#METABOLOMICS WORKBENCH bkopp20_20181010_103752 DATATRACK_ID:1538 VERSION 1 CREATED_ON January 7, 2019, 1:01 pm #PROJECT PR:PROJECT_TITLE Environmental exposures and inflammation in young children with cystic fibrosis PR:PROJECT_TYPE NIH/NIEHS 1U2CES026560-01 PR:PROJECT_SUMMARY Secondhand smoke exposure (SHSe) is a common environmental factor known to PR:PROJECT_SUMMARY increase asthma severity and respiratory infections in children, as well disrupt PR:PROJECT_SUMMARY metabolic signals and host immune responses in patients with cystic fibrosis PR:PROJECT_SUMMARY (CF). This study defines biomarkers and metabolic profiles of SHSe (includes PR:PROJECT_SUMMARY ENDS exposure) in the young CF population and determines how SHSe impacts PR:PROJECT_SUMMARY regulation of infection, inflammation, and respiratory health. PR:INSTITUTE Emory University PR:DEPARTMENT School of Medicine PR:LABORATORY Clinical Biomarkers Laboratory PR:LAST_NAME Ma PR:FIRST_NAME Chunyu PR:ADDRESS 615 Michael Street, Atlanta, GA, 30322, USA PR:EMAIL chunyu.ma@emory.edu PR:PHONE (404) 727 5091 PR:FUNDING_SOURCE NIEHS ES026560 PR:CONTRIBUTORS Benjamin Kopp, MD #STUDY ST:STUDY_TITLE Environmental exposures and inflammation in young children with cystic fibrosis ST:STUDY_TYPE Untargeted high-resolution mass spectrometry profiling ST:STUDY_SUMMARY Secondhand smoke exposure (SHSe) is a common environmental factor known to ST:STUDY_SUMMARY increase asthma severity and respiratory infections in children, as well disrupt ST:STUDY_SUMMARY metabolic signals and host immune responses in patients with cystic fibrosis ST:STUDY_SUMMARY (CF). This study defines biomarkers and metabolic profiles of SHSe (includes ST:STUDY_SUMMARY ENDS exposure) in the young CF population and determines how SHSe impacts ST:STUDY_SUMMARY regulation of infection, inflammation, and respiratory health. ST:INSTITUTE Emory University ST:DEPARTMENT School of Medicine ST:LABORATORY Clincal Biomarkers Laboratory ST:LAST_NAME Ma ST:FIRST_NAME Chunyu ST:ADDRESS 615 Michael St. Ste 225, Atlanta, GA, 30322, USA ST:EMAIL chunyu.ma@emory.edu ST:PHONE (404) 727 5091 ST:TOTAL_SUBJECTS 92 ST:STUDY_COMMENTS Both CHEAR and Clinical Biomarkers Laboratory pooled plasma samples were used ST:STUDY_COMMENTS for quality control. Study specific sample pools were not created #SUBJECT SU:SUBJECT_TYPE Plasma samples SU:SUBJECT_SPECIES Homo sapiens SU:TAXONOMY_ID 9606 SU:AGE_OR_AGE_RANGE 4 months - 10 years #SUBJECT_SAMPLE_FACTORS: SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Additional sample data SUBJECT_SAMPLE_FACTORS Quality Control NIST SRM 1950_1_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_1a_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_007,VT_180710_M351_009,VT_180710_M351_011" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1a_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_013,VT_180710_M351_015,VT_180710_M351_017" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1b_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_019,VT_180710_M351_021,VT_180710_M351_023" SUBJECT_SAMPLE_FACTORS Serum Study Sample 3_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_025,VT_180710_M351_027,VT_180710_M351_029" SUBJECT_SAMPLE_FACTORS Serum Study Sample 4_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_031,VT_180710_M351_033,VT_180710_M351_035" SUBJECT_SAMPLE_FACTORS Serum Study Sample 5_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_037,VT_180710_M351_039,VT_180710_M351_041" SUBJECT_SAMPLE_FACTORS Serum Study Sample 6_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_043,VT_180710_M351_045,VT_180710_M351_047" SUBJECT_SAMPLE_FACTORS Serum Study Sample 7_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_049,VT_180710_M351_051,VT_180710_M351_053" SUBJECT_SAMPLE_FACTORS Serum Study Sample 8_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_055,VT_180710_M351_057,VT_180710_M351_059" SUBJECT_SAMPLE_FACTORS Serum Study Sample 8_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_061,VT_180710_M351_063,VT_180710_M351_065" SUBJECT_SAMPLE_FACTORS Serum Study Sample 9_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_067,VT_180710_M351_069,VT_180710_M351_071" SUBJECT_SAMPLE_FACTORS Serum Study Sample 10_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508 del /1898+1G>A; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_073,VT_180710_M351_075,VT_180710_M351_077" SUBJECT_SAMPLE_FACTORS Serum Study Sample 10_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508 del /1898+1G>A; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_079,VT_180710_M351_081,VT_180710_M351_083" SUBJECT_SAMPLE_FACTORS Serum Study Sample 11_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R74Q/R297Q; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_085,VT_180710_M351_087,VT_180710_M351_089" SUBJECT_SAMPLE_FACTORS Serum Study Sample 