#METABOLOMICS WORKBENCH araskind_20170619_105956 DATATRACK_ID:985 STUDY_ID:ST000690 ANALYSIS_ID:AN001065 PROJECT_ID:PR000489
VERSION             	1
CREATED_ON             	June 30, 2017, 3:11 pm
#PROJECT
PR:PROJECT_TITLE                 	Human oral keratinocytes growth and proliferation based on culture medium volume
PR:PROJECT_TYPE                  	MS analysis
PR:PROJECT_SUMMARY               	Using different culture medium volume to affect cultured human oral
PR:PROJECT_SUMMARY               	keratinocytes growth and proliferation rates
PR:INSTITUTE                     	University of Michigan
PR:DEPARTMENT                    	Oral & Maxillofacial Surgery
PR:LABORATORY                    	Feinberg Lab
PR:LAST_NAME                     	Feinberg
PR:FIRST_NAME                    	Stephen
PR:ADDRESS                       	Ann Arbor, MI
PR:EMAIL                         	sefein@umich.edu
PR:PHONE                         	734-763-5963
#STUDY
ST:STUDY_TITLE                   	Human oral keratinocytes growth and proliferation based on culture medium volume
ST:STUDY_TYPE                    	MS analysis
ST:STUDY_SUMMARY                 	We seeded cells at density of 500k/T75 and cultured them at two different medium
ST:STUDY_SUMMARY                 	volume, one at 30ml, the other at 15ml. Culture medium is composed of 1x EDGS
ST:STUDY_SUMMARY                 	and 0.06mM calcium. We changed medium every day for 30ml culture, and every two
ST:STUDY_SUMMARY                 	days for 15ml culture. We collected spent medium when we changed medium. The
ST:STUDY_SUMMARY                 	collected spent medium was filtered through low protein binding 0.22um pore size
ST:STUDY_SUMMARY                 	filter and then stored at -80 degree C. For OA and SMT, spent medium was
ST:STUDY_SUMMARY                 	collected on the same day of D5 and D9 after cell seeding as marked on the
ST:STUDY_SUMMARY                 	tubes. For GK samples, 15ml and 30ml cultures were collected when cells reached
ST:STUDY_SUMMARY                 	at around 90% confluence, that is D5 for 15ml and D6 for 30 ml culture. The
ST:STUDY_SUMMARY                 	numbers 151, 152 were duplicated cell cultures in two T75s, same for 301 and
ST:STUDY_SUMMARY                 	302. One major differences among GK, OA, and SMT is GK was from frozen cells; OA
ST:STUDY_SUMMARY                 	and SMT were fresh cells that were never frozen. Blank15 and Blank30 were
ST:STUDY_SUMMARY                 	complete medium without cells incubating in incubator for two days for Blank15
ST:STUDY_SUMMARY                 	and one day for Blank30. Medium was collected in the same manner as others.
ST:INSTITUTE                     	University of Michigan
ST:DEPARTMENT                    	Biomedical Research Core Facilities
ST:LABORATORY                    	Metabolomics core
ST:LAST_NAME                     	Kachman
ST:FIRST_NAME                    	Maureen
ST:ADDRESS                       	6300 Brehm Tower, 1000 Wall Street, Ann Arbor, MI 48105-5714
ST:EMAIL                         	mkachman@med.umich.edu
ST:PHONE                         	(734) 232-8175
ST:NUM_GROUPS                    	10
ST:TOTAL_SUBJECTS                	5
#SUBJECT
SU:SUBJECT_TYPE                  	Human
SU:SUBJECT_SPECIES               	Homo sapiens
