232722.4773	207754.4588	182779.7070	193205.6510	312946.1546	265332.2446	293544.0244	361030.1165	207674.0613	251937.0505	301152.0286	416983.4819	168293.9629	253073.2517	289821.2252	272715.7206
glutamine	711.7507	4365.4954	2535.4021	2697.3086	4181.6074	826.6589	1060.0899	865.6811	1633.7838	2455.4538	423.9510	890.1649	2282.4624	7589.9676	727.8597	1183.6189	1565.7829	858.5478
glutathione	343.9561	279.6777	192.6862	140.5796	179.3323	359.3685	1626.2273	284.0212	263.6087	308.8621	331.0944	274.8517	1335.8861	186.5653	261.3717	2078.1244	2700.1977	319.0970
glyceric acid	1891.4178	5421.1210	4070.3600	3844.1958	4656.3106	3949.7162	6430.6618	3362.5390	5882.0150	7714.4253	4547.1553	3405.5013	1765.0007	2637.6087	1411.5804	1970.4345	1708.8809	1836.6270
glycerol-alpha-phosphate	1486.1627	3552.7479	3682.8103	3811.8321	4616.2246	6851.3668	4114.5511	3756.4726	3632.4885	7754.8150	5474.7825	3414.3674	3857.1770	3688.8539	4994.6232	5698.8341	7126.9044	5833.1356
glycine	2652.2078	5875.3344	7386.3045	6960.2093	5711.2065	7243.0006	19915.8709	14182.5807	13451.9126	15206.7075	13215.6391	11134.1538	7480.3797	5019.3884	4381.8710	4757.7601	5977.9724	5500.5263
glycolic acid	567.3572	484.7046	853.4801	1366.3532	1086.5428	1730.0869	841.4721	739.2333	671.8087	786.4105	1030.8011	1396.4240	1375.6909	1111.5716	1111.2626	807.1893	1029.6837	1177.6448
guanine	892.9236	2886.1476	2194.6632	2078.3537	2491.6642	3319.9868	2002.6211	1829.6025	1856.0807	3826.3265	1874.0133	1813.1346	2131.9810	3363.7610	1553.5174	2394.4029	3008.1696	2656.7168
guanosine	406.6174	1139.7392	1010.2418	1098.3417	1053.8410	1088.1190	1136.3998	833.5829	780.9900	1831.7899	929.5031	804.1629	760.1736	1181.9526	832.5814	872.1913	888.6596	1079.9408
heptadecanoic acid	553.0541	1052.4713	1070.1160	1040.6939	1101.3113	1048.0655	839.4097	806.3479	1099.6811	1417.2019	1391.9098	1219.1003	1652.3824	1634.4013	1120.7827	2104.3192	2324.8246	1087.2167
hexose-6-phosphate	156.6533	433.1850	509.4754	454.1026	445.1661	682.0214	622.8543	771.3316	763.2849	785.2225	793.5011	797.9566	999.9729	1196.4756	1156.2670	1033.2411	1071.1614	1219.2210
hexose NIST	154.6100	211.3354	421.2970	302.3979	381.8723	561.8610	990.9984	3075.5998	1439.0281	1022.8088	805.6944	3338.1183	3159.1376	929.4750	2337.6325	1886.0289	2878.5518	4485.0285
hydroxylamine	1443.2533	2990.2382	2721.5565	2810.5814	2885.1404	3161.9981	1571.5729	2347.0659	2409.8556	3778.8092	3567.9412	3237.0438	2008.6834	2400.7713	1747.3825	3271.4451	3584.7095	2656.7168
hypoxanthine	2821.1209	7754.2218	7022.7045	6465.6521	7848.4257	8139.7531	8250.7577	5384.7313	6102.3447	11593.0208	5754.2900	4863.1019	6033.8170	7766.4785	5075.9773	6155.7887	5434.6146	7718.6146
inosine	625.9319	1188.1045	1347.7148	1305.6713	1143.5072	1159.3251	1665.4135	950.3039	1036.7297	2619.3883	1331.8813	910.5571	899.9756	1190.8898	1474.7596	979.8813	863.7729	1472.8356
