{
"METABOLOMICS WORKBENCH":{"STUDY_ID":"ST002077","ANALYSIS_ID":"AN003386","VERSION":"1","CREATED_ON":"02-08-2024"},

"PROJECT":{"PROJECT_TITLE":"LLNL microBiospheres SFA","PROJECT_SUMMARY":"Algal and plant systems have the unrivaled advantage of converting solar energy and CO2 into useful organic molecules. Their growth and efficiency are largely shaped by the microbial communities in and around them. The microbiospheres Biospheres SFA seeks to understand phototroph-heterotroph interactions that shape productivity, robustness, the balance of resource fluxes, and the functionality of the surrounding microbiome.","INSTITUTE":"Lawrence Livermore National Laboratory","LAST_NAME":"Brisson","FIRST_NAME":"Vanessa","ADDRESS":"7000 East Ave, Livermore, CA, 94550, USA","EMAIL":"brisson2@llnl.gov","PHONE":"5107177560","DOI":"http://dx.doi.org/10.21228/M8GH6P"},

"STUDY":{"STUDY_TITLE":"Dynamic Phaeodactylum tricornutum exometabolites","STUDY_SUMMARY":"Algal bacterial interactions in phycosphere microbial communities have important implications for the stability and productivity of algal biofuel systems, and algal metabolites are important mediators of those interactions. We characterized exometabolites and cell associated metabolites from the model diatom Phaeodactylum tricornutum across different growth stages.","INSTITUTE":"Lawrence Livermore National Laboratory","LAST_NAME":"Brisson","FIRST_NAME":"Vanessa","ADDRESS":"7000 East Ave, Livermore, CA, 94550, USA","EMAIL":"brisson2@llnl.gov","PHONE":"5107177560","SUBMIT_DATE":"2022-02-02"},

"SUBJECT":{"SUBJECT_TYPE":"Other organism","SUBJECT_SPECIES":"Phaeodactylum tricornutum"},
"SUBJECT_SAMPLE_FACTORS":[
{
"Subject ID":"-",
"Sample ID":"1_extr-ctrl--extr-ctrl-_1",
"Factors":{"Type":"extraction control","Time Point":"extraction control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_1_extr-ctrl--extr-ctrl-_1_IR01_NA_082.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_1_extr-ctrl--extr-ctrl-_1_IR02_NA_083.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"2_extr-ctrl--extr-ctrl-_2",
"Factors":{"Type":"extraction control","Time Point":"extraction control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_2_extr-ctrl--extr-ctrl-_2_IR01_NA_175.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_2_extr-ctrl--extr-ctrl-_2_IR02_NA_176.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"3_extr-ctrl--extr-ctrl-_3",
"Factors":{"Type":"extraction control","Time Point":"extraction control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_3_extr-ctrl--extr-ctrl-_3_NA_010.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_3_extr-ctrl--extr-ctrl-_3_NA_011.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"4_extr-ctrl--extr-ctrl-_4",
"Factors":{"Type":"extraction control","Time Point":"extraction control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_4_extr-ctrl--extr-ctrl-_4_IR01_NA_055.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_4_extr-ctrl--extr-ctrl-_4_IR02_NA_056.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"10_exudate-0d_2",
"Factors":{"Type":"exudate","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_10_exudate-0d_2_IR01_NA_085.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_10_exudate-0d_2_IR02_NA_086.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"11_exudate-0d_3",
"Factors":{"Type":"exudate","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_11_exudate-0d_3_IR01_NA_091.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_11_exudate-0d_3_IR02_NA_092.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"12_exudate-0d_4",
"Factors":{"Type":"exudate","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_12_exudate-0d_4_NA_016.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_12_exudate-0d_4_NA_017.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"9_exudate-0d_1",
"Factors":{"Type":"exudate","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_9_exudate-0d_1_IR01_NA_121.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_9_exudate-0d_1_IR02_NA_122.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"25_exudate-12d_1",
"Factors":{"Type":"exudate","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_25_exudate-12d_1_IR01_NA_109.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_25_exudate-12d_1_IR02_NA_110.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"26_exudate-12d_2",
"Factors":{"Type":"exudate","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_26_exudate-12d_2_IR01_NA_067.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_26_exudate-12d_2_IR02_NA_068.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"27_exudate-12d_3",
"Factors":{"Type":"exudate","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_27_exudate-12d_3_NA_025.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_27_exudate-12d_3_NA_026.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"28_exudate-12d_4",
"Factors":{"Type":"exudate","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_28_exudate-12d_4_IR01_NA_046.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_28_exudate-12d_4_IR02_NA_047.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"13_exudate-3d_1",
"Factors":{"Type":"exudate","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_13_exudate-3d_1_IR01_NA_103.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_13_exudate-3d_1_IR02_NA_104.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"14_exudate-3d_2",
"Factors":{"Type":"exudate","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_14_exudate-3d_2_IR01_NA_160.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_14_exudate-3d_2_IR02_NA_161.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"15_exudate-3d_3",
"Factors":{"Type":"exudate","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_15_exudate-3d_3_IR01_NA_178.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_15_exudate-3d_3_IR02_NA_179.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"16_exudate-3d_4",
"Factors":{"Type":"exudate","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_16_exudate-3d_4_IR01_NA_034.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_16_exudate-3d_4_IR02_NA_035.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"17_exudate-6d_1",
"Factors":{"Type":"exudate","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_17_exudate-6d_1_IR01_NA_166.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_17_exudate-6d_1_IR02_NA_167.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"18_exudate-6d_2",
"Factors":{"Type":"exudate","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_18_exudate-6d_2_IR01_NA_112.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_18_exudate-6d_2_IR02_NA_113.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"19_exudate-6d_3",
"Factors":{"Type":"exudate","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_19_exudate-6d_3_IR01_NA_070.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_19_exudate-6d_3_IR02_NA_071.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"20_exudate-6d_4",
"Factors":{"Type":"exudate","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_20_exudate-6d_4_IR01_NA_127.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_20_exudate-6d_4_IR02_NA_128.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"21_exudate-9d_1",
"Factors":{"Type":"exudate","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_21_exudate-9d_1_NA_019.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_21_exudate-9d_1_NA_020.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"22_exudate-9d_2",
"Factors":{"Type":"exudate","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_22_exudate-9d_2_IR01_NA_076.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_22_exudate-9d_2_IR02_NA_077.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"23_exudate-9d_3",
"Factors":{"Type":"exudate","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_23_exudate-9d_3_NA_028.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_23_exudate-9d_3_IR02_NA_029.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"24_exudate-9d_4",
"Factors":{"Type":"exudate","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_24_exudate-9d_4_IR01_NA_145.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_24_exudate-9d_4_IR02_NA_146.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"5_exudate-med-ctrl-_1",
"Factors":{"Type":"exudate","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_5_exudate-med-ctrl-_1_IR01_NA_148.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_5_exudate-med-ctrl-_1_IR02_NA_149.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"6_exudate-med-ctrl-_2",
"Factors":{"Type":"exudate","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_6_exudate-med-ctrl-_2_IR01_NA_151.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_6_exudate-med-ctrl-_2_IR02_NA_152.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"7_exudate-med-ctrl-_3",
"Factors":{"Type":"exudate","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_7_exudate-med-ctrl-_3_IR01_NA_031.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_7_exudate-med-ctrl-_3_IR02_NA_032.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"8_exudate-med-ctrl-_4",
"Factors":{"Type":"exudate","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_8_exudate-med-ctrl-_4_IR01_NA_064.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_8_exudate-med-ctrl-_4_IR02_NA_065.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"33_pellet-0d_1",
"Factors":{"Type":"pellet","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_33_pellet-0d_1_IR01_NA_088.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_33_pellet-0d_1_IR02_NA_089.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"34_pellet-0d_2",
"Factors":{"Type":"pellet","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_34_pellet-0d_2_IR01_NA_133.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_34_pellet-0d_2_IR02_NA_134.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"35_pellet-0d_3",
"Factors":{"Type":"pellet","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_35_pellet-0d_3_IR01_NA_118.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_35_pellet-0d_3_IR02_NA_119.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"36_pellet-0d_4",
"Factors":{"Type":"pellet","Time Point":"0 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_36_pellet-0d_4_NA_022.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_36_pellet-0d_4_NA_023.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"49_pellet-12d_1",
"Factors":{"Type":"pellet","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_49_pellet-12d_1_IR01_NA_142.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_49_pellet-12d_1_IR02_NA_143.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"50_pellet-12d_2",