SU:TAXONOMY_ID                   	9606
#SUBJECT_SAMPLE_FACTORS:         	SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Additional sample data
SUBJECT_SAMPLE_FACTORS           	SU0003722	S00014307	Day:5 days | Line:GK | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003722	S00014308	Day:5 days | Line:GK | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003722	S00014309	Day:6 days | Line:GK | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003722	S00014310	Day:6 days | Line:GK | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003723	S00014311	Day:5 days | Line:OA | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003723	S00014312	Day:9 days | Line:OA | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003723	S00014313	Day:5 days | Line:OA | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003723	S00014314	Day:9 days | Line:OA | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003724	S00014315	Day:5 days | Line:SMT | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003724	S00014316	Day:9 days | Line:SMT | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003724	S00014317	Day:5 days | Line:SMT | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003724	S00014318	Day:9 days | Line:SMT | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU0003725	S00014319	Day:2 days | Line:Blank | Volume:15ml	
SUBJECT_SAMPLE_FACTORS           	SU0003725	S00014320	Day:2 days | Line:Blank | Volume:30ml	
SUBJECT_SAMPLE_FACTORS           	SU9999996	S00020128	Day:- | Line:- | Volume:-	
#COLLECTION
CO:COLLECTION_SUMMARY            	-
#TREATMENT
TR:TREATMENT_SUMMARY             	-
#SAMPLEPREP
SP:SAMPLEPREP_SUMMARY            	-
SP:SAMPLEPREP_PROTOCOL_FILENAME  	A003 - Untargeted Metabolomics.pdf
#CHROMATOGRAPHY
CH:CHROMATOGRAPHY_TYPE           	Reversed phase
CH:INSTRUMENT_NAME               	Agilent
CH:COLUMN_NAME                   	Waters Acquity HSS T3 (50 x 2.1mm, 1.8um)
#ANALYSIS
AN:ANALYSIS_TYPE                 	MS
AN:ANALYSIS_PROTOCOL_FILE        	A003 - Untargeted Metabolomics.pdf
#MS
MS:MS_COMMENTS                   	-
MS:INSTRUMENT_NAME               	Agilent 6530 QTOF
MS:INSTRUMENT_TYPE               	QTOF
MS:MS_TYPE                       	ESI
MS:ION_MODE                      	NEGATIVE
#MS_METABOLITE_DATA
MS_METABOLITE_DATA:UNITS         	peak area
MS_METABOLITE_DATA_START
Samples	S00014307	S00014308	S00014309	S00014310	S00014311	S00014312	S00014313	S00014314	S00014315	S00014316	S00014317	S00014318	S00014319	S00014320
Factors	Day:5 days | Line:GK | Volume:15ml	Day:5 days | Line:GK | Volume:15ml	Day:6 days | Line:GK | Volume:30ml	Day:6 days | Line:GK | Volume:30ml	Day:5 days | Line:OA | Volume:15ml	Day:9 days | Line:OA | Volume:15ml	Day:5 days | Line:OA | Volume:30ml	Day:9 days | Line:OA | Volume:30ml	Day:5 days | Line:SMT | Volume:15ml	Day:9 days | Line:SMT | Volume:15ml	Day:5 days | Line:SMT | Volume:30ml	Day:9 days | Line:SMT | Volume:30ml	Day:2 days | Line:Blank | Volume:15ml	Day:2 days | Line:Blank | Volume:30ml
3-HYDROXY-3-METHYL-GLUTARIC ACID	96569	94464		1007		109982	1684			87248			1	
3-INDOLEACETIC ACID	37965	36775	45382	41381	26230	13864	22645	20284	35163	17119	33653	25737	4811	
4-METHYL-2-OXOPENTANOATE	1102856	938236	1252565	1098589	893444	1164019	560450	1265825	1419147	780241	729913	1190012	1	