inosine-5^-monophosphate	1139.4822	2328.8951	4219.5013	3816.8889	2881.9757	3750.5615	4074.3337	4981.0710	4801.0226	4453.5541	4924.2090	3940.1322	1529.0848	1580.7778	1069.7200	1374.7443	1281.6607	1713.9773
isoleucine	5229.4945	11566.6704	13965.9396	11664.0647	10935.0511	13887.4245	12732.4216	12782.9007	13307.3212	15216.2110	11111.8294	10341.5170	6526.0366	9141.6993	4595.6419	6413.8564	7968.9016	8004.4507
lactic acid	4490.4997	11602.4186	19554.9281	15234.1808	18386.8360	11898.1027	14325.6500	4364.3947	11113.8608	13420.0590	4803.2142	10143.8011	9620.1275	6364.4459	2865.5688	7839.0500	7320.8126	5120.1044
lauric acid	421.6016	890.5527	999.3556	763.5801	1171.9894	1360.7050	1148.7744	748.9601	830.1707	1868.6158	1234.3351	1623.3983	1130.0664	1257.9193	1138.0921	1790.9513	1396.7613	1555.9879
levoglucosan	183.2162	264.9578	395.1700	296.3297	639.2669	411.6606	444.4540	359.8899	372.7899	402.7087	233.5482	360.8537	322.3214	264.7663	311.5689	456.9545	547.5055	374.1855
lysine	534.6644	2628.5498	2864.1661	2687.1950	2486.3897	1839.1214	2752.3150	2535.7649	3208.5507	3202.6626	1792.4121	2792.8479	2931.9593	3676.5651	780.6533	1318.4739	2056.2566	1586.1306
malic acid	4658.7317	14386.5786	14779.1407	15644.7947	15453.1704	15232.5532	18422.6704	19697.6505	16647.6763	18338.0942	15045.5690	14137.1303	12814.2157	11596.0942	10962.0339	8343.5433	13334.0410	14565.1692
mannose-6-phosphate NIST	1270.9347	2012.4177	7872.9188	4766.5600	3915.7737	13791.7413	11342.3427	16627.8868	9644.3407	12013.5484	18388.4035	18479.7872	17748.0625	18421.9261	23655.0063	17736.8208	21135.9949	27972.4422
methionine	401.8497	1085.0653	1242.1184	1482.6601	1109.7505	639.7428	1119.9004	1417.1881	1889.5235	1209.3140	942.6343	898.1444	425.2312	1208.7643	205.1162	373.5191	490.4737	610.1302
myristic acid	2432.2121	4524.2599	4804.0916	4286.1620	4578.2483	3940.8154	4841.5582	3473.4240	4324.9532	5868.3802	4626.8806	3966.7307	5034.8149	6037.1188	3665.2624	5683.3113	5969.6768	3806.2977
N-acetylgalactosamine	83.0943	127.2218	277.5988	197.2160	177.2225	263.6853	112.4025	165.3548	111.1484	193.6328	124.7466	231.4074	256.3037	187.6824	284.7394	230.9027	148.2827	459.4166
N-acetyl-L-ornithine	176.4052	544.6355	971.0514	1150.9326	1069.6645	354.9182	1040.4967	294.7207	553.7750	911.1432	238.2379	626.8392	1827.1349	1498.1081	387.7302	1739.5318	2078.0324	472.9289
nicotinamide	369.1568	1163.9218	1298.7268	1137.7849	1195.1971	482.8667	895.0953	796.6212	983.6145	1133.2864	363.9225	398.9783	567.9458	1232.2247	190.4032	439.4913	413.7400	405.3676
nicotinic acid	363.0269	1252.2411	1214.9028	1194.4213	1277.4790	1586.5620	1563.3232	1217.7897	1004.2705	1822.2865	1108.6505	913.2169	1114.5329	1026.6677	920.8593	1351.4600	1415.4262	1549.7515
N-methylalanine	493.1172	977.8205	1882.2285	1042.7166	868.1793	1159.3251	1376.6731	1067.9976	1205.9114	1174.8640	878.8541	833.4213	689.3017	949.5838	675.9315	633.5272	665.7170	784.7501
O-acetylserine	256.0940	198.7184	763.1245	1001.2507	438.8367	397.1968	896.1265	1796.5316	1608.2098	109.2897	805.6944	1088.7674	112.6183	230.1344	118.5693	61.1213	118.2114	148.6348