"Factors":{"Type":"pellet","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_50_pellet-12d_2_IR01_NA_130.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_50_pellet-12d_2_IR02_NA_131.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"51_pellet-12d_3",
"Factors":{"Type":"pellet","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_51_pellet-12d_3_IR01_NA_058.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_51_pellet-12d_3_IR02_NA_059.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"52_pellet-12d_4",
"Factors":{"Type":"pellet","Time Point":"12 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_52_pellet-12d_4_IR01_NA_163.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_52_pellet-12d_4_IR02_NA_164.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"37_pellet-3d_1",
"Factors":{"Type":"pellet","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_37_pellet-3d_1_IR01_NA_097.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_37_pellet-3d_1_IR02_NA_098.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"38_pellet-3d_2",
"Factors":{"Type":"pellet","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_38_pellet-3d_2_IR01_NA_037.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_38_pellet-3d_2_IR02_NA_038.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"39_pellet-3d_3",
"Factors":{"Type":"pellet","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_39_pellet-3d_3_IR01_NA_115.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_39_pellet-3d_3_IR02_NA_116.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"40_pellet-3d_4",
"Factors":{"Type":"pellet","Time Point":"3 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_40_pellet-3d_4_IR01_NA_154.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_40_pellet-3d_4_IR02_NA_155.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"41_pellet-6d_1",
"Factors":{"Type":"pellet","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_41_pellet-6d_1_IR01_NA_052.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_41_pellet-6d_1_IR02_NA_053.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"42_pellet-6d_2",
"Factors":{"Type":"pellet","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_42_pellet-6d_2_IR01_NA_079.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_42_pellet-6d_2_IR02_NA_080.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"43_pellet-6d_3",
"Factors":{"Type":"pellet","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_43_pellet-6d_3_IR01_NA_136.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_43_pellet-6d_3_IR02_NA_137.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"44_pellet-6d_4",
"Factors":{"Type":"pellet","Time Point":"6 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_44_pellet-6d_4_IR01_NA_043.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_44_pellet-6d_4_IR02_NA_044.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"45_pellet-9d_1",
"Factors":{"Type":"pellet","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_45_pellet-9d_1_IR01_NA_157.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_45_pellet-9d_1_IR02_NA_158.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"46_pellet-9d_2",
"Factors":{"Type":"pellet","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_46_pellet-9d_2_IR01_NA_094.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_46_pellet-9d_2_IR02_NA_095.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"47_pellet-9d_3",
"Factors":{"Type":"pellet","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_47_pellet-9d_3_IR01_NA_061.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_47_pellet-9d_3_IR02_NA_062.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"48_pellet-9d_4",
"Factors":{"Type":"pellet","Time Point":"9 days"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_48_pellet-9d_4_IR01_NA_049.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_48_pellet-9d_4_IR02_NA_050.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"29_pellet-med-ctrl-_1",
"Factors":{"Type":"pellet","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_29_pellet-med-ctrl-_1_IR01_NA_124.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_29_pellet-med-ctrl-_1_IR02_NA_125.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"30_pellet-med-ctrl-_2",
"Factors":{"Type":"pellet","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_30_pellet-med-ctrl-_2_NA_013.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_30_pellet-med-ctrl-_2_NA_014.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"31_pellet-med-ctrl-_3",
"Factors":{"Type":"pellet","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_31_pellet-med-ctrl-_3_IR01_NA_169.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_31_pellet-med-ctrl-_3_IR02_NA_170.mzML"}
},
{
"Subject ID":"-",
"Sample ID":"32_pellet-med-ctrl-_4",
"Factors":{"Type":"pellet","Time Point":"medium control"},
"Additional sample data":{"RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_POS_MSMS-v2_32_pellet-med-ctrl-_4_IR01_NA_100.mzML","RAW_FILE_NAME":"20190429_JJ_VB_BioSFA_Pttime_1_QE144_Ag68377-924_USHXG01160_NEG_MSMS-v2_32_pellet-med-ctrl-_4_IR02_NA_101.mzML"}
}
],
"COLLECTION":{"COLLECTION_SUMMARY":"Spent medium and cell pellets were collected from axenic Phaeodactylum tricornutum cultures at 5 time points: 0, 3, 6, 9, and 12 days after inoculation. Cultures from four replicate flasks were destructively harvested at each collection time point.","SAMPLE_TYPE":"Algae"},

"TREATMENT":{"TREATMENT_SUMMARY":"Treatments were different time points during algal growth: 0, 3, 6, 9, and 12 days after inoculation."},

"SAMPLEPREP":{"SAMPLEPREP_SUMMARY":"Cell pellets were disrupted for metabolite extraction by resuspension in sterile water, lyophilization, and grinding by vortexing with a sterilized steel ball. Disrupted pellets were resuspended in 50 mL sterile water, filtered, and frozen in the same manner as spent medium. Spent medium and cell pellet samples were extracted by solid phase extraction using Agilent Bond Elut PPL columns."},

"CHROMATOGRAPHY":{"INSTRUMENT_NAME":"Agilent 1290 Infinity","COLUMN_NAME":"Agilent InfinityLab Poroshell 120 HILIC-Z (150 x 2.1mm,2.7um)","CHROMATOGRAPHY_TYPE":"HILIC"},

"ANALYSIS":{"ANALYSIS_TYPE":"MS"},

"MS":{"INSTRUMENT_NAME":"Thermo Q Exactive Orbitrap","INSTRUMENT_TYPE":"Orbitrap","MS_TYPE":"ESI","MS_COMMENTS":"Metabolite identifications w ere obtained using Metabolite Atlas (https://github.com/biorack/metatlas) to identify features with m/z , retention time, and fragmentation spectra that matched to a library of analytical standards run in our lab under the same LC-MS/MS analysis conditions.","ION_MODE":"NEGATIVE"},

"MS_METABOLITE_DATA":{
"Units":"metabolite quantification (peak height or area as denoted in metaboilite table)",

"Data":[{"Metabolite":"2-hydroxyphenylacetic acid","1_extr-ctrl--extr-ctrl-_1":"466105.8100","2_extr-ctrl--extr-ctrl-_2":"148825.3100","3_extr-ctrl--extr-ctrl-_3":"686598.1300","4_extr-ctrl--extr-ctrl-_4":"673267.2500","10_exudate-0d_2":"1584445.6300","11_exudate-0d_3":"218281.8600","12_exudate-0d_4":"1862579.6300","9_exudate-0d_1":"1164887.2500","25_exudate-12d_1":"48701792.0000","26_exudate-12d_2":"53755280.0000","27_exudate-12d_3":"51415100.0000","28_exudate-12d_4":"48912196.0000","13_exudate-3d_1":"2264777.5000","14_exudate-3d_2":"1405906.8800","15_exudate-3d_3":"1427549.1300","16_exudate-3d_4":"2362982.5000","17_exudate-6d_1":"2865528.5000","18_exudate-6d_2":"2336657.2500","19_exudate-6d_3":"3066217.5000","20_exudate-6d_4":"3271088.7500","21_exudate-9d_1":"11112846.0000","22_exudate-9d_2":"11196985.0000","23_exudate-9d_3":"14469986.0000","24_exudate-9d_4":"12428801.0000","5_exudate-med-ctrl-_1":"1113950.0000","6_exudate-med-ctrl-_2":"1824819.3800","7_exudate-med-ctrl-_3":"339909.3400","8_exudate-med-ctrl-_4":"1511736.7500","33_pellet-0d_1":"523024.0900","34_pellet-0d_2":"301119.9700","35_pellet-0d_3":"334848.8800","36_pellet-0d_4":"334414.4100","49_pellet-12d_1":"2427836.0000","50_pellet-12d_2":"2937871.0000","51_pellet-12d_3":"5524693.5000","52_pellet-12d_4":"2500975.0000","37_pellet-3d_1":"480553.0300","38_pellet-3d_2":"413848.5300","39_pellet-3d_3":"433338.0000","40_pellet-3d_4":"506407.7200","41_pellet-6d_1":"694579.1900","42_pellet-6d_2":"1008117.8100","43_pellet-6d_3":"833145.8800","44_pellet-6d_4":"761282.4400","45_pellet-9d_1":"1150855.3800","46_pellet-9d_2":"1428847.8800","47_pellet-9d_3":"1321258.3800","48_pellet-9d_4":"1397027.5000","29_pellet-med-ctrl-_1":"350162.8400","30_pellet-med-ctrl-_2":"677024.3100","31_pellet-med-ctrl-_3":"543626.3800","32_pellet-med-ctrl-_4":"293576.0600"},{"Metabolite":"2-methylmaleic acid","1_extr-ctrl--extr-ctrl-_1":"1785636.3800","2_extr-ctrl--extr-ctrl-_2":"205900.5300","3_extr-ctrl--extr-ctrl-_3":"1739480.5000","4_extr-ctrl--extr-ctrl-_4":"1819526.0000","10_exudate-0d_2":"2539378.5000","11_exudate-0d_3":"185073.0800","12_exudate-0d_4":"2503678.5000","9_exudate-0d_1":"2047213.8800","25_exudate-12d_1":"3725279.5000","26_exudate-12d_2":"9164709.0000","27_exudate-12d_3":"7548247.5000","28_exudate-12d_4":"12903401.0000","13_exudate-3d_1":"2648127.5000","14_exudate-3d_2":"2120796.0000","15_exudate-3d_3":"1821357.8800","16_exudate-3d_4":"2868817.7500","17_exudate-6d_1":"2105093.7500","18_exudate-6d_2":"3216579.5000","19_exudate-6d_3":"2959703.5000","20_exudate-6d_4":"2302132.0000","21_exudate-9d_1":"7023957.0000","22_exudate-9d_2":"8154217.0000","23_exudate-9d_3":"2141857.5000","24_exudate-9d_4":"1578302.6300","5_exudate-med-ctrl-_1":"2101271.7500","6_exudate-med-ctrl-_2":"2772313.0000","7_exudate-med-ctrl-_3":"142241.8800","8_exudate-med-ctrl-_4":"2708758.5000","33_pellet-0d_1":"3200804.7500","34_pellet-0d_2":"1366366.1300","35_pellet-0d_3":"1712314.7500","36_pellet-0d_4":"1587231.3800","49_pellet-12d_1":"1371267.2500","50_pellet-12d_2":"1426786.3800","51_pellet-12d_3":"2295410.0000","52_pellet-12d_4":"1602538.6300","37_pellet-3d_1":"3648336.7500","38_pellet-3d_2":"3363441.7500","39_pellet-3d_3":"3232958.0000","40_pellet-3d_4":"3493345.7500","41_pellet-6d_1":"2671471.5000","42_pellet-6d_2":"2474533.5000","43_pellet-6d_3":"4335353.0000","44_pellet-6d_4":"3506451.0000","45_pellet-9d_1":"1532113.8800","46_pellet-9d_2":"1117791.0000","47_pellet-9d_3":"1961410.2500","48_pellet-9d_4":"2336115.0000","29_pellet-med-ctrl-_1":"1211891.1300","30_pellet-med-ctrl-_2":"1750178.3800","31_pellet-med-ctrl-_3":"2225286.2500","32_pellet-med-ctrl-_4":"1311727.1300"},{"Metabolite":"2-oxovaleric