12_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R74Q/R297Q; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_091,VT_180710_M351_093,VT_180710_M351_095" SUBJECT_SAMPLE_FACTORS Serum Study Sample 14_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_097,VT_180710_M351_099,VT_180710_M351_101" SUBJECT_SAMPLE_FACTORS Serum Study Sample 15_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_103,VT_180710_M351_105,VT_180710_M351_107" SUBJECT_SAMPLE_FACTORS Serum Study Sample 23_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508del/Unknown; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_109,VT_180710_M351_111,VT_180710_M351_113" SUBJECT_SAMPLE_FACTORS Serum Study Sample 25_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_115,VT_180710_M351_117,VT_180710_M351_119" SUBJECT_SAMPLE_FACTORS Serum Study Sample 26_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, CFTR del 2,3"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_121,VT_180710_M351_123,VT_180710_M351_125" SUBJECT_SAMPLE_FACTORS Serum Study Sample 27_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=Delta F 508/Q493X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_127,VT_180710_M351_129,VT_180710_M351_131" SUBJECT_SAMPLE_FACTORS Serum Study Sample 28_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=" F508del, 3849 + 10kb C>T"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_133,VT_180710_M351_135,VT_180710_M351_137" SUBJECT_SAMPLE_FACTORS Serum Study Sample 29_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_139,VT_180710_M351_141,VT_180710_M351_143" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1c_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_145,VT_180710_M351_147,VT_180710_M351_149" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1d_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_151,VT_180710_M351_153,VT_180710_M351_155" SUBJECT_SAMPLE_FACTORS Serum Study Sample 30_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_157,VT_180710_M351_159,VT_180710_M351_161" SUBJECT_SAMPLE_FACTORS Serum Study Sample 31_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_163,VT_180710_M351_165,VT_180710_M351_167" SUBJECT_SAMPLE_FACTORS Serum Study Sample 32_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R560T/R1158X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_169,VT_180710_M351_171,VT_180710_M351_173" SUBJECT_SAMPLE_FACTORS Serum Study Sample 33_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_175,VT_180710_M351_177,VT_180710_M351_179" SUBJECT_SAMPLE_FACTORS Serum Study Sample 35_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=deltaF508/G542X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_181,VT_180710_M351_183,VT_180710_M351_185" SUBJECT_SAMPLE_FACTORS Serum Study Sample 35_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508/G542X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_187,VT_180710_M351_189,VT_180710_M351_191" SUBJECT_SAMPLE_FACTORS Serum Study Sample 36_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and G55.D Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_193,VT_180710_M351_195,VT_180710_M351_197" SUBJECT_SAMPLE_FACTORS Serum Study Sample 37_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and G55.D Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_199,VT_180710_M351_201,VT_180710_M351_203" SUBJECT_SAMPLE_FACTORS Serum Study Sample 38_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=DeltaF508/ c.2789+5G>A]; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_205,VT_180710_M351_207,VT_180710_M351_209" SUBJECT_SAMPLE_FACTORS Serum Study Sample 38_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_211,VT_180710_M351_213,VT_180710_M351_215" SUBJECT_SAMPLE_FACTORS Serum Study Sample 42_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_217,VT_180710_M351_219,VT_180710_M351_221" SUBJECT_SAMPLE_FACTORS Serum Study Sample 43_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_223,VT_180710_M351_225,VT_180710_M351_227" SUBJECT_SAMPLE_FACTORS Serum Study Sample 43_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_229,VT_180710_M351_231,VT_180710_M351_233" SUBJECT_SAMPLE_FACTORS Serum Study Sample 44_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/2789+5G->A; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_235,VT_180710_M351_237,VT_180710_M351_239" SUBJECT_SAMPLE_FACTORS Serum Study Sample 45_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=621+1G>T/Delta F508; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_241,VT_180710_M351_243,VT_180710_M351_245" SUBJECT_SAMPLE_FACTORS Serum Study Sample 47_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_247,VT_180710_M351_249,VT_180710_M351_251" SUBJECT_SAMPLE_FACTORS Serum Study Sample 49_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=l507del/2622+1G>A; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_253,VT_180710_M351_255,VT_180710_M351_257" SUBJECT_SAMPLE_FACTORS