oleic acid	132.1336	376.4083	263.4467	450.0571	139.2463	400.5346	79.4036	373.5074	338.3634	299.3587	48.7731	333.3685	461.1525	550.7586	431.8692	582.1077	182.5018	607.0120
ornithine 4tms	550.3297	2091.2742	2576.7697	2563.8086	2756.4431	1786.8293	2694.5669	1779.0234	2010.5081	2769.0677	1376.9026	1836.1867	2450.4190	3668.7450	949.4198	1519.3010	1865.4592	1610.0369
orotic acid	121.9171	251.2894	372.3089	594.6822	527.4480	324.8781	1111.6506	202.3165	365.9046	553.5759	173.5197	580.7350	1405.7871	449.0973	507.1650	713.0819	535.0622	556.0812
oxoproline	43194.0714	117852.6057	119421.9012	112399.9965	116872.9744	125988.1575	117385.3578	93300.0016	102615.5879	207541.0874	119689.2320	117504.4227	122303.4799	145620.3547	101324.8157	154497.1978	174488.3548	134342.9755
palmitic acid	5845.2099	12920.8992	12292.7266	11221.0871	12597.5671	7958.3999	9432.5310	7158.8913	11499.4377	13447.3814	9957.2197	9618.0364	15631.6150	17433.2418	5804.7024	13509.7489	18203.5221	7144.8635
palmitoleic acid	457.7000	1040.9057	1061.4071	1235.8872	1217.3499	1188.2526	1050.8089	1191.5274	901.9745	1433.8330	1103.9608	1070.1484	1098.0285	1177.4839	926.9176	1086.6010	1124.0455	1349.1465
pelargonic acid	2526.2041	3628.4501	6116.9705	2970.3770	4907.3758	4008.6838	3145.2082	3201.0749	2418.7082	6950.5856	2760.3709	2963.9653	4139.6936	4445.1694	4620.7405	7398.5885	3548.4166	6094.0260
pentadecanoic acid	375.2867	804.3362	879.6071	540.0685	588.6319	587.4507	574.3872	771.3316	793.7769	761.4639	860.0952	908.7839	1192.2007	1092.5800	630.9271	781.9646	992.3538	1102.8077
phenylalanine	682.4633	1791.6195	1674.3016	1443.2169	1530.6540	2323.1007	1891.2498	1516.4010	1573.7833	2580.1866	1761.4599	1427.4556	1606.7525	1758.4058	1645.2571	1534.8239	1785.6146	1862.6121
phosphate	92683.5606	191793.7106	217957.4888	198459.0093	212811.5391	217824.0650	205367.6592	200532.6063	189800.2307	228685.0752	175998.7349	16083.2577	191505.4870	224735.2101	167483.0182	195341.7529	208180.6840	225203.5214
phosphoenolpyruvate	1148.3365	4062.6865	2401.5015	2457.6153	2990.6299	3170.8989	3562.8506	3407.2821	4135.1156	5228.0853	3904.6633	2915.2013	1301.9064	1853.3642	941.6306	1322.3546	1551.2657	1502.9783
phosphoethanolamine	384.1410	2608.5728	2924.0404	3414.3659	3985.3968	5740.9959	1012.6539	1935.6241	1679.0300	5004.7542	4266.7099	2525.0892	2098.9722	2750.4416	1843.4496	3658.5467	5729.1062	4692.9094
proline	9471.3923	20235.6275	21439.3338	16410.3975	20427.0047	20684.2741	15278.4934	14586.2410	20291.9682	24101.9365	10587.5184	11783.1585	19794.6089	40752.7861	15118.8828	16843.2856	22092.0557	19868.2087
propane-1_3-diol NIST	811.8725	1320.5834	1278.0430	1111.4894	1369.2549	1032.4892	1142.5871	906.5335	1128.2059	1301.9726	1163.0513	1034.6837	1205.7925	1272.4423	993.5587	1219.5156	1147.8951	1156.8567