acid","1_extr-ctrl--extr-ctrl-_1":"92804.1300","2_extr-ctrl--extr-ctrl-_2":"66901.5200","3_extr-ctrl--extr-ctrl-_3":"85413.7800","4_extr-ctrl--extr-ctrl-_4":"97036.1600","10_exudate-0d_2":"105255.4100","11_exudate-0d_3":"97413.6800","12_exudate-0d_4":"117030.5600","9_exudate-0d_1":"88573.0500","25_exudate-12d_1":"43698496.0000","26_exudate-12d_2":"37346164.0000","27_exudate-12d_3":"46385952.0000","28_exudate-12d_4":"32717944.0000","13_exudate-3d_1":"160251.1700","14_exudate-3d_2":"92456.5400","15_exudate-3d_3":"81652.0000","16_exudate-3d_4":"224078.2500","17_exudate-6d_1":"205942.3900","18_exudate-6d_2":"432060.5900","19_exudate-6d_3":"433227.5300","20_exudate-6d_4":"3221719.7500","21_exudate-9d_1":"11581435.0000","22_exudate-9d_2":"9634048.0000","23_exudate-9d_3":"16362419.0000","24_exudate-9d_4":"3334244.0000","5_exudate-med-ctrl-_1":"195440.5500","6_exudate-med-ctrl-_2":"603825.5600","7_exudate-med-ctrl-_3":"110030.9000","8_exudate-med-ctrl-_4":"115670.0900","33_pellet-0d_1":"92130.1600","34_pellet-0d_2":"58535.1000","35_pellet-0d_3":"75320.6600","36_pellet-0d_4":"98413.4300","49_pellet-12d_1":"3396321.0000","50_pellet-12d_2":"3999020.5000","51_pellet-12d_3":"611679.8100","52_pellet-12d_4":"2513640.0000","37_pellet-3d_1":"67622.8400","38_pellet-3d_2":"91081.8400","39_pellet-3d_3":"105050.3800","40_pellet-3d_4":"78423.7600","41_pellet-6d_1":"81838.0900","42_pellet-6d_2":"130614.5900","43_pellet-6d_3":"202711.7300","44_pellet-6d_4":"219772.6700","45_pellet-9d_1":"1825635.3800","46_pellet-9d_2":"930862.5000","47_pellet-9d_3":"1621847.7500","48_pellet-9d_4":"2350737.7500","29_pellet-med-ctrl-_1":"74745.5900","30_pellet-med-ctrl-_2":"163409.9800","31_pellet-med-ctrl-_3":"69994.9300","32_pellet-med-ctrl-_4":"72357.8700"},{"Metabolite":"3-(4-hydroxyphenyl)lactic acid","1_extr-ctrl--extr-ctrl-_1":"35876.5900","2_extr-ctrl--extr-ctrl-_2":"29134.6600","3_extr-ctrl--extr-ctrl-_3":"86659.1500","4_extr-ctrl--extr-ctrl-_4":"254362.2700","10_exudate-0d_2":"115031.8500","11_exudate-0d_3":"34627.1900","12_exudate-0d_4":"141527.8800","9_exudate-0d_1":"89004.6300","25_exudate-12d_1":"15393714.0000","26_exudate-12d_2":"10952307.0000","27_exudate-12d_3":"9498560.0000","28_exudate-12d_4":"9764950.0000","13_exudate-3d_1":"165222.9800","14_exudate-3d_2":"147131.4400","15_exudate-3d_3":"171264.0500","16_exudate-3d_4":"169120.5800","17_exudate-6d_1":"626109.4400","18_exudate-6d_2":"668911.5600","19_exudate-6d_3":"677061.3800","20_exudate-6d_4":"64056.3200","21_exudate-9d_1":"3042246.0000","22_exudate-9d_2":"3594527.5000","23_exudate-9d_3":"3610382.2500","24_exudate-9d_4":"2910129.7500","5_exudate-med-ctrl-_1":"36284.7100","6_exudate-med-ctrl-_2":"41912.5000","7_exudate-med-ctrl-_3":"34927.6100","8_exudate-med-ctrl-_4":"46706.6700","33_pellet-0d_1":"33347.8600","34_pellet-0d_2":"41594.2100","35_pellet-0d_3":"79599.8900","36_pellet-0d_4":"64751.8000","49_pellet-12d_1":"39302.9400","50_pellet-12d_2":"36652.7300","51_pellet-12d_3":"58856.8500","52_pellet-12d_4":"67489.7800","37_pellet-3d_1":"48069.3800","38_pellet-3d_2":"54249.5200","39_pellet-3d_3":"81057.4800","40_pellet-3d_4":"33474.0300","41_pellet-6d_1":"167232.7500","42_pellet-6d_2":"62228.4800","43_pellet-6d_3":"58423.0800","44_pellet-6d_4":"74178.5000","45_pellet-9d_1":"42404.2700","46_pellet-9d_2":"75049.6200","47_pellet-9d_3":"58407.4100","48_pellet-9d_4":"232411.8300","29_pellet-med-ctrl-_1":"37931.7600","30_pellet-med-ctrl-_2":"70460.2500","31_pellet-med-ctrl-_3":"29209.8200","32_pellet-med-ctrl-_4":"35617.3600"},{"Metabolite":"4-hydroxy-2-quinolinecarboxylic acid","1_extr-ctrl--extr-ctrl-_1":"51439.0500","2_extr-ctrl--extr-ctrl-_2":"41165.7200","3_extr-ctrl--extr-ctrl-_3":"54541.5200","4_extr-ctrl--extr-ctrl-_4":"59619.2000","10_exudate-0d_2":"131103.5800","11_exudate-0d_3":"54848.1700","12_exudate-0d_4":"147493.6900","9_exudate-0d_1":"130925.5300","25_exudate-12d_1":"34893072.0000","26_exudate-12d_2":"42083592.0000","27_exudate-12d_3":"38111516.0000","28_exudate-12d_4":"39816280.0000","13_exudate-3d_1":"643412.7500","14_exudate-3d_2":"581762.3100","15_exudate-3d_3":"599184.0600","16_exudate-3d_4":"450422.8400","17_exudate-6d_1":"5123912.0000","18_exudate-6d_2":"5297127.0000","19_exudate-6d_3":"4944025.5000","20_exudate-6d_4":"2998144.0000","21_exudate-9d_1":"16144428.0000","22_exudate-9d_2":"18434128.0000","23_exudate-9d_3":"22560222.0000","24_exudate-9d_4":"18569872.0000","5_exudate-med-ctrl-_1":"77137.6400","6_exudate-med-ctrl-_2":"68845.7900","7_exudate-med-ctrl-_3":"2086643.1300","8_exudate-med-ctrl-_4":"65582.6000","33_pellet-0d_1":"35419.8300","34_pellet-0d_2":"37902.4500","35_pellet-0d_3":"39778.1600","36_pellet-0d_4":"47917.7900","49_pellet-12d_1":"1418407.3800","50_pellet-12d_2":"1189200.5000","51_pellet-12d_3":"3789881.7500","52_pellet-12d_4":"1067472.3800","37_pellet-3d_1":"80411.8200","38_pellet-3d_2":"50180.1400","39_pellet-3d_3":"46074.0000","40_pellet-3d_4":"69540.6900","41_pellet-6d_1":"127888.8100","42_pellet-6d_2":"94931.3900","43_pellet-6d_3":"106319.6200","44_pellet-6d_4":"97267.3800","45_pellet-9d_1":"266891.7200","46_pellet-9d_2":"379360.8800","47_pellet-9d_3":"286333.5000","48_pellet-9d_4":"400864.0000","29_pellet-med-ctrl-_1":"37635.2800","30_pellet-med-ctrl-_2":"34850.5700","31_pellet-med-ctrl-_3":"43779.4600","32_pellet-med-ctrl-_4":"73129.7400"},{"Metabolite":"4-hydroxybenzoic acid","1_extr-ctrl--extr-ctrl-_1":"578694.7500","2_extr-ctrl--extr-ctrl-_2":"272153.1300","3_extr-ctrl--extr-ctrl-_3":"719296.4400","4_extr-ctrl--extr-ctrl-_4":"562997.8800","10_exudate-0d_2":"1659466.1300","11_exudate-0d_3":"378963.0000","12_exudate-0d_4":"2920912.0000","9_exudate-0d_1":"1343865.5000","25_exudate-12d_1":"147684720.0000","26_exudate-12d_2":"147914192.0000","27_exudate-12d_3":"157728912.0000","28_exudate-12d_4":"134091960.0000","13_exudate-3d_1":"6179428.0000","14_exudate-3d_2":"7122249.0000","15_exudate-3d_3":"6115786.5000","16_exudate-3d_4":"5728746.5000","17_exudate-6d_1":"31136302.0000","18_exudate-6d_2":"31854272.0000","19_exudate-6d_3":"37678480.0000","20_exudate-6d_4":"31829232.0000","21_exudate-9d_1":"124008768.0000","22_exudate-9d_2":"134657936.0000","23_exudate-9d_3":"113040520.0000","24_exudate-9d_4":"110377376.0000","5_exudate-med-ctrl-_1":"1101251.5000","6_exudate-med-ctrl-_2":"1075868.7500","7_exudate-med-ctrl-_3":"389076.1300","8_exudate-med-ctrl-_4":"1196808.0000","33_pellet-0d_1":"549560.2500","34_pellet-0d_2":"420402.0900","35_pellet-0d_3":"504702.5300","36_pellet-0d_4":"446882.2200","49_pellet-12d_1":"3112627.0000","50_pellet-12d_2":"4116404.0000","51_pellet-12d_3":"756776.9400","52_pellet-12d_4":"7766302.5000","37_pellet-3d_1":"1369624.6300","38_pellet-3d_2":"966585.5000","39_pellet-3d_3":"875059.8800","40_pellet-3d_4":"979572.0600","41_pellet-6d_1":"1391260.8800","42_pellet-6d_2":"1120061.0000","43_pellet-6d_3":"1383470.8800","44_pellet-6d_4":"1326279.5000","45_pellet-9d_1":"1780099.6300","46_pellet-9d_2":"3465335.5000","47_pellet-9d_3":"2022477.5000","48_pellet-9d_4":"2365981.2500","29_pellet-med-ctrl-_1":"322544.5300","30_pellet-med-ctrl-_2":"559540.8800","31_pellet-med-ctrl-_3":"427002.9400","32_pellet-med-ctrl-_4":"401185.3100"},{"Metabolite":"4-pyridoxic acid","1_extr-ctrl--extr-ctrl-_1":"52949.2400","2_extr-ctrl--extr-ctrl-_2":"29642.8300","3_extr-ctrl--extr-ctrl-_3":"39853.8700","4_extr-ctrl--extr-ctrl-_4":"32454.5500","10_exudate-0d_2":"174371.2500","11_exudate-0d_3":"36720.4800","12_exudate-0d_4":"160676.1100","9_exudate-0d_1":"140971.5300","25_exudate-12d_1":"16516759.0000","26_exudate-12d_2":"11100565.0000","27_exudate-12d_3":"9609976.0000","28_exudate-12d_4":"5963966.0000","13_exudate-3d_1":"556285.3800","14_exudate-3d_2":"461566.5900","15_exudate-3d_3":"522016.8100","16_exudate-3d_4":"525722.7500","17_exudate-6d_1":"6344424.5000","18_exudate-6d_2":"6665158.0000","19_exudate-6d_3":"6168015.5000","20_exudate-6d_4":"4397328.0000","21_exudate-9d_1":"7917664.0000","22_exudate-9d_2":"10973457.0000","23_exudate-9d_3":"7531458.5000","24_exudate-9d_4":"3688769.7500","5_exudate-med-ctrl-_1":"31762.4200","6_exudate-med-ctrl-_2":"51148.8100","7_exudate-med-ctrl-_3":"37300.7100","8_exudate-med-ctrl-_4":"34517.3700","33_pellet-0d_1":"23471.6900","34_pellet-0d_2":"30230.3200","35_pellet-0d_3":"34637.4500","36_pellet-0d_4":"35092.7800","49_pellet-12d_1":"73607.1200","50_pellet-12d_2":"129337.7300","51_pellet-12d_3":"211890.5300","52_pellet-12d_4":"223829.1900","37_pellet-3d_1":"54942.2900","38_pellet-3d_2":"53489.1400","39_pellet-3d_3":"31681.0400","40_pellet-3d_4":"25939.7600","41_pellet-6d_1":"70797.6400","42_pellet-6d_2":"65118.7800","43_pellet-6d_3":"77573.9400","44_pellet-6d_4":"67698.0600","45_pellet-9d_1":"46657.7800","46_pellet-9d_2":"96009.0600","47_pellet-9d_3":"53037.0900","48_pellet-9d_4":"68582.6400","29_pellet-med-ctrl-_1":"23629.9000","30_pellet-med-ctrl-_2":"34127.8200","31_pellet-med-ctrl-_3":"55715.2900","32_pellet-med-ctrl-_4":"31107.5100"},{"Metabolite":"5-hydroxyindoleacetic acid","1_extr-ctrl--extr-ctrl-_1":"22230.1600","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"21036.2400","4_extr-ctrl--extr-ctrl-_4":"39819.9000","10_exudate-0d_2":"47641.2000","11_exudate-0d_3":"61113.1000","12_exudate-0d_4":"78349.7000","9_exudate-0d_1":"52814.1900","25_exudate-12d_1":"12145915.0000","26_exudate-12d_2":"3023155.5000","27_exudate-12d_3":"7632433.0000","28_exudate-12d_4":"199833.8300","13_exudate-3d_1":"113926.0900","14_exudate-3d_2":"61950.8800","15_exudate-3d_3":"49167.0900","16_exudate-3d_4":"51477.5900","17_exudate-6d_1":"321412.8800","18_exudate-6d_2":"577204.7500","19_exudate-6d_3":"702465.6900","20_exudate-6d_4":"156188.7000","21_exudate-9d_1":"3427053.0000","22_exudate-9d_2":"5786818.5000","23_exudate-9d_3":"6435831.5000","24_exudate-9d_4":"356105.5900","5_exudate-med-ctrl-_1":"40955.2600","6_exudate-med-ctrl-_2":"37898.5400","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"27717.8200","34_pellet-0d_2":"21027.7800","35_pellet-0d_3":"48467.3700","36_pellet-0d_4":"40353.6200","49_pellet-12d_1":"74093.1200","50_pellet-12d_2":"119944.0600","51_pellet-12d_3":"85484.2700","52_pellet-12d_4":"39155.0400","37_pellet-3d_1":"54789.4800","38_pellet-3d_2":"43590.7500","39_pellet-3d_3":"73994.7300","40_pellet-3d_4":"27625.1400","41_pellet-6d_1":"367998.2200","42_pellet-6d_2":"31561.1500","43_pellet-6d_3":"76340.9800","44_pellet-6d_4":"387738.5900","45_pellet-9d_1":"144027.1300","46_pellet-9d_2":"112692.6400","47_pellet-9d_3":"166785.8400","48_pellet-9d_4":"360015.0900","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"28126.8300","31_pellet-med-ctrl-_3":"52618.8900","32_pellet-med-ctrl-_4":"17635.0100"},{"Metabolite":"adenine","1_extr-ctrl--extr-ctrl-_1":"214385.1600","2_extr-ctrl--extr-ctrl-_2":"98540.8400","3_extr-ctrl--extr-ctrl-_3":"165945.6600","4_extr-ctrl--extr-ctrl-_4":"314301.0600","10_exudate-0d_2":"538879.4400","11_exudate-0d_3":"137757.5800","12_exudate-0d_4":"620573.8100","9_exudate-0d_1":"451742.9400","25_exudate-12d_1":"30310732.0000","26_exudate-12d_2":"106217672.0000","27_exudate-12d_3":"101916224.0000","28_exudate-12d_4":"116468368.0000","13_exudate-3d_1":"1095062.0000","14_exudate-3d_2":"835220.8100","15_exudate-3d_3":"908704.8100","16_exudate-3d_4":"1167622.1300","17_exudate-6d_1":"8717080.0000","18_exudate-6d_2":"8782035.0000","19_exudate-6d_3":"8054853.0000","20_exudate-6d_4":"7340889.5000","21_exudate-9d_1":"53216396.0000","22_exudate-9d_2":"55008108.0000","23_exudate-9d_3":"100021888.0000","24_exudate-9d_4":"113733712.0000","5_exudate-med-ctrl-_1":"183106.0900","6_exudate-med-ctrl-_2":"137275.3800","7_exudate-med-ctrl-_3":"135349.4500","8_exudate-med-ctrl-_4":"170488.5900","33_pellet-0d_1":"173200.0300","34_pellet-0d_2":"139854.0300","35_pellet-0d_3":"203213.5800","36_pellet-0d_4":"160026.9700","49_pellet-12d_1":"100787816.0000","50_pellet-12d_2":"88438152.0000","51_pellet-12d_3":"710258240.0000","52_pellet-12d_4":"64718056.0000","37_pellet-3d_1":"482232.0300","38_pellet-3d_2":"403294.3800","39_pellet-3d_3":"353542.3100","40_pellet-3d_4":"367563.8400","41_pellet-6d_1":"26723032.0000","42_pellet-6d_2":"6888552.0000","43_pellet-6d_3":"7786933.0000","44_pellet-6d_4":"7729796.5000","45_pellet-9d_1":"174314544.0000","46_pellet-9d_2":"95629128.0000","47_pellet-9d_3":"157241040.0000","48_pellet-9d_4":"153467904.0000","29_pellet-med-ctrl-_1":"98088.3600","30_pellet-med-ctrl-_2":"165532.8900","31_pellet-med-ctrl-_3":"194640.8300","32_pellet-med-ctrl-_4":"127809.8100"},{"Metabolite":"adenosine 