5-OXOPROLINE	34000000	33400000	35000000	33800000	35200000	29400000	33700000	35400000	35600000	30000000	33100000	29200000	30000000	22800000
5?-DEOXY-5?-(METHYLTHIO)ADENOSINE	300116	349114	242770	223487	275933	187735	145717	384808	241378	194394	132044	246277	1	
ADENINE	4432338	4271630	5341802	5191583	4797486	3603654	4858353	5136602	4912430	3841044	4849092	4388055	4590274	3726021
CITRAMALIC ACID	140058	123573	149154	132462	83953	67372	81527	110031	100630	72229	91330	64107	65414	18907
CITRIC ACID	915967	1035145	382886	301915	179465	2072210	22372	745169	357931	1332302	107343	427336	5621	23928
FOLIC ACID	37285	34939	36878	35339	33087	29945	30265	44473	36113	32405	33154	31450	25150	16777
FRUCTOSE (M-H)	502850	379687	1992626	2105967	2081242	151444	2713072	926251	1588196	135519	2644573	1481969	3240435	3247787
GLYCERIC ACID	1	1	4757	1699			1	5339			2900		5461	
HYPOXANTHINE	180809	211365	104537	66592	14791	215592	20092	75393	76226	162457		84546	1	
ISOLEUCINE	95846	85802	130752	133998	124982	29976	138415	129641	113894	74458	140357	89255	139261	83579
L-NORLEUCINE	50051	45721	90333	133998	78881	29981	89678	129641	71009	35389	94890	55927	101145	62633
N-ACETYL-DL-GLUTAMIC ACID	477873	472933	185159	182027	358827	527373	193577	447567	414822	320222	179714	191505	15077	13089
N-ACETYL-L-ALANINE	1	56170					1			72768			1	
N-ACETYLGALACTOSAMINE (M-H)	1	71929	14994		27336		10595	35859	29110	41361	9342		1	
N-ACETYLGLYCINE	4638	2850	2867	3403			1	2199	2465		2924	2822	1891	
N-METHYL-D-ASPARTIC ACID	1	1	39783		29783		1059	53074	51806	71081	33663		8273	7920
PANTOTHENIC ACID	90306	82982	95166	89088	82948	74071	77074	115402	90511	76735	80479	74918	62371	41268
PYRUVIC ACID	276317	258546	208369	195039	179629	314628	155233	221375	235519	267810	167888	212146	34615	58787
SUCCINATE	53385	55221	23785	19813	14965	81663	13368	36714	26536	60558	14275	24422	5976	5024
THYMIDINE	1	3350	10135		61732		157851	3591	9638		115961		195365	137341
URIC ACID	1	1					1			496979			1	
URIDINE (M-H)	139185	137681	184215	173538	120159	169142	119786	175857	122215	138661	142388	128960	19748	18659
XANTHINE	420005	447912	232063	178327	49575	627774	18102	347103	186903	549225	95429	294395	1280	
MS_METABOLITE_DATA_END
#METABOLITES
METABOLITES_START
metabolite_name	moverz_quant	ri	ri_type	pubchem_id	inchi_key	kegg_id	other_id	other_id_type
3-HYDROXY-3-METHYL-GLUTARIC ACID	162.0522	1.574		1662
3-INDOLEACETIC ACID	175.0628	6.841		802
4-METHYL-2-OXOPENTANOATE	130.0631	4.845		70
5-OXOPROLINE	129.0427	1.171		7405
5?-DEOXY-5?-(METHYLTHIO)ADENOSINE	297.089	4.477		439176
ADENINE	135.0545	0.869		190
CITRAMALIC ACID	148.0368	1.396		441696
CITRIC ACID	192.0271	1.003		311
FOLIC ACID	441.1394	5.825		6037
FRUCTOSE (M-H)	180.0635	0.66		5984
GLYCERIC ACID	106.0269	0.806		439194
HYPOXANTHINE	136.0378	1.104		790
ISOLEUCINE	131.0941	1.493		6306
L-NORLEUCINE	131.0944	1.579		21236
N-ACETYL-DL-GLUTAMIC ACID	189.0635	1.286		185
N-ACETYL-L-ALANINE	131.0574	1.49		88064
N-ACETYLGALACTOSAMINE (M-H)	221.0895	0.695		35717
N-ACETYLGLYCINE	117.0419	1.142		1097
N-METHYL-D-ASPARTIC ACID	147.0529	0.792		4376
PANTOTHENIC ACID	219.1105	3.286		6613
PYRUVIC ACID	88.0166	0.972		1060
SUCCINATE	118.0267	1.301		1110
THYMIDINE	242.0903	2.738		5789
URIC ACID	168.0276	0.994		1175
URIDINE (M-H)	244.0696	1.324		6029
XANTHINE	152.0334	1.266		1188
METABOLITES_END
#END