putrescine	92437.0020	219288.3411	230266.5447	181439.7705	238873.7978	396496.9857	179140.7476	260697.4461	160848.5200	259350.3317	199310.4095	218568.2805	261989.0128	329608.3644	172656.7935	271552.2598	275956.2697	345034.3373
pyrophosphate	28005.5162	82566.9537	86233.0634	83979.6477	81315.5974	96598.9314	65641.0110	68978.2520	73585.1881	123454.5640	84225.5474	76435.3720	66820.5183	91305.2773	74831.0701	87920.5729	107510.1777	102368.8276
ribose	956.2660	2578.0816	3900.5348	2842.9451	2408.3274	3251.0058	3755.6880	3296.3971	2642.9723	4548.5886	3505.0989	2980.8110	352.4176	2543.7675	2465.7220	2607.8424	1875.8286	2862.5188
ribose-5-phosphate	78.3266	212.3868	92.5329	245.7615	332.2922	371.6071	325.8642	413.3871	354.1012	286.2914	362.0466	418.4839	199.0237	119.5358	265.6991	239.6343	266.4942	357.5550
serine	1358.1157	3268.8645	3597.8978	3983.7641	3666.8182	3453.4983	3949.5565	3793.4342	4516.7580	4543.8369	4039.7273	3820.4387	3455.2461	1817.6151	1074.9128	1882.1481	2108.1037	1592.3670
spermidine	299.0034	717.0684	690.1867	551.1936	753.1957	1111.4835	607.3861	933.7684	623.6116	3379.6643	783.1837	848.4938	838.8122	1359.5806	513.2233	3573.1709	741.4137	1324.2008
stearic acid	34330.9024	79941.5582	76729.3880	70425.3431	83090.9873	38511.4015	53584.0358	31721.8644	74063.2247	79678.1107	59965.6108	56999.8101	104506.8751	132533.9725	25854.1637	98887.4815	146593.5700	31293.3382
succinic acid	5068.0735	16077.2618	14334.9826	14507.0098	14998.5102	15481.7748	16459.2355	13095.1295	13864.0471	17946.0769	14109.5003	11611.1545	12106.4679	14537.5697	9524.4894	11315.2030	12232.8083	13338.6724
threonine	3529.4661	9493.2703	10087.1772	9375.3473	8269.3292	10638.6439	11062.8832	8888.3082	8453.1834	14459.4988	8980.8194	8679.9941	7492.0299	9137.2307	5455.9183	7068.7275	8898.0019	8156.2037
thymidine	200.9248	520.4529	458.3101	398.4775	240.5163	521.8076	505.2957	347.2451	364.9210	574.9587	453.9652	472.5676	222.3241	403.2938	373.0173	479.2687	398.1858	520.7414
thymidine-5-phosphate	243.8342	574.0753	621.6035	526.9208	603.4005	1267.2470	1011.6227	583.6053	520.3321	1515.8002	768.1766	540.8372	684.4475	566.3988	1086.1639	1522.2116	1470.3842	1171.4084
thymine	1251.8639	2788.3656	3001.3326	2395.9221	2531.7502	5250.3410	5037.4892	2620.3877	2539.6928	6690.4286	3729.2677	2690.8868	3329.0359	2623.0857	4893.3633	5687.1920	5544.5305	4691.8700
tryptophan	1026.4194	3519.1024	3860.2558	3320.3091	3509.6387	3130.8454	3541.1951	3313.9052	3810.5228	5489.4302	3236.8467	3106.7109	1045.6027	2561.6420	809.2138	1091.4519	1564.7459	1598.6035
tyrosine	2238.7794	8203.1781	7593.1428	7078.5389	7156.4140	6611.0460	6367.7576	6416.7399	6527.2662	8424.8082	4972.0442	5536.0453	6434.7770	10806.2639	4486.5927	4638.4280	5368.2503	6607.4916
UDP-glucuronic acid	313.3065	1074.5511	918.7975	968.8870	972.6140	1240.5447	719.7886	806.3479	760.3340	1249.7036	903.2406	681.8095	851.4332	1099.2829	824.7922	890.6247	1059.7550	1089.2955
UDP-N-acetylglucosamine	155.9722	260.7521	272.1557	260.9320	198.3204	318.2025	176.3379	152.7100	141.6405	363.5070	232.6103	187.0765	302.9044	334.0301	163.5737	352.1751	377.4470	354.4368