5^-monophosphoric acid","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"","11_exudate-0d_3":"","12_exudate-0d_4":"","9_exudate-0d_1":"","25_exudate-12d_1":"","26_exudate-12d_2":"","27_exudate-12d_3":"","28_exudate-12d_4":"","13_exudate-3d_1":"","14_exudate-3d_2":"","15_exudate-3d_3":"","16_exudate-3d_4":"","17_exudate-6d_1":"","18_exudate-6d_2":"","19_exudate-6d_3":"","20_exudate-6d_4":"","21_exudate-9d_1":"","22_exudate-9d_2":"","23_exudate-9d_3":"","24_exudate-9d_4":"","5_exudate-med-ctrl-_1":"","6_exudate-med-ctrl-_2":"","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"","34_pellet-0d_2":"","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"1125316.0000","50_pellet-12d_2":"897331.1900","51_pellet-12d_3":"105672.4000","52_pellet-12d_4":"643804.1900","37_pellet-3d_1":"","38_pellet-3d_2":"","39_pellet-3d_3":"","40_pellet-3d_4":"","41_pellet-6d_1":"359541.5900","42_pellet-6d_2":"100858.5100","43_pellet-6d_3":"124516.3000","44_pellet-6d_4":"149514.6600","45_pellet-9d_1":"2515946.2500","46_pellet-9d_2":"1537881.5000","47_pellet-9d_3":"2093714.7500","48_pellet-9d_4":"1859695.8800","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"","32_pellet-med-ctrl-_4":""},{"Metabolite":"carnosine","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"9777.8200","4_extr-ctrl--extr-ctrl-_4":"6938.9200","10_exudate-0d_2":"","11_exudate-0d_3":"8905.5500","12_exudate-0d_4":"","9_exudate-0d_1":"14536.4500","25_exudate-12d_1":"6511.4700","26_exudate-12d_2":"7984.3000","27_exudate-12d_3":"17604.4300","28_exudate-12d_4":"14296.2500","13_exudate-3d_1":"5599.6800","14_exudate-3d_2":"8589.1800","15_exudate-3d_3":"15191.8100","16_exudate-3d_4":"","17_exudate-6d_1":"6949.9900","18_exudate-6d_2":"","19_exudate-6d_3":"","20_exudate-6d_4":"","21_exudate-9d_1":"","22_exudate-9d_2":"5446.7700","23_exudate-9d_3":"10795.9100","24_exudate-9d_4":"7857.5900","5_exudate-med-ctrl-_1":"6913.6400","6_exudate-med-ctrl-_2":"6145.6800","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"","34_pellet-0d_2":"8888.2700","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"188159.1900","50_pellet-12d_2":"156330.4700","51_pellet-12d_3":"181474.8900","52_pellet-12d_4":"91738.8000","37_pellet-3d_1":"","38_pellet-3d_2":"","39_pellet-3d_3":"","40_pellet-3d_4":"","41_pellet-6d_1":"16836.4700","42_pellet-6d_2":"","43_pellet-6d_3":"","44_pellet-6d_4":"","45_pellet-9d_1":"118666.1000","46_pellet-9d_2":"32107.8100","47_pellet-9d_3":"88933.4100","48_pellet-9d_4":"122004.9400","29_pellet-med-ctrl-_1":"9591.5100","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"5978.2600","32_pellet-med-ctrl-_4":""},{"Metabolite":"dethiobiotin","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"75528.2400","11_exudate-0d_3":"22699.5000","12_exudate-0d_4":"109459.8200","9_exudate-0d_1":"74684.9100","25_exudate-12d_1":"7281106.0000","26_exudate-12d_2":"9080440.0000","27_exudate-12d_3":"6332539.5000","28_exudate-12d_4":"7923445.5000","13_exudate-3d_1":"653950.9400","14_exudate-3d_2":"511977.6600","15_exudate-3d_3":"792350.6900","16_exudate-3d_4":"646531.3800","17_exudate-6d_1":"3265642.5000","18_exudate-6d_2":"2474636.2500","19_exudate-6d_3":"3073958.5000","20_exudate-6d_4":"277319.7500","21_exudate-9d_1":"6014805.5000","22_exudate-9d_2":"6308952.5000","23_exudate-9d_3":"6990055.0000","24_exudate-9d_4":"5428560.0000","5_exudate-med-ctrl-_1":"","6_exudate-med-ctrl-_2":"39674.3700","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"20671.6100","34_pellet-0d_2":"17808.7700","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"","50_pellet-12d_2":"","51_pellet-12d_3":"61083.8100","52_pellet-12d_4":"23974.9200","37_pellet-3d_1":"40514.1700","38_pellet-3d_2":"","39_pellet-3d_3":"42503.4400","40_pellet-3d_4":"28594.8300","41_pellet-6d_1":"135270.7300","42_pellet-6d_2":"101086.1300","43_pellet-6d_3":"146703.9500","44_pellet-6d_4":"126028.3700","45_pellet-9d_1":"","46_pellet-9d_2":"","47_pellet-9d_3":"37268.1100","48_pellet-9d_4":"48892.8300","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"","32_pellet-med-ctrl-_4":""},{"Metabolite":"formyl-methionyl peptide","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"","11_exudate-0d_3":"","12_exudate-0d_4":"","9_exudate-0d_1":"","25_exudate-12d_1":"5001695.5000","26_exudate-12d_2":"4588843.5000","27_exudate-12d_3":"3850237.5000","28_exudate-12d_4":"4480527.0000","13_exudate-3d_1":"86290.7700","14_exudate-3d_2":"64684.7400","15_exudate-3d_3":"103175.2300","16_exudate-3d_4":"87655.3400","17_exudate-6d_1":"538754.0600","18_exudate-6d_2":"344404.3100","19_exudate-6d_3":"652564.0000","20_exudate-6d_4":"468951.7800","21_exudate-9d_1":"2652601.0000","22_exudate-9d_2":"3064012.0000","23_exudate-9d_3":"3613482.5000","24_exudate-9d_4":"2380012.0000","5_exudate-med-ctrl-_1":"","6_exudate-med-ctrl-_2":"","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"","34_pellet-0d_2":"","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"348183.7500","50_pellet-12d_2":"379063.6600","51_pellet-12d_3":"371068.3400","52_pellet-12d_4":"721849.3100","37_pellet-3d_1":"36690.0000","38_pellet-3d_2":"","39_pellet-3d_3":"13662.0000","40_pellet-3d_4":"30110.9900","41_pellet-6d_1":"241400.5800","42_pellet-6d_2":"264074.9400","43_pellet-6d_3":"274262.4700","44_pellet-6d_4":"348293.9700","45_pellet-9d_1":"158279.6600","46_pellet-9d_2":"224604.4500","47_pellet-9d_3":"190598.3900","48_pellet-9d_4":"310460.3800","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"","32_pellet-med-ctrl-_4":""},{"Metabolite":"galacturonic acid","1_extr-ctrl--extr-ctrl-_1":"23618.7800","2_extr-ctrl--extr-ctrl-_2":"21559.9900","3_extr-ctrl--extr-ctrl-_3":"28309.6600","4_extr-ctrl--extr-ctrl-_4":"36804.0000","10_exudate-0d_2":"21088.9800","11_exudate-0d_3":"21536.4600","12_exudate-0d_4":"25635.9800","9_exudate-0d_1":"23111.5300","25_exudate-12d_1":"82275.3900","26_exudate-12d_2":"167747.2200","27_exudate-12d_3":"135934.0500","28_exudate-12d_4":"292806.0000","13_exudate-3d_1":"22122.1300","14_exudate-3d_2":"20561.2700","15_exudate-3d_3":"15599.3500","16_exudate-3d_4":"24310.3800","17_exudate-6d_1":"27292.2900","18_exudate-6d_2":"22178.4300","19_exudate-6d_3":"24995.4300","20_exudate-6d_4":"19090.0300","21_exudate-9d_1":"95257.1700","22_exudate-9d_2":"121710.6200","23_exudate-9d_3":"175001.0600","24_exudate-9d_4":"114545.6500","5_exudate-med-ctrl-_1":"20029.2800","6_exudate-med-ctrl-_2":"23702.8900","7_exudate-med-ctrl-_3":"21886.8900","8_exudate-med-ctrl-_4":"20479.2700","33_pellet-0d_1":"12884.2700","34_pellet-0d_2":"28183.2900","35_pellet-0d_3":"21844.8200","36_pellet-0d_4":"22847.1300","49_pellet-12d_1":"26595.4900","50_pellet-12d_2":"25847.3300","51_pellet-12d_3":"23406.2900","52_pellet-12d_4":"16677.1000","37_pellet-3d_1":"22782.0300","38_pellet-3d_2":"29507.8700","39_pellet-3d_3":"25305.4900","40_pellet-3d_4":"20013.5600","41_pellet-6d_1":"33578.2700","42_pellet-6d_2":"24252.4000","43_pellet-6d_3":"36549.6300","44_pellet-6d_4":"28522.0700","45_pellet-9d_1":"31594.1000","46_pellet-9d_2":"17614.0000","47_pellet-9d_3":"43793.4500","48_pellet-9d_4":"69818.8400","29_pellet-med-ctrl-_1":"16595.8100","30_pellet-med-ctrl-_2":"20914.2500","31_pellet-med-ctrl-_3":"21871.1600","32_pellet-med-ctrl-_4":"17800.3200"},{"Metabolite":"glutamic acid","1_extr-ctrl--extr-ctrl-_1":"156445.4200","2_extr-ctrl--extr-ctrl-_2":"117950.4600","3_extr-ctrl--extr-ctrl-_3":"482799.3800","4_extr-ctrl--extr-ctrl-_4":"141959.4500","10_exudate-0d_2":"139848.6600","11_exudate-0d_3":"148945.1600","12_exudate-0d_4":"101868.3000","9_exudate-0d_1":"111719.2500","25_exudate-12d_1":"164345.0200","26_exudate-12d_2":"147482.8400","27_exudate-12d_3":"144954.6700","28_exudate-12d_4":"225116.2500","13_exudate-3d_1":"139703.9200","14_exudate-3d_2":"114548.4100","15_exudate-3d_3":"128352.2800","16_exudate-3d_4":"121494.4800","17_exudate-6d_1":"124159.8600","18_exudate-6d_2":"131216.8800","19_exudate-6d_3":"132278.3800","20_exudate-6d_4":"102343.1900","21_exudate-9d_1":"157842.5900","22_exudate-9d_2":"130961.8300","23_exudate-9d_3":"172026.3000","24_exudate-9d_4":"149537.5600","5_exudate-med-ctrl-_1":"117762.3400","6_exudate-med-ctrl-_2":"124423.8900","7_exudate-med-ctrl-_3":"148724.1100","8_exudate-med-ctrl-_4":"121965.8400","33_pellet-0d_1":"114348.4500","34_pellet-0d_2":"111742.7700","35_pellet-0d_3":"117610.7700","36_pellet-0d_4":"146666.2000","49_pellet-12d_1":"4601234.0000","50_pellet-12d_2":"1762213.7500","51_pellet-12d_3":"6781108.0000","52_pellet-12d_4":"372265.3100","37_pellet-3d_1":"188957.3400","38_pellet-3d_2":"148242.2800","39_pellet-3d_3":"129568.0200","40_pellet-3d_4":"186775.6400","41_pellet-6d_1":"352735.5300","42_pellet-6d_2":"337331.8800","43_pellet-6d_3":"386694.3100","44_pellet-6d_4":"1511582.2500","45_pellet-9d_1":"375491.9400","46_pellet-9d_2":"272298.6300","47_pellet-9d_3":"358007.2500","48_pellet-9d_4":"1819110.8800","29_pellet-med-ctrl-_1":"103815.8500","30_pellet-med-ctrl-_2":"130664.5200","31_pellet-med-ctrl-_3":"158568.5500","32_pellet-med-ctrl-_4":"109467.7800"},{"Metabolite":"hypoxanthine","1_extr-ctrl--extr-ctrl-_1":"221054.2700","2_extr-ctrl--extr-ctrl-_2":"151756.4400","3_extr-ctrl--extr-ctrl-_3":"118993.2300","4_extr-ctrl--extr-ctrl-_4":"147