Serum Study Sample 50_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_259,VT_180710_M351_261,VT_180710_M351_263" SUBJECT_SAMPLE_FACTORS Serum Study Sample 51_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_265,VT_180710_M351_267,VT_180710_M351_269" SUBJECT_SAMPLE_FACTORS Serum Study Sample 52_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_271,VT_180710_M351_273,VT_180710_M351_275" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1e_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_277,VT_180710_M351_279,VT_180710_M351_281" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1f_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_283,VT_180710_M351_285,VT_180710_M351_287" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_1b_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_289,VT_180710_M351_291,VT_180710_M351_293" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_2a_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_001,VT_180711_M351_003,VT_180711_M351_005" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2a_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_007,VT_180711_M351_009,VT_180711_M351_011" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2b_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_013,VT_180711_M351_015,VT_180711_M351_017" SUBJECT_SAMPLE_FACTORS Serum Study Sample 54_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_019,VT_180711_M351_021,VT_180711_M351_023" SUBJECT_SAMPLE_FACTORS Serum Study Sample 55_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=160; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_025,VT_180711_M351_027,VT_180711_M351_029" SUBJECT_SAMPLE_FACTORS Serum Study Sample 58_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_031,VT_180711_M351_033,VT_180711_M351_035" SUBJECT_SAMPLE_FACTORS Serum Study Sample 59_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_037,VT_180711_M351_039,VT_180711_M351_041" SUBJECT_SAMPLE_FACTORS Serum Study Sample 60_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_043,VT_180711_M351_045,VT_180711_M351_047" SUBJECT_SAMPLE_FACTORS Serum Study Sample 61_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_049,VT_180711_M351_051,VT_180711_M351_053" SUBJECT_SAMPLE_FACTORS Serum Study Sample 63_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=180; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_055,VT_180711_M351_057,VT_180711_M351_059" SUBJECT_SAMPLE_FACTORS Serum Study Sample 64_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/ 2184delA); Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_061,VT_180711_M351_063,VT_180711_M351_065" SUBJECT_SAMPLE_FACTORS Serum Study Sample 65_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="deltaF508, R 553X"; Volume (uL)=180; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_067,VT_180711_M351_069,VT_180711_M351_071" SUBJECT_SAMPLE_FACTORS Serum Study Sample 67_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508/Y1092X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_073,VT_180711_M351_075,VT_180711_M351_077" SUBJECT_SAMPLE_FACTORS Serum Study Sample 67_Visit_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype=deltaF508/Y1092X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_079,VT_180711_M351_081,VT_180711_M351_083" SUBJECT_SAMPLE_FACTORS Serum Study Sample 68_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="Delta F508, p.S489X "; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_085,VT_180711_M351_087,VT_180711_M351_089" SUBJECT_SAMPLE_FACTORS Serum Study Sample 69_Baseline_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_091,VT_180711_M351_093,VT_180711_M351_095" SUBJECT_SAMPLE_FACTORS Serum Study Sample 71_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F4508del/ R117H (5T/9T; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_097,VT_180711_M351_099,VT_180711_M351_101" SUBJECT_SAMPLE_FACTORS Serum Study Sample 72_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R553X/DeltaF508.; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_103,VT_180711_M351_105,VT_180711_M351_107" SUBJECT_SAMPLE_FACTORS Serum Study Sample 73_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508Del/F508Del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_109,VT_180711_M351_111,VT_180711_M351_113" SUBJECT_SAMPLE_FACTORS Serum Study Sample 74_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_115,VT_180711_M351_117,VT_180711_M351_119" SUBJECT_SAMPLE_FACTORS Serum Study Sample 75_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=165; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_121,VT_180711_M351_123,VT_180711_M351_125" SUBJECT_SAMPLE_FACTORS Serum Study Sample 76_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and 621+1G>T; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_127,VT_180711_M351_129,VT_180711_M351_131" SUBJECT_SAMPLE_FACTORS Serum Study Sample 