uracil	6565.8149	14737.7528	14873.8508	12019.0536	11775.8032	15961.3037	16580.9190	11900.6841	14753.2346	23114.7657	14352.4280	10916.9323	13015.1811	15977.5857	10671.2362	11487.8949	11961.1294	16449.6087
urea	1330.8716	3243.6304	3271.3110	2781.2519	712.0547	146.8627	2414.0762	3356.7030	2494.4465	2953.1970	2690.0251	2520.6561	83.4929	2350.4992	45.0044	1543.5555	89.1770	81.0735
uridine-5^-monophosphate	3387.7970	14777.7068	15495.4543	14155.0550	13384.5195	11828.0092	11384.6225	11754.7828	13589.6186	17006.4233	10041.6347	8042.5155	10314.2834	17019.8936	9901.8340	8307.6467	8038.3767	12151.6729
valine	228872.4558	487104.9679	529304.6460	417944.2828	488176.2967	535367.8934	397401.6980	277491.6603	319926.5339	540502.7651	260807.6838	226293.3866	390893.2846	554406.1353	362481.9011	413715.5662	463401.2186	462815.4485
xylulose NIST	73.5589	343.8143	420.2083	379.2616	98.1053	488.4297	370.2065	305.4201	309.8386	491.8035	329.2185	282.8313	237.8576	479.2605	298.5869	322.0996	328.7107	406.4070
uridine-5-monophosphate	3388	14778	15495	14155	13385	11828	11385	11755	13590	17006	10042	8043	10314	17020	9902	8308	8038	12152
propane-1,3-diol NIST	812	1321	1278	1111	1369	1032	1143	907	1128	1302	1163	1035	1206	1272	994	1220	1148	1157
ornithine	550	2091	2577	2564	2756	1787	2695	1779	2011	2769	1377	1836	2450	3669	949	1519	1865	1610
inosine-5-monophosphate	1139	2329	4220	3817	2882	3751	4074	4981	4801	4454	4924	3940	1529	1581	1070	1375	1282	1714
fructose-1,6-bisphosphate	513	1272	2137	1766	1564	1508	1978	2924	2427	1226	1891	1537	3786	4166	1261	2193	1750	1915
2-deoxyguanosine	129	248	225	150	275	171	148	156	151	280	223	199	199	225	159	162	121	141
2,5-dihydroxypyrazine NIST	3130	10025	11194	10790	11018	11687	4337	5266	6300	7989	7775	4789	7990	11338	6074	7972	12043	10956
MS_METABOLITE_DATA_END
#METABOLITES
METABOLITES_START
metabolite_name	moverz_quant	ri	ri_type	pubchem_id	inchi_key	kegg_id	other_id	other_id_type
2,5-dihydroxypyrazine NIST	241	397526	Fiehn	23368901	USHRADXTTYICIJ-UHFFFAOYSA-N		2254	BinBase
2'-deoxyguanosine	295	962182	Fiehn	187790		C00330	66347	BinBase
2-hydroxyglutaric acid	247	506306	Fiehn	43	HWXBTNAVRSUOJR-UHFFFAOYSA-N	C02630	2000	BinBase
2-hydroxyhexanoic acid	159	323093	Fiehn				106285	BinBase
2-isopropylmalic acid	275	508690	Fiehn	5280523		C02504	17246	BinBase
3-phosphoglycerate	227	610734	Fiehn	724	OSJPPGNTCRNQQC-UHFFFAOYSA-N	C00597	1667	BinBase
adenine	264	646534	Fiehn	190	GFFGJBXGBJISGV-UHFFFAOYSA-N	C00147	1764	BinBase
adenosine	236	918039	Fiehn	60961	OIRDTQYFTABQOQ-KQYNXXCUSA-N	C00212	290	BinBase
adenosine-5-monophosphate	169	1038688	Fiehn	6083	UDMBCSSLTHHNCD-KQYNXXCUSA-N	C00020	1726	BinBase
alanine	116	244189	Fiehn	5950		C00041	2	BinBase
alanine-alanine	116	522546	Fiehn	5484352		C00993	84119	BinBase
alpha-ketoglutarate	198	507392	Fiehn	51	KPGXRSRHYNQIFN-UHFFFAOYSA-N	C00026	294	BinBase