149.0300","10_exudate-0d_2":"102497.3100","11_exudate-0d_3":"104357.9000","12_exudate-0d_4":"90385.7000","9_exudate-0d_1":"99180.6900","25_exudate-12d_1":"1035597.0600","26_exudate-12d_2":"14669115.0000","27_exudate-12d_3":"8962711.0000","28_exudate-12d_4":"16951600.0000","13_exudate-3d_1":"92149.5700","14_exudate-3d_2":"112961.9500","15_exudate-3d_3":"126179.2600","16_exudate-3d_4":"102391.1200","17_exudate-6d_1":"255763.7000","18_exudate-6d_2":"282974.0900","19_exudate-6d_3":"261169.7800","20_exudate-6d_4":"161137.3000","21_exudate-9d_1":"2987554.5000","22_exudate-9d_2":"3604956.5000","23_exudate-9d_3":"7348953.0000","24_exudate-9d_4":"6744573.5000","5_exudate-med-ctrl-_1":"84966.9500","6_exudate-med-ctrl-_2":"97166.8800","7_exudate-med-ctrl-_3":"96237.8800","8_exudate-med-ctrl-_4":"139314.1700","33_pellet-0d_1":"123891.7300","34_pellet-0d_2":"137788.4400","35_pellet-0d_3":"123616.1200","36_pellet-0d_4":"124799.8200","49_pellet-12d_1":"3249856.5000","50_pellet-12d_2":"3165320.5000","51_pellet-12d_3":"2126242.7500","52_pellet-12d_4":"1889808.6300","37_pellet-3d_1":"150069.2700","38_pellet-3d_2":"145127.1700","39_pellet-3d_3":"202838.7200","40_pellet-3d_4":"207652.3100","41_pellet-6d_1":"6267500.0000","42_pellet-6d_2":"1719249.6300","43_pellet-6d_3":"4260835.0000","44_pellet-6d_4":"2725011.2500","45_pellet-9d_1":"18222354.0000","46_pellet-9d_2":"11427137.0000","47_pellet-9d_3":"17182146.0000","48_pellet-9d_4":"12694867.0000","29_pellet-med-ctrl-_1":"125127.0100","30_pellet-med-ctrl-_2":"115011.5000","31_pellet-med-ctrl-_3":"205212.2300","32_pellet-med-ctrl-_4":"132126.8100"},{"Metabolite":"indole-3-acetic acid","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"34939.6200","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"919933.5000","11_exudate-0d_3":"23738.3200","12_exudate-0d_4":"1304582.1400","9_exudate-0d_1":"626674.4400","25_exudate-12d_1":"99400939.7000","26_exudate-12d_2":"132619500.8200","27_exudate-12d_3":"162087369.2000","28_exudate-12d_4":"133465231.4100","13_exudate-3d_1":"2238001.1500","14_exudate-3d_2":"1619020.4600","15_exudate-3d_3":"1847019.1100","16_exudate-3d_4":"1663936.8700","17_exudate-6d_1":"12606589.0700","18_exudate-6d_2":"13376710.0500","19_exudate-6d_3":"15665235.7300","20_exudate-6d_4":"11273689.6500","21_exudate-9d_1":"40019236.5200","22_exudate-9d_2":"39832682.7300","23_exudate-9d_3":"78083748.8900","24_exudate-9d_4":"60999358.0000","5_exudate-med-ctrl-_1":"324707.9400","6_exudate-med-ctrl-_2":"258037.1800","7_exudate-med-ctrl-_3":"69758.1000","8_exudate-med-ctrl-_4":"652677.2900","33_pellet-0d_1":"59115.3300","34_pellet-0d_2":"110942.4500","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"4156943.1500","50_pellet-12d_2":"4941086.4900","51_pellet-12d_3":"17555772.0800","52_pellet-12d_4":"4615925.9100","37_pellet-3d_1":"54161.4000","38_pellet-3d_2":"59604.3800","39_pellet-3d_3":"145548.2700","40_pellet-3d_4":"76659.9400","41_pellet-6d_1":"149073.3600","42_pellet-6d_2":"62865.6800","43_pellet-6d_3":"113773.7800","44_pellet-6d_4":"68080.8900","45_pellet-9d_1":"999985.9300","46_pellet-9d_2":"1344995.2600","47_pellet-9d_3":"1189999.6400","48_pellet-9d_4":"1481057.3200","29_pellet-med-ctrl-_1":"15772.1000","30_pellet-med-ctrl-_2":"22349.1400","31_pellet-med-ctrl-_3":"19455.9500","32_pellet-med-ctrl-_4":"29020.0000"},{"Metabolite":"indole-3-pyruvic acid","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"87557.1200","11_exudate-0d_3":"156214.5500","12_exudate-0d_4":"146048.9200","9_exudate-0d_1":"38165.4100","25_exudate-12d_1":"20334108.0000","26_exudate-12d_2":"28264178.0000","27_exudate-12d_3":"53718472.0000","28_exudate-12d_4":"35300896.0000","13_exudate-3d_1":"85133.6500","14_exudate-3d_2":"139770.8000","15_exudate-3d_3":"72959.4600","16_exudate-3d_4":"125831.3000","17_exudate-6d_1":"1438391.1300","18_exudate-6d_2":"1138335.7500","19_exudate-6d_3":"610317.8800","20_exudate-6d_4":"10178057.0000","21_exudate-9d_1":"6795900.5000","22_exudate-9d_2":"9831115.0000","23_exudate-9d_3":"6969740.0000","24_exudate-9d_4":"9473965.0000","5_exudate-med-ctrl-_1":"83766.9800","6_exudate-med-ctrl-_2":"80427.0200","7_exudate-med-ctrl-_3":"74704.8400","8_exudate-med-ctrl-_4":"97010.2200","33_pellet-0d_1":"71355.7300","34_pellet-0d_2":"37886.9300","35_pellet-0d_3":"49755.5000","36_pellet-0d_4":"26679.0100","49_pellet-12d_1":"6470270.5000","50_pellet-12d_2":"6026851.0000","51_pellet-12d_3":"13794454.0000","52_pellet-12d_4":"4334246.0000","37_pellet-3d_1":"55185.9900","38_pellet-3d_2":"34967.7200","39_pellet-3d_3":"51421.4400","40_pellet-3d_4":"36757.4300","41_pellet-6d_1":"136805.0200","42_pellet-6d_2":"81731.2200","43_pellet-6d_3":"54668.0700","44_pellet-6d_4":"45240.1100","45_pellet-9d_1":"1602520.1300","46_pellet-9d_2":"1285881.1300","47_pellet-9d_3":"1198342.2500","48_pellet-9d_4":"1172175.6300","29_pellet-med-ctrl-_1":"21921.7900","30_pellet-med-ctrl-_2":"23097.9000","31_pellet-med-ctrl-_3":"26869.1800","32_pellet-med-ctrl-_4":"22598.5700"},{"Metabolite":"inosine","1_extr-ctrl--extr-ctrl-_1":"296748.4700","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"131278.5200","4_extr-ctrl--extr-ctrl-_4":"245777.9100","10_exudate-0d_2":"71179.0500","11_exudate-0d_3":"","12_exudate-0d_4":"217010.3900","9_exudate-0d_1":"85678.6800","25_exudate-12d_1":"201994.8300","26_exudate-12d_2":"317711.8800","27_exudate-12d_3":"230975.7800","28_exudate-12d_4":"256319.0900","13_exudate-3d_1":"117991.2000","14_exudate-3d_2":"108267.2700","15_exudate-3d_3":"144237.7700","16_exudate-3d_4":"128346.6200","17_exudate-6d_1":"943009.8100","18_exudate-6d_2":"1067724.5000","19_exudate-6d_3":"779162.1300","20_exudate-6d_4":"533910.2500","21_exudate-9d_1":"288048.9400","22_exudate-9d_2":"338979.1900","23_exudate-9d_3":"358522.6900","24_exudate-9d_4":"257999.4400","5_exudate-med-ctrl-_1":"48827.6300","6_exudate-med-ctrl-_2":"81393.3300","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"30102.3900","33_pellet-0d_1":"110410.5200","34_pellet-0d_2":"105491.0500","35_pellet-0d_3":"137677.5600","36_pellet-0d_4":"64310.9500","49_pellet-12d_1":"6389735.0000","50_pellet-12d_2":"7578261.5000","51_pellet-12d_3":"2500533.7500","52_pellet-12d_4":"14395358.0000","37_pellet-3d_1":"347885.7200","38_pellet-3d_2":"280733.3400","39_pellet-3d_3":"296205.0300","40_pellet-3d_4":"302772.9100","41_pellet-6d_1":"34013484.0000","42_pellet-6d_2":"38971708.0000","43_pellet-6d_3":"36612388.0000","44_pellet-6d_4":"38513820.0000","45_pellet-9d_1":"15740554.0000","46_pellet-9d_2":"18888354.0000","47_pellet-9d_3":"14746273.0000","48_pellet-9d_4":"17177862.0000","29_pellet-med-ctrl-_1":"58787.7000","30_pellet-med-ctrl-_2":"92199.1800","31_pellet-med-ctrl-_3":"79796.1900","32_pellet-med-ctrl-_4":"16219.7600"},{"Metabolite":"isoleucine","1_extr-ctrl--extr-ctrl-_1":"46686.0000","2_extr-ctrl--extr-ctrl-_2":"17440.1600","3_extr-ctrl--extr-ctrl-_3":"114899.0500","4_extr-ctrl--extr-ctrl-_4":"30795.6200","10_exudate-0d_2":"16464.1700","11_exudate-0d_3":"22186.1200","12_exudate-0d_4":"23779.8900","9_exudate-0d_1":"13978.5500","25_exudate-12d_1":"34914.4900","26_exudate-12d_2":"36340.1300","27_exudate-12d_3":"39325.4900","28_exudate-12d_4":"64746.7500","13_exudate-3d_1":"24929.0800","14_exudate-3d_2":"15573.4700","15_exudate-3d_3":"20622.3300","16_exudate-3d_4":"19945.5000","17_exudate-6d_1":"54601.8400","18_exudate-6d_2":"30123.5900","19_exudate-6d_3":"63466.8400","20_exudate-6d_4":"56051.8900","21_exudate-9d_1":"99871.8800","22_exudate-9d_2":"173996.7800","23_exudate-9d_3":"196327.0600","24_exudate-9d_4":"92175.5800","5_exudate-med-ctrl-_1":"19749.6700","6_exudate-med-ctrl-_2":"25463.3400","7_exudate-med-ctrl-_3":"21510.0300","8_exudate-med-ctrl-_4":"24738.0200","33_pellet-0d_1":"20503.4300","34_pellet-0d_2":"12233.9900","35_pellet-0d_3":"19153.3300","36_pellet-0d_4":"20461.6000","49_pellet-12d_1":"170671.3800","50_pellet-12d_2":"91546.5100","51_pellet-12d_3":"370762.2500","52_pellet-12d_4":"187254.8400","37_pellet-3d_1":"21273.6800","38_pellet-3d_2":"18149.1800","39_pellet-3d_3":"34391.7300","40_pellet-3d_4":"34033.4300","41_pellet-6d_1":"102791.4500","42_pellet-6d_2":"73766.4500","43_pellet-6d_3":"274665.5900","44_pellet-6d_4":"334965.2200","45_pellet-9d_1":"76834.3800","46_pellet-9d_2":"104536.6600","47_pellet-9d_3":"291897.0000","48_pellet-9d_4":"209664.1300","29_pellet-med-ctrl-_1":"12712.1100","30_pellet-med-ctrl-_2":"13753.5200","31_pellet-med-ctrl-_3":"28208.5800","32_pellet-med-ctrl-_4":"18180.8100"},{"Metabolite":"leucine/norleucine","1_extr-ctrl--extr-ctrl-_1":"46244.6500","2_extr-ctrl--extr-ctrl-_2":"15594.3100","3_extr-ctrl--extr-ctrl-_3":"171679.1700","4_extr-ctrl--extr-ctrl-_4":"37534.0100","10_exudate-0d_2":"18309.8100","11_exudate-0d_3":"22909.5100","12_exudate-0d_4":"18830.5400","9_exudate-0d_1":"17299.5000","25_exudate-12d_1":"41189.8500","26_exudate-12d_2":"43981.8600","27_exudate-12d_3":"51069.0000","28_exudate-12d_4":"65094.7500","13_exudate-3d_1":"20443.7600","14_exudate-3d_2":"21958.4500","15_exudate-3d_3":"15390.9400","16_exudate-3d_4":"12202.2500","17_exudate-6d_1":"21096.5500","18_exudate-6d_2":"31651.7600","19_exudate-6d_3":"31797.7100","20_exudate-6d_4":"15175.9200","21_exudate-9d_1":"29604.5100","22_exudate-9d_2":"34895.5700","23_exudate-9d_3":"58984.0000","24_exudate-9d_4":"39059.7100","5_exudate-med-ctrl-_1":"18706.7800","6_exudate-med-ctrl-_2":"24962.0400","7_exudate-med-ctrl-_3":"15832.6000","8_exudate-med-ctrl-_4":"29544.6200","33_pellet-0d_1":"21098.6300","34_pellet-0d_2":"17110.5700","35_pellet-0d_3":"29469.2400","36_pellet-0d_4":"19037.1700","49_pellet-12d_1":"312247.0000","50_pellet-12d_2":"177331.7200","51_pellet-12d_3":"910800.3100","52_pellet-12d_4":"841761.8800","37_pellet-3d_1":"59363.0300","38_pellet-3d_2":"65657.6200","39_pellet-3d_3":"85974.8800","40_pellet-3d_4":"86252.2700","41_pellet-6d_1":"293337.2800","42_pellet-6d_2":"262635.3100","43_pellet-6d_3":"832085.5600","44_pellet-6d_4":"853792.3100","45_pellet-9d_1":"196863.5200","46_pellet-9d_2":"400211.9700","47_pellet-9d_3":"1234939.0000","48_pellet-9d_4":"945725.0000","29_pellet-med-ctrl-_1":"15287.3000","30_pellet-med-ctrl-_2":"26157.6300","31_pellet-med-ctrl-_3":"33073.1700","32_pellet-med-ctrl-_4":"22127.3300"},{"Metabolite":"lumichrome","1_extr-ctrl--extr-ctrl-_1":"231466.8100","2_extr-ctrl--extr-ctrl-_2":"72096.1600","3_extr-ctrl--extr-ctrl-_3":"199336.5900","4_extr-ctrl--extr-ctrl-_4":"162150.7800","10_exudate-0d_2":"1860589.1300","11_exudate-0d_3":"988038.6300","12_exudate-0d_4":"2234152.2500","9_exudate-0d_1":"1467311.2500","25_exudate-12d_1":"157648528.0000","26_exudate-12d_2":"200719552.0000","27_exudate-12d_3":"173569568.0000","28_exudate-12d_4":"190868144.0000","13_exudate-3d_1":"13059999.0000","14_exudate-3d_2":"12656172.0000","15_exudate-3d_3":"13805393.0000","16_exudate-3d_4":"13752188.0000","17_exudate-6d_1":"82978488.0000","18_exudate-6d_2":"87577728.0000","19_exudate-6d_3":"81932856.0000","20_exudate-6d_4":"54933164.0000","21_exudate-9d_1":"141510704.0000","22_exudate-9d_2":"182821216.0000","23_exudate-9d_3":"186417888.0000","24_exudate-9d_4":"150837312.0000","5_exudate-med-ctrl-_1":"175971.6700","6_exudate-med-ctrl-_2":"169374.7000","7_exudate-med-ctrl-_3":"115082.2600","8_exudate-med-ctrl-_4":"249966.0500","33_pellet-0d_1":"214671.0500","34_pellet-0d_2":"139407.6300","35_pellet-0d_3":"171396.4500","36_pellet-0d_4":"197457.6400","49_pellet-12d_1":"1783234.8800","50_pellet-12d_2":"3889832.2500","51_pellet-12d_3":"8121775.5000","52_pellet-12d_4":"3849262.5000","37_pellet-3d_1":"756316.6300","38_pellet-3d_2":"500014.8800","39_pellet-3d_3":"464594.6900","40_pellet-3d_4":"526338.8800","41_pellet-6d_1":"1210017.6300","42_pellet-6d_2":"1054982.5000","43_pellet-6d_3":"1062150.3800","44_pellet-6d_4":"895445.3800","45_pellet-9d_1":"2209328.2500","46_pellet-9d_2":"3963927.7500","47_pellet-9d_3":"2590733.7500","48_pellet-9d_4":"2480702.7500","29_pellet-med-ctrl-_1":"137582.9400","30_pellet-med-ctrl-_2":"196105.7500","31_pellet-med-ctrl-_3":"250414.6400","32_pellet-med-ctrl-_4":"139719.7800"},{"Metabolite":"mandelic