78_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=R1162X/E193X; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_133,VT_180711_M351_135,VT_180711_M351_137" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2c_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_139,VT_180711_M351_141,VT_180711_M351_143" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2d_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_145,VT_180711_M351_147,VT_180711_M351_149" SUBJECT_SAMPLE_FACTORS Serum Study Sample 79_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/R785/S1235R; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_151,VT_180711_M351_153,VT_180711_M351_155" SUBJECT_SAMPLE_FACTORS Serum Study Sample 80_Baseline_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_157,VT_180711_M351_159,VT_180711_M351_161" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncH_001_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=nch_001; CF genotype=F508del/3120+1G>A; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_163,VT_180711_M351_165,VT_180711_M351_167" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCH_002_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=nch_002; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_169,VT_180711_M351_171,VT_180711_M351_173" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCH_003_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=nch_003; CF genotype="F508del, Y1092X"; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_175,VT_180711_M351_177,VT_180711_M351_179" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_7_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_7; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_181,VT_180711_M351_183,VT_180711_M351_185" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_12_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_12; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_187,VT_180711_M351_189,VT_180711_M351_191" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_15_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_15; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_193,VT_180711_M351_195,VT_180711_M351_197" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_30_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_30; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_199,VT_180711_M351_201,VT_180711_M351_203" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_31_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_31; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_205,VT_180711_M351_207,VT_180711_M351_209" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_32_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_32; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_211,VT_180711_M351_213,VT_180711_M351_215" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_48_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=hc_48; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_217,VT_180711_M351_219,VT_180711_M351_221" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_60_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=hc_60; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_223,VT_180711_M351_225,VT_180711_M351_227" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_62_1 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_62; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_229,VT_180711_M351_231,VT_180711_M351_233" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_64_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_64; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_235,VT_180711_M351_237,VT_180711_M351_239" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_106_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=ncf_106; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_241,VT_180711_M351_243,VT_180711_M351_245" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCF_108_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_108; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_247,VT_180711_M351_249,VT_180711_M351_251" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_110_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_110; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_253,VT_180711_M351_255,VT_180711_M351_257" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_112_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_112; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_259,VT_180711_M351_261,VT_180711_M351_263" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_114_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_114; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_265,VT_180711_M351_267,VT_180711_M351_269" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2e_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_271,VT_180711_M351_273,VT_180711_M351_275" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2f_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_277,VT_180711_M351_279,VT_180711_M351_281" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_2b_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_283,VT_180711_M351_285,VT_180711_M351_287" SUBJECT_SAMPLE_FACTORS