aspartic acid	232	480387	Fiehn	5960	CKLJMWTZIZZHCS-REOHCLBHSA-N	C00049	79	BinBase
benzoic acid	179	339067	Fiehn	243	WPYMKLBDIGXBTP-UHFFFAOYSA-N	C00180	36	BinBase
beta-alanine	248	435564	Fiehn	239	UCMIRNVEIXFBKS-UHFFFAOYSA-N	C00099	148	BinBase
cholesterol	129	1076014	Fiehn	5997		C00187	87943	BinBase
citric acid	273	620091	Fiehn	311		C00158	37754	BinBase
cysteine	220	500158	Fiehn	5862	XUJNEKJLAYXESH-REOHCLBHSA-N	C00097	65	BinBase
cysteine-glycine	220	715335	Fiehn	439498	ZUKPVRWZDMRIEO-VKHMYHEASA-N	C01419	2787	BinBase
cytidine-5-monophosphate	243	700635	Fiehn				2246	BinBase
cytosin	254	486724	Fiehn	597	OPTASPLRGRRNAP-UHFFFAOYSA-N	C00380	2186	BinBase
fructose	307	639442	Fiehn	439709	RFSUNEUAIZKAJO-ARQDHWQXSA-N	C02336	21	BinBase
fructose-1,6-bisphosphate	315	939046	Fiehn				110203	BinBase
fructose-1-phosphate	387	803180	Fiehn	481		C01094	87944	BinBase
fructose-6-phosphate	315	804279	Fiehn	440641		C05345	6431	BinBase
fumaric acid	245	392338	Fiehn	444972		C00122	64523	BinBase
glucose	117	714386	Fiehn	64689	WQZGKKKJIJFFOK-VFUOTHLCSA-N	C00221	5	BinBase
glucose-1-phosphate	217	597071	Fiehn	65533		C00103	62291	BinBase
glucose-6-phosphate	387	818275	Fiehn	5958		C00092	308	BinBase
glutamic acid	246	529100	Fiehn	33032		C00025	28	BinBase
glutamine	156	600315	Fiehn	5961	ZDXPYRJPNDTMRX-VKHMYHEASA-N	C00064	18	BinBase
glutathione	213	761296	Fiehn	124886		C00051	84386	BinBase
glyceric acid	189	377495	Fiehn	439194		C00258	48	BinBase
glycerol-alpha-phosphate	357	593299	Fiehn	754		C03189	62254	BinBase
glycine	248	368707	Fiehn	750	DHMQDGOQFOQNFH-UHFFFAOYSA-N	C00037	6	BinBase
glycolic acid	177	227636	Fiehn	757	AEMRFAOFKBGASW-UHFFFAOYSA-N	C00160	1971	BinBase
guanine	352	744307	Fiehn	764		C00242	2519	BinBase
guanosine	324	957445	Fiehn	6802		C00387	64568	BinBase
heptadecanoic acid	117	751309	Fiehn	10465	KEMQGTRYUADPNZ-UHFFFAOYSA-N		727	BinBase
hexose-6-phosphate	387	806282	Fiehn	208		C02965	18607	BinBase
hexose NIST	204	682268	Fiehn	206			62272	BinBase
hydroxylamine	146	255241	Fiehn	787		C00192	139	BinBase
hypoxanthine	265	619128	Fiehn	790		C00262	1663	BinBase
inosine	230	897434	Fiehn	6021		C00294	84524	BinBase
inosine-5'-monophosphate	169	1018687	Fiehn	8582		C00130	68093	BinBase
isoleucine	158	359251	Fiehn	6306	AGPKZVBTJJNPAG-WHFBIAKZSA-N	C00407	15	BinBase
lactic acid	191	217657	Fiehn	612	JVTAAEKCZFNVCJ-UHFFFAOYSA-N	C01432	80	BinBase
lauric acid	117	547906	Fiehn	3893	POULHZVOKOAJMA-UHFFFAOYSA-N	C02679	49	BinBase
levoglucosan	204	569637	Fiehn	2724705		0	3169	BinBase
lysine	156	663483	Fiehn	5962	KDXKERNSBIXSRK-YFKPBYRVSA-N	C00047	12	BinBase
malic acid	233	463180	Fiehn	525	BJEPYKJPYRNKOW-UHFFFAOYSA-N	C00711	1391	BinBase
mannose-6-phosphate NIST	387	822643	Fiehn	65127		C00275	87363	BinBase
methionine	176	483560	Fiehn	6137	FFEARJCKVFRZRR-BYPYZUCNSA-N	C00073	45	BinBase
myristic acid	117	634414	Fiehn	11005	TUNFSRHWOTWDNC-UHFFFAOYSA-N	C06424	127	BinBase
N-acetylgalactosamine	202	725570	Fiehn	440552		C05021	62259	BinBase