acid","1_extr-ctrl--extr-ctrl-_1":"183492.9200","2_extr-ctrl--extr-ctrl-_2":"72827.9700","3_extr-ctrl--extr-ctrl-_3":"167808.5900","4_extr-ctrl--extr-ctrl-_4":"116618.0900","10_exudate-0d_2":"7047963.0000","11_exudate-0d_3":"166078.7700","12_exudate-0d_4":"6372451.0000","9_exudate-0d_1":"10195424.0000","25_exudate-12d_1":"11850559.0000","26_exudate-12d_2":"17920664.0000","27_exudate-12d_3":"8251037.0000","28_exudate-12d_4":"11550470.0000","13_exudate-3d_1":"6956440.5000","14_exudate-3d_2":"6446998.0000","15_exudate-3d_3":"5986197.0000","16_exudate-3d_4":"10779453.0000","17_exudate-6d_1":"7734565.5000","18_exudate-6d_2":"14119389.0000","19_exudate-6d_3":"8798827.0000","20_exudate-6d_4":"1295299.3800","21_exudate-9d_1":"7936390.0000","22_exudate-9d_2":"18257566.0000","23_exudate-9d_3":"19036506.0000","24_exudate-9d_4":"7516253.5000","5_exudate-med-ctrl-_1":"5321779.0000","6_exudate-med-ctrl-_2":"7332169.0000","7_exudate-med-ctrl-_3":"545463.1900","8_exudate-med-ctrl-_4":"10141023.0000","33_pellet-0d_1":"88751.8500","34_pellet-0d_2":"182499.5800","35_pellet-0d_3":"146221.5000","36_pellet-0d_4":"104743.3000","49_pellet-12d_1":"124191.4900","50_pellet-12d_2":"153777.7700","51_pellet-12d_3":"284627.9100","52_pellet-12d_4":"115930.2000","37_pellet-3d_1":"412107.7500","38_pellet-3d_2":"243358.7200","39_pellet-3d_3":"255171.5000","40_pellet-3d_4":"490639.1600","41_pellet-6d_1":"610100.3100","42_pellet-6d_2":"392746.2500","43_pellet-6d_3":"492645.0900","44_pellet-6d_4":"348732.1900","45_pellet-9d_1":"105043.9500","46_pellet-9d_2":"176506.0900","47_pellet-9d_3":"176422.6400","48_pellet-9d_4":"193904.9800","29_pellet-med-ctrl-_1":"101326.3800","30_pellet-med-ctrl-_2":"128617.6100","31_pellet-med-ctrl-_3":"126132.4800","32_pellet-med-ctrl-_4":"113037.2700"},{"Metabolite":"N-acetyl-hexosamines","1_extr-ctrl--extr-ctrl-_1":"23195.0000","2_extr-ctrl--extr-ctrl-_2":"19225.3300","3_extr-ctrl--extr-ctrl-_3":"18028.2600","4_extr-ctrl--extr-ctrl-_4":"20680.0300","10_exudate-0d_2":"17290.7700","11_exudate-0d_3":"21127.5800","12_exudate-0d_4":"","9_exudate-0d_1":"12711.1600","25_exudate-12d_1":"196094.5300","26_exudate-12d_2":"430178.5600","27_exudate-12d_3":"388638.3800","28_exudate-12d_4":"1034511.0600","13_exudate-3d_1":"20178.8200","14_exudate-3d_2":"13549.1000","15_exudate-3d_3":"20081.7500","16_exudate-3d_4":"20794.0600","17_exudate-6d_1":"29573.1700","18_exudate-6d_2":"33185.1900","19_exudate-6d_3":"34703.2300","20_exudate-6d_4":"25700.7900","21_exudate-9d_1":"296031.9100","22_exudate-9d_2":"434938.0600","23_exudate-9d_3":"357549.2200","24_exudate-9d_4":"383747.4400","5_exudate-med-ctrl-_1":"27300.4600","6_exudate-med-ctrl-_2":"11914.4300","7_exudate-med-ctrl-_3":"18151.6200","8_exudate-med-ctrl-_4":"18413.5500","33_pellet-0d_1":"17872.3200","34_pellet-0d_2":"23348.1700","35_pellet-0d_3":"","36_pellet-0d_4":"11817.9800","49_pellet-12d_1":"51851.5000","50_pellet-12d_2":"127128.1300","51_pellet-12d_3":"49749.0700","52_pellet-12d_4":"43878.4800","37_pellet-3d_1":"21577.3400","38_pellet-3d_2":"12148.5300","39_pellet-3d_3":"15680.4400","40_pellet-3d_4":"17217.2400","41_pellet-6d_1":"81349.6500","42_pellet-6d_2":"","43_pellet-6d_3":"","44_pellet-6d_4":"23994.1000","45_pellet-9d_1":"139804.9700","46_pellet-9d_2":"161415.4800","47_pellet-9d_3":"51444.3600","48_pellet-9d_4":"70328.6600","29_pellet-med-ctrl-_1":"17517.6500","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"","32_pellet-med-ctrl-_4":"16741.3900"},{"Metabolite":"N-acetyl-leucine","1_extr-ctrl--extr-ctrl-_1":"59402.8400","2_extr-ctrl--extr-ctrl-_2":"34702.6800","3_extr-ctrl--extr-ctrl-_3":"46057.4200","4_extr-ctrl--extr-ctrl-_4":"46189.0500","10_exudate-0d_2":"61911.6900","11_exudate-0d_3":"38618.4700","12_exudate-0d_4":"56554.0200","9_exudate-0d_1":"58585.6400","25_exudate-12d_1":"1623575.8800","26_exudate-12d_2":"1711307.2500","27_exudate-12d_3":"1616434.1300","28_exudate-12d_4":"1975652.2500","13_exudate-3d_1":"123938.7100","14_exudate-3d_2":"119149.4500","15_exudate-3d_3":"130525.5200","16_exudate-3d_4":"128314.4900","17_exudate-6d_1":"619084.3800","18_exudate-6d_2":"595806.9400","19_exudate-6d_3":"684229.7500","20_exudate-6d_4":"620631.3100","21_exudate-9d_1":"972110.6900","22_exudate-9d_2":"1283036.5000","23_exudate-9d_3":"1645870.2500","24_exudate-9d_4":"1032949.6900","5_exudate-med-ctrl-_1":"41945.3800","6_exudate-med-ctrl-_2":"52285.3500","7_exudate-med-ctrl-_3":"40595.6700","8_exudate-med-ctrl-_4":"44451.7400","33_pellet-0d_1":"45732.7400","34_pellet-0d_2":"41841.2400","35_pellet-0d_3":"32273.3900","36_pellet-0d_4":"46665.7100","49_pellet-12d_1":"120867.8300","50_pellet-12d_2":"175434.5500","51_pellet-12d_3":"261733.9700","52_pellet-12d_4":"120846.8100","37_pellet-3d_1":"41454.4300","38_pellet-3d_2":"41661.4800","39_pellet-3d_3":"43518.0800","40_pellet-3d_4":"40532.3000","41_pellet-6d_1":"78324.3800","42_pellet-6d_2":"63084.9600","43_pellet-6d_3":"73002.2800","44_pellet-6d_4":"87904.9100","45_pellet-9d_1":"85957.7900","46_pellet-9d_2":"98276.9900","47_pellet-9d_3":"88719.4000","48_pellet-9d_4":"99751.6100","29_pellet-med-ctrl-_1":"37648.6800","30_pellet-med-ctrl-_2":"46852.7000","31_pellet-med-ctrl-_3":"39514.8100","32_pellet-med-ctrl-_4":"41477.4200"},{"Metabolite":"n-acetyl-tryptophan","1_extr-ctrl--extr-ctrl-_1":"","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"","4_extr-ctrl--extr-ctrl-_4":"","10_exudate-0d_2":"15596.2200","11_exudate-0d_3":"","12_exudate-0d_4":"","9_exudate-0d_1":"","25_exudate-12d_1":"1497854.2500","26_exudate-12d_2":"727940.5000","27_exudate-12d_3":"740713.5000","28_exudate-12d_4":"593404.4400","13_exudate-3d_1":"16478.2000","14_exudate-3d_2":"20630.2900","15_exudate-3d_3":"25035.1900","16_exudate-3d_4":"19417.9500","17_exudate-6d_1":"130241.4500","18_exudate-6d_2":"137997.5600","19_exudate-6d_3":"148666.9100","20_exudate-6d_4":"42882.8700","21_exudate-9d_1":"363345.3100","22_exudate-9d_2":"410728.9400","23_exudate-9d_3":"398484.6300","24_exudate-9d_4":"290815.7500","5_exudate-med-ctrl-_1":"12542.6200","6_exudate-med-ctrl-_2":"14395.8400","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"17360.3700","33_pellet-0d_1":"","34_pellet-0d_2":"12804.9100","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"","50_pellet-12d_2":"","51_pellet-12d_3":"","52_pellet-12d_4":"","37_pellet-3d_1":"","38_pellet-3d_2":"15191.5800","39_pellet-3d_3":"12591.6300","40_pellet-3d_4":"13159.4000","41_pellet-6d_1":"22440.8100","42_pellet-6d_2":"20660.6000","43_pellet-6d_3":"19959.8000","44_pellet-6d_4":"20410.0100","45_pellet-9d_1":"","46_pellet-9d_2":"","47_pellet-9d_3":"","48_pellet-9d_4":"19396.9900","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"12026.4200","32_pellet-med-ctrl-_4":""},{"Metabolite":"nicotinic/isonicotinic acid","1_extr-ctrl--extr-ctrl-_1":"77722.6200","2_extr-ctrl--extr-ctrl-_2":"56210.8900","3_extr-ctrl--extr-ctrl-_3":"51301.1500","4_extr-ctrl--extr-ctrl-_4":"64375.9400","10_exudate-0d_2":"52922.4000","11_exudate-0d_3":"46194.5900","12_exudate-0d_4":"76112.6600","9_exudate-0d_1":"47524.8800","25_exudate-12d_1":"304724.6300","26_exudate-12d_2":"603760.0600","27_exudate-12d_3":"469883.6300","28_exudate-12d_4":"549336.0000","13_exudate-3d_1":"70888.5800","14_exudate-3d_2":"75238.2400","15_exudate-3d_3":"52158.3200","16_exudate-3d_4":"62281.7000","17_exudate-6d_1":"178514.7200","18_exudate-6d_2":"132052.4700","19_exudate-6d_3":"269246.5300","20_exudate-6d_4":"176067.6600","21_exudate-9d_1":"352044.4700","22_exudate-9d_2":"511300.1600","23_exudate-9d_3":"581937.5600","24_exudate-9d_4":"364124.1300","5_exudate-med-ctrl-_1":"50790.2600","6_exudate-med-ctrl-_2":"50561.5700","7_exudate-med-ctrl-_3":"66218.1000","8_exudate-med-ctrl-_4":"52604.5100","33_pellet-0d_1":"42491.7900","34_pellet-0d_2":"41692.3600","35_pellet-0d_3":"40919.6100","36_pellet-0d_4":"43228.9900","49_pellet-12d_1":"55945.1100","50_pellet-12d_2":"64336.0600","51_pellet-12d_3":"122331.1600","52_pellet-12d_4":"73175.3600","37_pellet-3d_1":"49374.2600","38_pellet-3d_2":"46276.5200","39_pellet-3d_3":"51305.3800","40_pellet-3d_4":"55897.5400","41_pellet-6d_1":"53138.8400","42_pellet-6d_2":"46230.4300","43_pellet-6d_3":"56390.1700","44_pellet-6d_4":"49909.4500","45_pellet-9d_1":"66865.9000","46_pellet-9d_2":"68295.9100","47_pellet-9d_3":"80651.5000","48_pellet-9d_4":"73620.9800","29_pellet-med-ctrl-_1":"44728.8800","30_pellet-med-ctrl-_2":"54081.3500","31_pellet-med-ctrl-_3":"42444.2300","32_pellet-med-ctrl-_4":"47909.5800"},{"Metabolite":"N-methyl-glutamic acid","1_extr-ctrl--extr-ctrl-_1":"12969.0500","2_extr-ctrl--extr-ctrl-_2":"13697.8400","3_extr-ctrl--extr-ctrl-_3":"13667.4000","4_extr-ctrl--extr-ctrl-_4":"12272.4700","10_exudate-0d_2":"14636.3400","11_exudate-0d_3":"16855.8300","12_exudate-0d_4":"17060.8500","9_exudate-0d_1":"15793.7400","25_exudate-12d_1":"17282.4000","26_exudate-12d_2":"64854.5500","27_exudate-12d_3":"43183.1700","28_exudate-12d_4":"74051.1100","13_exudate-3d_1":"12718.3600","14_exudate-3d_2":"12831.1800","15_exudate-3d_3":"13292.6900","16_exudate-3d_4":"11812.1200","17_exudate-6d_1":"17289.4300","18_exudate-6d_2":"13444.2600","19_exudate-6d_3":"12723.1700","20_exudate-6d_4":"13365.0900","21_exudate-9d_1":"29840.7600","22_exudate-9d_2":"37950.1800","23_exudate-9d_3":"43937.4600","24_exudate-9d_4":"39996.5400","5_exudate-med-ctrl-_1":"15622.4200","6_exudate-med-ctrl-_2":"13112.6700","7_exudate-med-ctrl-_3":"15668.8400","8_exudate-med-ctrl-_4":"16265.9000","33_pellet-0d_1":"14728.8100","34_pellet-0d_2":"16202.6400","35_pellet-0d_3":"12362.2000","36_pellet-0d_4":"13043.5100","49_pellet-12d_1":"56402.1400","50_pellet-12d_2":"73095.0500","51_pellet-12d_3":"16042.3000","52_pellet-12d_4":"41087.8600","37_pellet-3d_1":"12770.6900","38_pellet-3d_2":"14018.3700","39_pellet-3d_3":"12565.6100","40_pellet-3d_4":"14382.4500","41_pellet-6d_1":"120319.1200","42_pellet-6d_2":"44156.6200","43_pellet-6d_3":"45184.0400","44_pellet-6d_4":"42524.3700","45_pellet-9d_1":"427212.5600","46_pellet-9d_2":"229715.5800","47_pellet-9d_3":"390325.6600","48_pellet-9d_4":"290593.7500","29_pellet-med-ctrl-_1":"12424.6700","30_pellet-med-ctrl-_2":"14310.9300","31_pellet-med-ctrl-_3":"15864.1700","32_pellet-med-ctrl-_4":"16645.7100"},{"Metabolite":"pantothenic