Quality Control NIST SRM 1950_2_1 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: HILICpos; Date Analyzed->10523=Date Analyzed->10523; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_289,VT_180711_M351_291,VT_180711_M351_293" SUBJECT_SAMPLE_FACTORS Quality Control NIST SRM 1950_1_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_002,VT_180710_M351_004,VT_180710_M351_006" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_1a_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_008,VT_180710_M351_010,VT_180710_M351_012" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1a_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_014,VT_180710_M351_016,VT_180710_M351_018" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1b_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_020,VT_180710_M351_022,VT_180710_M351_024" SUBJECT_SAMPLE_FACTORS Serum Study Sample 3_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_026,VT_180710_M351_028,VT_180710_M351_030" SUBJECT_SAMPLE_FACTORS Serum Study Sample 4_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_032,VT_180710_M351_034,VT_180710_M351_036" SUBJECT_SAMPLE_FACTORS Serum Study Sample 5_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_038,VT_180710_M351_040,VT_180710_M351_042" SUBJECT_SAMPLE_FACTORS Serum Study Sample 6_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_044,VT_180710_M351_046,VT_180710_M351_048" SUBJECT_SAMPLE_FACTORS Serum Study Sample 7_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_050,VT_180710_M351_052,VT_180710_M351_054" SUBJECT_SAMPLE_FACTORS Serum Study Sample 8_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_056,VT_180710_M351_058,VT_180710_M351_060" SUBJECT_SAMPLE_FACTORS Serum Study Sample 8_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_062,VT_180710_M351_064,VT_180710_M351_066" SUBJECT_SAMPLE_FACTORS Serum Study Sample 9_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_068,VT_180710_M351_070,VT_180710_M351_072" SUBJECT_SAMPLE_FACTORS Serum Study Sample 10_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508 del /1898+1G>A; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_074,VT_180710_M351_076,VT_180710_M351_078" SUBJECT_SAMPLE_FACTORS Serum Study Sample 10_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508 del /1898+1G>A; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_080,VT_180710_M351_082,VT_180710_M351_084" SUBJECT_SAMPLE_FACTORS Serum Study Sample 11_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R74Q/R297Q; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_086,VT_180710_M351_088,VT_180710_M351_090" SUBJECT_SAMPLE_FACTORS Serum Study Sample 12_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R74Q/R297Q; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_092,VT_180710_M351_094,VT_180710_M351_096" SUBJECT_SAMPLE_FACTORS Serum Study Sample 14_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_098,VT_180710_M351_100,VT_180710_M351_102" SUBJECT_SAMPLE_FACTORS Serum Study Sample 15_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_104,VT_180710_M351_106,VT_180710_M351_108" SUBJECT_SAMPLE_FACTORS Serum Study Sample 23_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508del/Unknown; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_110,VT_180710_M351_112,VT_180710_M351_114" SUBJECT_SAMPLE_FACTORS Serum Study Sample 25_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_116,VT_180710_M351_118,VT_180710_M351_120" SUBJECT_SAMPLE_FACTORS Serum Study Sample 26_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, CFTR del 2,3"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_122,VT_180710_M351_124,VT_180710_M351_126" SUBJECT_SAMPLE_FACTORS Serum Study Sample 27_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=Delta F 508/Q493X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_128,VT_180710_M351_130,VT_180710_M351_132" SUBJECT_SAMPLE_FACTORS Serum Study Sample 28_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=" F508del, 3849 + 10kb C>T"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_134,VT_180710_M351_136,VT_180710_M351_138" SUBJECT_SAMPLE_FACTORS Serum Study Sample 29_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_140,VT_180710_M351_142,VT_180710_M351_144" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1c_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_146,VT_180710_M351_148,VT_180710_M351_150" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1d_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_152,VT_180710_M351_154,VT_180710_M351_156" SUBJECT_SAMPLE_FACTORS Serum Study Sample 