N-acetyl-L-ornithine	174	694651	Fiehn	439232		C00437	19188	BinBase
nicotinamide	179	469827	Fiehn	936		C00153	1749	BinBase
nicotinic acid	180	366992	Fiehn	938		C00253	285	BinBase
N-methylalanine	130	286855	Fiehn	5288725		C02721	35	BinBase
O-acetylserine	174	414914	Fiehn	99478		C00979	3943	BinBase
oleic acid	339	779120	Fiehn	445639		C00712	43	BinBase
ornithine 4tms	142	619548	Fiehn	6262	AHLPHDHHMVZTML-BYPYZUCNSA-N	C00077	1964	BinBase
orotic acid	254	586317	Fiehn	967	PXQPEWDEAKTCGB-UHFFFAOYSA-N	C00295	18492	BinBase
oxoproline	156	485935	Fiehn	7405		C01879	10	BinBase
palmitic acid	313	713809	Fiehn	985	IPCSVZSSVZVIGE-UHFFFAOYSA-N	C00249	11	BinBase
palmitoleic acid	117	706508	Fiehn	445638	SECPZKHBENQXJG-FPLPWBNLSA-N	C08362	96	BinBase
pelargonic acid	117	399229	Fiehn	8158	FBUKVWPVBMHYJY-UHFFFAOYSA-N	C01601	50	BinBase
pentadecanoic acid	117	674647	Fiehn	13849		C16537	1680	BinBase
phenylalanine	218	537804	Fiehn	6140	COLNVLDHVKWLRT-QMMMGPOBSA-N	C00079	33	BinBase
phosphate	314	345365	Fiehn	1004		C00009	4	BinBase
phosphoenolpyruvate	211	518184	Fiehn				1685	BinBase
phosphoethanolamine	299	604335	Fiehn	1015		C00346	41988	BinBase
proline	142	364716	Fiehn	145742	ONIBWKKTOPOVIA-BYPYZUCNSA-N	C00148	8	BinBase
propane-1,3-diol NIST	177	214380	Fiehn	10442	YPFDHNVEDLHUCE-UHFFFAOYSA-N	C02457	282	BinBase
putrescine	174	588119	Fiehn	1049		C00138	21703	BinBase
pyrophosphate	110	327517	Fiehn	1023		C00013	88181	BinBase
ribose	217	553135	Fiehn	5779	HMFHBZSHGGEWLO-SOOFDHNKSA-N	C00121	1662	BinBase
ribose-5-phosphate	315	733959	Fiehn	439167		C00117	13110	BinBase
serine	218	395020	Fiehn	5951	MTCFGRXMJLQNBG-REOHCLBHSA-N	C00065	25	BinBase
spermidine	144	792924	Fiehn	1102		C00315	1714	BinBase
stearic acid	100	329250	Fiehn	5281	QIQXTHQIDYTFRH-UHFFFAOYSA-N	C01530	13	BinBase
succinic acid	247	370608	Fiehn	1110	KDYFGRWQOYBRFD-UHFFFAOYSA-N	C00042	161	BinBase
threonine	218	409568	Fiehn	6288	AYFVYJQAPQTCCC-GBXIJSLDSA-N	C00188	26	BinBase
thymidine	170	349402	Fiehn	5789	IQFYYKKMVGJFEH-XLPZGREQSA-N	C00214	87703	BinBase
thymidine-5-phosphate	170	608111	Fiehn	9700		C00364	1810	BinBase
thymine	255	420133	Fiehn	1135		C00178	1692	BinBase
tryptophan	202	780482	Fiehn	6305	QIVBCDIJIAJPQS-VIFPVBQESA-N	C00078	14	BinBase
tyrosine	218	671252	Fiehn	6057	OUYCCCASQSFEME-QMMMGPOBSA-N	C00082	16	BinBase
UDP-glucuronic acid	217	587601	Fiehn	17473		C00167	7831	BinBase
UDP-N-acetylglucosamine	226	625003	Fiehn	445675		C00043	62293	BinBase
uracil	241	385735	Fiehn	1174		C00106	1664	BinBase
urea	189	332913	Fiehn	1176		C00086	22329	BinBase
uridine-5'-monophosphate	169	980179	Fiehn				110201	BinBase
valine	144	313502	Fiehn	6287		C00183	3	BinBase
xylulose NIST	173	553450	Fiehn	22253		C00312	31632	BinBase
uridine-5-monophosphate	169	980179					
ornithine	142	619548	6262		C00077		
inosine-5-monophosphate	169	1018687	8582		C00130		
2-deoxyguanosine	295	962182	187790		C00330		
2,5-dihydroxypyrazine NIST	241	397526	23368901				
METABOLITES_END
#END