acid","1_extr-ctrl--extr-ctrl-_1":"121647.9800","2_extr-ctrl--extr-ctrl-_2":"47442.1800","3_extr-ctrl--extr-ctrl-_3":"67195.1600","4_extr-ctrl--extr-ctrl-_4":"61848.5500","10_exudate-0d_2":"79966.4500","11_exudate-0d_3":"43054.0900","12_exudate-0d_4":"109968.7300","9_exudate-0d_1":"90088.9100","25_exudate-12d_1":"30851248.0000","26_exudate-12d_2":"24796286.0000","27_exudate-12d_3":"21863766.0000","28_exudate-12d_4":"27128216.0000","13_exudate-3d_1":"158562.4700","14_exudate-3d_2":"145782.8400","15_exudate-3d_3":"183692.1700","16_exudate-3d_4":"174377.9700","17_exudate-6d_1":"2360601.5000","18_exudate-6d_2":"1760256.0000","19_exudate-6d_3":"2128997.2500","20_exudate-6d_4":"363964.3100","21_exudate-9d_1":"7123230.5000","22_exudate-9d_2":"10521822.0000","23_exudate-9d_3":"9966843.0000","24_exudate-9d_4":"5961436.5000","5_exudate-med-ctrl-_1":"61869.0100","6_exudate-med-ctrl-_2":"55003.4200","7_exudate-med-ctrl-_3":"56999.4400","8_exudate-med-ctrl-_4":"72515.3700","33_pellet-0d_1":"18374.6500","34_pellet-0d_2":"31007.2700","35_pellet-0d_3":"40321.1600","36_pellet-0d_4":"45677.1700","49_pellet-12d_1":"70478.9700","50_pellet-12d_2":"94400.9400","51_pellet-12d_3":"113283.1500","52_pellet-12d_4":"226699.4800","37_pellet-3d_1":"60360.3600","38_pellet-3d_2":"60313.2100","39_pellet-3d_3":"57402.9800","40_pellet-3d_4":"62776.6300","41_pellet-6d_1":"259163.2000","42_pellet-6d_2":"163569.5500","43_pellet-6d_3":"284285.7500","44_pellet-6d_4":"270314.1600","45_pellet-9d_1":"61768.7500","46_pellet-9d_2":"129879.9500","47_pellet-9d_3":"163850.2700","48_pellet-9d_4":"239576.6300","29_pellet-med-ctrl-_1":"35012.9500","30_pellet-med-ctrl-_2":"34828.5000","31_pellet-med-ctrl-_3":"60002.1800","32_pellet-med-ctrl-_4":"42852.2900"},{"Metabolite":"phenylalanine","1_extr-ctrl--extr-ctrl-_1":"98904.1100","2_extr-ctrl--extr-ctrl-_2":"21173.9400","3_extr-ctrl--extr-ctrl-_3":"185457.9500","4_extr-ctrl--extr-ctrl-_4":"60115.6300","10_exudate-0d_2":"91487.1400","11_exudate-0d_3":"29858.8000","12_exudate-0d_4":"75387.5200","9_exudate-0d_1":"62221.2300","25_exudate-12d_1":"1095055.7500","26_exudate-12d_2":"1776595.5000","27_exudate-12d_3":"2118694.0000","28_exudate-12d_4":"2610440.2500","13_exudate-3d_1":"366025.9400","14_exudate-3d_2":"283140.8800","15_exudate-3d_3":"372635.0300","16_exudate-3d_4":"356382.7200","17_exudate-6d_1":"1669743.8800","18_exudate-6d_2":"1654869.1300","19_exudate-6d_3":"1897332.5000","20_exudate-6d_4":"1459247.5000","21_exudate-9d_1":"4045504.0000","22_exudate-9d_2":"3937829.2500","23_exudate-9d_3":"3952028.5000","24_exudate-9d_4":"3259501.7500","5_exudate-med-ctrl-_1":"77615.7700","6_exudate-med-ctrl-_2":"89359.7600","7_exudate-med-ctrl-_3":"34598.8200","8_exudate-med-ctrl-_4":"84796.1600","33_pellet-0d_1":"204892.8400","34_pellet-0d_2":"203314.8300","35_pellet-0d_3":"161154.2300","36_pellet-0d_4":"157284.2800","49_pellet-12d_1":"22888786.0000","50_pellet-12d_2":"25471736.0000","51_pellet-12d_3":"20023998.0000","52_pellet-12d_4":"29472026.0000","37_pellet-3d_1":"1917496.0000","38_pellet-3d_2":"1708452.1300","39_pellet-3d_3":"1257823.5000","40_pellet-3d_4":"1895498.6300","41_pellet-6d_1":"15267668.0000","42_pellet-6d_2":"13820604.0000","43_pellet-6d_3":"20601630.0000","44_pellet-6d_4":"22210618.0000","45_pellet-9d_1":"37636580.0000","46_pellet-9d_2":"36350344.0000","47_pellet-9d_3":"46234252.0000","48_pellet-9d_4":"52161940.0000","29_pellet-med-ctrl-_1":"31010.7300","30_pellet-med-ctrl-_2":"30401.0300","31_pellet-med-ctrl-_3":"35922.7100","32_pellet-med-ctrl-_4":"27879.8200"},{"Metabolite":"proline","1_extr-ctrl--extr-ctrl-_1":"8369.8300","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"34548.0000","4_extr-ctrl--extr-ctrl-_4":"13016.0300","10_exudate-0d_2":"8894.6500","11_exudate-0d_3":"11405.9400","12_exudate-0d_4":"10592.2200","9_exudate-0d_1":"8468.0500","25_exudate-12d_1":"18147.5600","26_exudate-12d_2":"24826.8800","27_exudate-12d_3":"16553.9100","28_exudate-12d_4":"31519.2600","13_exudate-3d_1":"13600.1700","14_exudate-3d_2":"6228.4000","15_exudate-3d_3":"10626.8200","16_exudate-3d_4":"10533.2400","17_exudate-6d_1":"17175.5600","18_exudate-6d_2":"15165.0000","19_exudate-6d_3":"22044.6500","20_exudate-6d_4":"19600.6800","21_exudate-9d_1":"19227.0300","22_exudate-9d_2":"21407.6500","23_exudate-9d_3":"36694.0100","24_exudate-9d_4":"18264.7900","5_exudate-med-ctrl-_1":"","6_exudate-med-ctrl-_2":"14655.6900","7_exudate-med-ctrl-_3":"9007.9000","8_exudate-med-ctrl-_4":"7432.5100","33_pellet-0d_1":"","34_pellet-0d_2":"8931.5600","35_pellet-0d_3":"9406.5800","36_pellet-0d_4":"8375.0400","49_pellet-12d_1":"153429.4500","50_pellet-12d_2":"101218.4400","51_pellet-12d_3":"411474.8100","52_pellet-12d_4":"49751.0500","37_pellet-3d_1":"36361.5700","38_pellet-3d_2":"15705.9200","39_pellet-3d_3":"18682.4500","40_pellet-3d_4":"37607.7100","41_pellet-6d_1":"74795.6300","42_pellet-6d_2":"83615.9000","43_pellet-6d_3":"179888.5900","44_pellet-6d_4":"350624.5300","45_pellet-9d_1":"55479.5000","46_pellet-9d_2":"62029.9000","47_pellet-9d_3":"99894.1600","48_pellet-9d_4":"146139.9200","29_pellet-med-ctrl-_1":"8294.2400","30_pellet-med-ctrl-_2":"8575.6600","31_pellet-med-ctrl-_3":"7332.3800","32_pellet-med-ctrl-_4":""},{"Metabolite":"pterin","1_extr-ctrl--extr-ctrl-_1":"18754.3900","2_extr-ctrl--extr-ctrl-_2":"","3_extr-ctrl--extr-ctrl-_3":"17480.1200","4_extr-ctrl--extr-ctrl-_4":"25420.0800","10_exudate-0d_2":"","11_exudate-0d_3":"19338.3500","12_exudate-0d_4":"","9_exudate-0d_1":"","25_exudate-12d_1":"67833.4000","26_exudate-12d_2":"65956.0000","27_exudate-12d_3":"58513.3800","28_exudate-12d_4":"101472.9100","13_exudate-3d_1":"","14_exudate-3d_2":"","15_exudate-3d_3":"","16_exudate-3d_4":"","17_exudate-6d_1":"21685.6700","18_exudate-6d_2":"16970.9900","19_exudate-6d_3":"22107.2400","20_exudate-6d_4":"26241.4400","21_exudate-9d_1":"62531.8000","22_exudate-9d_2":"41908.2500","23_exudate-9d_3":"126668.4800","24_exudate-9d_4":"28455.7500","5_exudate-med-ctrl-_1":"","6_exudate-med-ctrl-_2":"","7_exudate-med-ctrl-_3":"","8_exudate-med-ctrl-_4":"","33_pellet-0d_1":"","34_pellet-0d_2":"15365.7500","35_pellet-0d_3":"","36_pellet-0d_4":"","49_pellet-12d_1":"1447983.8800","50_pellet-12d_2":"1619607.6300","51_pellet-12d_3":"3134154.2500","52_pellet-12d_4":"1034932.5000","37_pellet-3d_1":"63152.7100","38_pellet-3d_2":"41524.3000","39_pellet-3d_3":"42207.0200","40_pellet-3d_4":"41393.4600","41_pellet-6d_1":"489729.4100","42_pellet-6d_2":"341044.9700","43_pellet-6d_3":"509100.9400","44_pellet-6d_4":"477813.7200","45_pellet-9d_1":"1930921.2500","46_pellet-9d_2":"1142584.8800","47_pellet-9d_3":"1457918.5000","48_pellet-9d_4":"1566913.0000","29_pellet-med-ctrl-_1":"","30_pellet-med-ctrl-_2":"","31_pellet-med-ctrl-_3":"","32_pellet-med-ctrl-_4":""},{"Metabolite":"pyrrole-2-carboxylic acid","1_extr-ctrl--extr-ctrl-_1":"58658.3700","2_extr-ctrl--extr-ctrl-_2":"34793.4600","3_extr-ctrl--extr-ctrl-_3":"55052.5400","4_extr-ctrl--extr-ctrl-_4":"59134.6800","10_exudate-0d_2":"50878.2100","11_exudate-0d_3":"47118.6800","12_exudate-0d_4":"74904.2900","9_exudate-0d_1":"45330.6600","25_exudate-12d_1":"2624357.5000","26_exudate-12d_2":"1369587.1300","27_exudate-12d_3":"1376778.3800","28_exudate-12d_4":"977005.8100","13_exudate-3d_1":"71592.9300","14_exudate-3d_2":"76025.3500","15_exudate-3d_3":"52227.6700","16_exudate-3d_4":"82320.4100","17_exudate-6d_1":"345722.5000","18_exudate-6d_2":"332211.3400","19_exudate-6d_3":"419670.7200","20_exudate-6d_4":"252588.9800","21_exudate-9d_1":"1415665.6300","22_exudate-9d_2":"1946548.6300","23_exudate-9d_3":"991782.5600","24_exudate-9d_4":"686595.0000","5_exudate-med-ctrl-_1":"51420.3400","6_exudate-med-ctrl-_2":"47329.4600","7_exudate-med-ctrl-_3":"63027.2200","8_exudate-med-ctrl-_4":"59274.6800","33_pellet-0d_1":"48093.1100","34_pellet-0d_2":"42136.6300","35_pellet-0d_3":"43431.8800","36_pellet-0d_4":"40368.4500","49_pellet-12d_1":"90831.9100","50_pellet-12d_2":"110603.3300","51_pellet-12d_3":"740165.5000","52_pellet-12d_4":"146807.3800","37_pellet-3d_1":"56901.4700","38_pellet-3d_2":"47315.2600","39_pellet-3d_3":"43879.7300","40_pellet-3d_4":"42038.2200","41_pellet-6d_1":"82679.0800","42_pellet-6d_2":"72643.3500","43_pellet-6d_3":"194974.6300","44_pellet-6d_4":"163660.2700","45_pellet-9d_1":"66104.8800","46_pellet-9d_2":"104698.8400","47_pellet-9d_3":"156661.9700","48_pellet-9d_4":"122328.4800","29_pellet-med-ctrl-_1":"48194.5600","30_pellet-med-ctrl-_2":"46080.5600","31_pellet-med-ctrl-_3":"35961.2500","32_pellet-med-ctrl-_4":"40083.6600"},{"Metabolite":"salicylic acid","1_extr-ctrl--extr-ctrl-_1":"896746.8800","2_extr-ctrl--extr-ctrl-_2":"385532.2200","3_extr-ctrl--extr-ctrl-_3":"1098520.8800","4_extr-ctrl--extr-ctrl-_4":"816090.3100","10_exudate-0d_2":"15118690.0000","11_exudate-0d_3":"7682190.5000","12_exudate-0d_4":"16351994.0000","9_exudate-0d_1":"11387909.0000","25_exudate-12d_1":"98139424.0000","26_exudate-12d_2":"85564312.0000","27_exudate-12d_3":"99576312.0000","28_exudate-12d_4":"45161812.0000","13_exudate-3d_1":"18964802.0000","14_exudate-3d_2":"11237139.0000","15_exudate-3d_3":"13887408.0000","16_exudate-3d_4":"21133554.0000","17_exudate-6d_1":"44241684.0000","18_exudate-6d_2":"48069584.0000","19_exudate-6d_3":"45176808.0000","20_exudate-6d_4":"132337048.0000","21_exudate-9d_1":"63645340.0000","22_exudate-9d_2":"70961344.0000","23_exudate-9d_3":"105829432.0000","24_exudate-9d_4":"31842298.0000","5_exudate-med-ctrl-_1":"21939168.0000","6_exudate-med-ctrl-_2":"46909588.0000","7_exudate-med-ctrl-_3":"6384815.5000","8_exudate-med-ctrl-_4":"26662508.0000","33_pellet-0d_1":"7967215.5000","34_pellet-0d_2":"913197.5600","35_pellet-0d_3":"1324756.6300","36_pellet-0d_4":"802558.2500","49_pellet-12d_1":"57441900.0000","50_pellet-12d_2":"54378264.0000","51_pellet-12d_3":"28609092.0000","52_pellet-12d_4":"9338222.0000","37_pellet-3d_1":"1022585.3800","38_pellet-3d_2":"1418966.8800","39_pellet-3d_3":"1003805.8100","40_pellet-3d_4":"1272085.3800","41_pellet-6d_1":"6436978.0000","42_pellet-6d_2":"10315288.0000","43_pellet-6d_3":"30556460.0000","44_pellet-6d_4":"27947394.0000","45_pellet-9d_1":"51227316.0000","46_pellet-9d_2":"45904328.0000","47_pellet-9d_3":"43957336.0000","48_pellet-9d_4":"47244640.0000","29_pellet-med-ctrl-_1":"408183.1900","30_pellet-med-ctrl-_2":"2156951.2500","31_pellet-med-ctrl-_3":"551511.1300","32_pellet-med-ctrl-_4":"689255.6300"},{"Metabolite":"shikimic