30_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_158,VT_180710_M351_160,VT_180710_M351_162" SUBJECT_SAMPLE_FACTORS Serum Study Sample 31_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_164,VT_180710_M351_166,VT_180710_M351_168" SUBJECT_SAMPLE_FACTORS Serum Study Sample 32_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R560T/R1158X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_170,VT_180710_M351_172,VT_180710_M351_174" SUBJECT_SAMPLE_FACTORS Serum Study Sample 33_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_176,VT_180710_M351_178,VT_180710_M351_180" SUBJECT_SAMPLE_FACTORS Serum Study Sample 35_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=deltaF508/G542X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_182,VT_180710_M351_184,VT_180710_M351_186" SUBJECT_SAMPLE_FACTORS Serum Study Sample 35_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508/G542X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_188,VT_180710_M351_190,VT_180710_M351_192" SUBJECT_SAMPLE_FACTORS Serum Study Sample 36_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and G55.D Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_194,VT_180710_M351_196,VT_180710_M351_198" SUBJECT_SAMPLE_FACTORS Serum Study Sample 37_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and G55.D Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_200,VT_180710_M351_202,VT_180710_M351_204" SUBJECT_SAMPLE_FACTORS Serum Study Sample 38_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=DeltaF508/ c.2789+5G>A]; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_206,VT_180710_M351_208,VT_180710_M351_210" SUBJECT_SAMPLE_FACTORS Serum Study Sample 38_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_212,VT_180710_M351_214,VT_180710_M351_216" SUBJECT_SAMPLE_FACTORS Serum Study Sample 42_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_218,VT_180710_M351_220,VT_180710_M351_222" SUBJECT_SAMPLE_FACTORS Serum Study Sample 43_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=visit_2; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_224,VT_180710_M351_226,VT_180710_M351_228" SUBJECT_SAMPLE_FACTORS Serum Study Sample 43_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_230,VT_180710_M351_232,VT_180710_M351_234" SUBJECT_SAMPLE_FACTORS Serum Study Sample 44_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/2789+5G->A; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_236,VT_180710_M351_238,VT_180710_M351_240" SUBJECT_SAMPLE_FACTORS Serum Study Sample 45_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=621+1G>T/Delta F508; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_242,VT_180710_M351_244,VT_180710_M351_246" SUBJECT_SAMPLE_FACTORS Serum Study Sample 47_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_248,VT_180710_M351_250,VT_180710_M351_252" SUBJECT_SAMPLE_FACTORS Serum Study Sample 49_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=l507del/2622+1G>A; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_254,VT_180710_M351_256,VT_180710_M351_258" SUBJECT_SAMPLE_FACTORS Serum Study Sample 50_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_260,VT_180710_M351_262,VT_180710_M351_264" SUBJECT_SAMPLE_FACTORS Serum Study Sample 51_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_266,VT_180710_M351_268,VT_180710_M351_270" SUBJECT_SAMPLE_FACTORS Serum Study Sample 52_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_272,VT_180710_M351_274,VT_180710_M351_276" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1e_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_278,VT_180710_M351_280,VT_180710_M351_282" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_1f_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_284,VT_180710_M351_286,VT_180710_M351_288" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_1b_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->1; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180710_M351_290,VT_180710_M351_292,VT_180710_M351_294" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_2a_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_002,VT_180711_M351_004,VT_180711_M351_006" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2a_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_008,VT_180711_M351_010,VT_180711_M351_012" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2b_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_014,VT_180711_M351_016,VT_180711_M351_018" SUBJECT_SAMPLE_FACTORS Serum Study Sample 54_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_020,VT_180711_M351_022,VT_180711_M351_024" SUBJECT_SAMPLE_FACTORS Serum Study Sample 55_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=160; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_026,VT_180711_M351_028,VT_180711_M351_030" SUBJECT_SAMPLE_FACTORS Serum Study Sample 58_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_032,VT_180711_M351_034,VT_180711_M351_036" SUBJECT_SAMPLE_FACTORS