acid","1_extr-ctrl--extr-ctrl-_1":"53041.9600","2_extr-ctrl--extr-ctrl-_2":"45804.3900","3_extr-ctrl--extr-ctrl-_3":"49092.6500","4_extr-ctrl--extr-ctrl-_4":"59177.4600","10_exudate-0d_2":"52599.7600","11_exudate-0d_3":"50415.1700","12_exudate-0d_4":"52080.6600","9_exudate-0d_1":"55007.0800","25_exudate-12d_1":"70960.2000","26_exudate-12d_2":"2138747.2500","27_exudate-12d_3":"2250536.7500","28_exudate-12d_4":"2548965.0000","13_exudate-3d_1":"53498.1500","14_exudate-3d_2":"59296.6200","15_exudate-3d_3":"49229.6700","16_exudate-3d_4":"51490.9800","17_exudate-6d_1":"59823.2000","18_exudate-6d_2":"53971.5900","19_exudate-6d_3":"45048.1300","20_exudate-6d_4":"45219.4000","21_exudate-9d_1":"1296636.7500","22_exudate-9d_2":"1738450.2500","23_exudate-9d_3":"53268.4800","24_exudate-9d_4":"57145.3500","5_exudate-med-ctrl-_1":"57596.0800","6_exudate-med-ctrl-_2":"51692.4100","7_exudate-med-ctrl-_3":"78453.8700","8_exudate-med-ctrl-_4":"55841.8300","33_pellet-0d_1":"51039.0600","34_pellet-0d_2":"53731.0200","35_pellet-0d_3":"42016.3100","36_pellet-0d_4":"71472.9500","49_pellet-12d_1":"59775.6500","50_pellet-12d_2":"95950.7300","51_pellet-12d_3":"36707.2500","52_pellet-12d_4":"71305.7600","37_pellet-3d_1":"51680.5900","38_pellet-3d_2":"59141.4400","39_pellet-3d_3":"41155.8000","40_pellet-3d_4":"55938.7000","41_pellet-6d_1":"106733.1300","42_pellet-6d_2":"75569.4100","43_pellet-6d_3":"80733.3400","44_pellet-6d_4":"74066.6500","45_pellet-9d_1":"80473.3400","46_pellet-9d_2":"107670.1400","47_pellet-9d_3":"83252.4000","48_pellet-9d_4":"142166.8300","29_pellet-med-ctrl-_1":"42201.8100","30_pellet-med-ctrl-_2":"75474.9200","31_pellet-med-ctrl-_3":"53155.8700","32_pellet-med-ctrl-_4":"42158.2500"},{"Metabolite":"tyrosine","1_extr-ctrl--extr-ctrl-_1":"17907.4900","2_extr-ctrl--extr-ctrl-_2":"12270.0800","3_extr-ctrl--extr-ctrl-_3":"101093.4500","4_extr-ctrl--extr-ctrl-_4":"21830.7300","10_exudate-0d_2":"17724.7900","11_exudate-0d_3":"13234.4700","12_exudate-0d_4":"15394.6700","9_exudate-0d_1":"10292.1300","25_exudate-12d_1":"19682.4300","26_exudate-12d_2":"17720.9100","27_exudate-12d_3":"20183.4500","28_exudate-12d_4":"41816.5200","13_exudate-3d_1":"13207.5800","14_exudate-3d_2":"16181.4100","15_exudate-3d_3":"11646.9600","16_exudate-3d_4":"17173.2600","17_exudate-6d_1":"13514.7800","18_exudate-6d_2":"13753.7800","19_exudate-6d_3":"14960.8200","20_exudate-6d_4":"32300.6500","21_exudate-9d_1":"16140.4600","22_exudate-9d_2":"17594.9400","23_exudate-9d_3":"25229.8000","24_exudate-9d_4":"19240.2500","5_exudate-med-ctrl-_1":"16229.7600","6_exudate-med-ctrl-_2":"19503.5700","7_exudate-med-ctrl-_3":"18703.1400","8_exudate-med-ctrl-_4":"14141.6000","33_pellet-0d_1":"12213.3100","34_pellet-0d_2":"17071.2800","35_pellet-0d_3":"16651.1000","36_pellet-0d_4":"13547.6700","49_pellet-12d_1":"194646.0200","50_pellet-12d_2":"91893.3000","51_pellet-12d_3":"325267.4400","52_pellet-12d_4":"257888.9800","37_pellet-3d_1":"11948.8900","38_pellet-3d_2":"17059.4800","39_pellet-3d_3":"22926.2700","40_pellet-3d_4":"23241.9000","41_pellet-6d_1":"34912.1100","42_pellet-6d_2":"37063.8600","43_pellet-6d_3":"107053.3200","44_pellet-6d_4":"102830.3100","45_pellet-9d_1":"60884.0800","46_pellet-9d_2":"74377.8800","47_pellet-9d_3":"202916.0500","48_pellet-9d_4":"159093.2800","29_pellet-med-ctrl-_1":"13800.2500","30_pellet-med-ctrl-_2":"13615.0500","31_pellet-med-ctrl-_3":"12869.8600","32_pellet-med-ctrl-_4":"13772.5000"},{"Metabolite":"xanthine","1_extr-ctrl--extr-ctrl-_1":"552667.9400","2_extr-ctrl--extr-ctrl-_2":"231310.0600","3_extr-ctrl--extr-ctrl-_3":"508936.9100","4_extr-ctrl--extr-ctrl-_4":"153456.9100","10_exudate-0d_2":"88973.6300","11_exudate-0d_3":"229599.9200","12_exudate-0d_4":"85686.0900","9_exudate-0d_1":"69512.7800","25_exudate-12d_1":"129925.5500","26_exudate-12d_2":"435933.8400","27_exudate-12d_3":"482207.0900","28_exudate-12d_4":"666052.6300","13_exudate-3d_1":"86978.5700","14_exudate-3d_2":"108649.7100","15_exudate-3d_3":"71491.6600","16_exudate-3d_4":"76513.6800","17_exudate-6d_1":"108831.8300","18_exudate-6d_2":"173295.8800","19_exudate-6d_3":"116879.4500","20_exudate-6d_4":"133747.9400","21_exudate-9d_1":"285746.5900","22_exudate-9d_2":"336023.4700","23_exudate-9d_3":"287358.6600","24_exudate-9d_4":"546839.7500","5_exudate-med-ctrl-_1":"86991.3900","6_exudate-med-ctrl-_2":"146875.7000","7_exudate-med-ctrl-_3":"169904.7300","8_exudate-med-ctrl-_4":"71109.6300","33_pellet-0d_1":"120952.3100","34_pellet-0d_2":"131348.6700","35_pellet-0d_3":"203346.9700","36_pellet-0d_4":"104131.7900","49_pellet-12d_1":"919044.9400","50_pellet-12d_2":"796933.9400","51_pellet-12d_3":"453190.5000","52_pellet-12d_4":"652353.9400","37_pellet-3d_1":"115427.7400","38_pellet-3d_2":"103879.8100","39_pellet-3d_3":"118393.9500","40_pellet-3d_4":"58295.8700","41_pellet-6d_1":"209612.0300","42_pellet-6d_2":"101879.3000","43_pellet-6d_3":"239503.0600","44_pellet-6d_4":"126907.3800","45_pellet-9d_1":"440424.3100","46_pellet-9d_2":"326716.0600","47_pellet-9d_3":"243264.0500","48_pellet-9d_4":"346473.7800","29_pellet-med-ctrl-_1":"63723.2300","30_pellet-med-ctrl-_2":"240622.3300","31_pellet-med-ctrl-_3":"100216.8200","32_pellet-med-ctrl-_4":"153348.1600"}],

"Metabolites":[{"Metabolite":"2-hydroxyphenylacetic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"1.11","ri_type":"","moverz_quant":"151.0401","":""},{"Metabolite":"2-methylmaleic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.10","ri_type":"","moverz_quant":"129.0194","":""},{"Metabolite":"2-oxovaleric acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"4.45","ri_type":"","moverz_quant":"115.0402","":""},{"Metabolite":"3-(4-hydroxyphenyl)lactic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"5.82","ri_type":"","moverz_quant":"181.0507","":""},{"Metabolite":"4-hydroxy-2-quinolinecarboxylic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"7.43","ri_type":"","moverz_quant":"188.0352","":""},{"Metabolite":"4-hydroxybenzoic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"1.63","ri_type":"","moverz_quant":"137.0244","":""},{"Metabolite":"4-pyridoxic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.55","ri_type":"","moverz_quant":"182.0458","":""},{"Metabolite":"5-hydroxyindoleacetic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"0.84","ri_type":"","moverz_quant":"190.051","":""},{"Metabolite":"adenine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.35","ri_type":"","moverz_quant":"134.0473","":""},{"Metabolite":"adenosine 5'-monophosphoric acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"14.77","ri_type":"","moverz_quant":"346.0561","":""},{"Metabolite":"carnosine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"16.75","ri_type":"","moverz_quant":"225.0991","":""},{"Metabolite":"dethiobiotin","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"1.88","ri_type":"","moverz_quant":"213.1243","":""},{"Metabolite":"formyl-methionyl peptide","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"4.99","ri_type":"","moverz_quant":"176.0386","":""},{"Metabolite":"galacturonic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"14.82","ri_type":"","moverz_quant":"193.0351","":""},{"Metabolite":"glutamic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"15.70","ri_type":"","moverz_quant":"146.0459","":""},{"Metabolite":"hypoxanthine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.81","ri_type":"","moverz_quant":"135.0313","":""},{"Metabolite":"indole-3-acetic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"1.03","ri_type":"","moverz_quant":"174.0560","":""},{"Metabolite":"indole-3-pyruvic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"0.85","ri_type":"","moverz_quant":"202.051","":""},{"Metabolite":"inosine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"4.79","ri_type":"","moverz_quant":"267.0729","":""},{"Metabolite":"isoleucine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"9.28","ri_type":"","moverz_quant":"130.0874","":""},{"Metabolite":"leucine/norleucine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"8.94","ri_type":"","moverz_quant":"130.0874","":""},{"Metabolite":"lumichrome","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"0.89","ri_type":"","moverz_quant":"241.0727","":""},{"Metabolite":"mandelic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"3.02","ri_type":"","moverz_quant":"151.0401","":""},{"Metabolite":"N-acetyl-hexosamines","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"6.93","ri_type":"","moverz_quant":"220.0825","":""},{"Metabolite":"N-acetyl-leucine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"3.22","ri_type":"","moverz_quant":"172.0979","":""},{"Metabolite":"n-acetyl-tryptophan","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"6.48","ri_type":"","moverz_quant":"245.0927","":""},{"Metabolite":"nicotinic/isonicotinic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"5.67","ri_type":"","moverz_quant":"122.0249","":""},{"Metabolite":"N-methyl-glutamic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"14.61","ri_type":"","moverz_quant":"160.0619","":""},{"Metabolite":"pantothenic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"6.86","ri_type":"","moverz_quant":"218.1032","":""},{"Metabolite":"phenylalanine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"8.69","ri_type":"","moverz_quant":"164.0717","":""},{"Metabolite":"proline","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"10.18","ri_type":"","moverz_quant":"114.0562","":""},{"Metabolite":"pterin","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"3.40","ri_type":"","moverz_quant":"162.0421","":""},{"Metabolite":"pyrrole-2-carboxylic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.18","ri_type":"","moverz_quant":"110.0249","":""},{"Metabolite":"salicylic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.17","ri_type":"","moverz_quant":"137.0245","":""},{"Metabolite":"shikimic acid","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"12.78","ri_type":"","moverz_quant":"173.046","":""},{"Metabolite":"tyrosine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"11.34","ri_type":"","moverz_quant":"180.0665","":""},{"Metabolite":"xanthine","pubchem_id":"","inchi_key":"","kegg_id":"","other_id":"","other_id_type":"","ri":"2.39","ri_type":"","moverz_quant":"151.026","":""}]
}

}