Serum Study Sample 59_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_038,VT_180711_M351_040,VT_180711_M351_042" SUBJECT_SAMPLE_FACTORS Serum Study Sample 60_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_044,VT_180711_M351_046,VT_180711_M351_048" SUBJECT_SAMPLE_FACTORS Serum Study Sample 61_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_050,VT_180711_M351_052,VT_180711_M351_054" SUBJECT_SAMPLE_FACTORS Serum Study Sample 63_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=180; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_056,VT_180711_M351_058,VT_180711_M351_060" SUBJECT_SAMPLE_FACTORS Serum Study Sample 64_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/ 2184delA); Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_062,VT_180711_M351_064,VT_180711_M351_066" SUBJECT_SAMPLE_FACTORS Serum Study Sample 65_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="deltaF508, R 553X"; Volume (uL)=180; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_068,VT_180711_M351_070,VT_180711_M351_072" SUBJECT_SAMPLE_FACTORS Serum Study Sample 67_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508/Y1092X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_074,VT_180711_M351_076,VT_180711_M351_078" SUBJECT_SAMPLE_FACTORS Serum Study Sample 67_Visit_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=visit_2; CF genotype=deltaF508/Y1092X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_080,VT_180711_M351_082,VT_180711_M351_084" SUBJECT_SAMPLE_FACTORS Serum Study Sample 68_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="Delta F508, p.S489X "; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_086,VT_180711_M351_088,VT_180711_M351_090" SUBJECT_SAMPLE_FACTORS Serum Study Sample 69_Baseline_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_092,VT_180711_M351_094,VT_180711_M351_096" SUBJECT_SAMPLE_FACTORS Serum Study Sample 71_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F4508del/ R117H (5T/9T; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_098,VT_180711_M351_100,VT_180711_M351_102" SUBJECT_SAMPLE_FACTORS Serum Study Sample 72_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=R553X/DeltaF508.; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_104,VT_180711_M351_106,VT_180711_M351_108" SUBJECT_SAMPLE_FACTORS Serum Study Sample 73_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508Del/F508Del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_110,VT_180711_M351_112,VT_180711_M351_114" SUBJECT_SAMPLE_FACTORS Serum Study Sample 74_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_116,VT_180711_M351_118,VT_180711_M351_120" SUBJECT_SAMPLE_FACTORS Serum Study Sample 75_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype="F508del, F508del"; Volume (uL)=165; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_122,VT_180711_M351_124,VT_180711_M351_126" SUBJECT_SAMPLE_FACTORS Serum Study Sample 76_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=deltaF508 and 621+1G>T; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_128,VT_180711_M351_130,VT_180711_M351_132" SUBJECT_SAMPLE_FACTORS Serum Study Sample 78_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=baseline; CF genotype=R1162X/E193X; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_134,VT_180711_M351_136,VT_180711_M351_138" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2c_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_140,VT_180711_M351_142,VT_180711_M351_144" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2d_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_146,VT_180711_M351_148,VT_180711_M351_150" SUBJECT_SAMPLE_FACTORS Serum Study Sample 79_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/R785/S1235R; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_152,VT_180711_M351_154,VT_180711_M351_156" SUBJECT_SAMPLE_FACTORS Serum Study Sample 80_Baseline_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F Sample Matrix=Serum; Event Name=baseline; CF genotype=F508del/F508del; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_158,VT_180711_M351_160,VT_180711_M351_162" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncH_001_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=nch_001; CF genotype=F508del/3120+1G>A; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_164,VT_180711_M351_166,VT_180711_M351_168" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCH_002_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M Sample Matrix=Serum; Event Name=nch_002; CF genotype="F508del, F508del"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_170,VT_180711_M351_172,VT_180711_M351_174" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCH_003_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=nch_003; CF genotype="F508del, Y1092X"; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_176,VT_180711_M351_178,VT_180711_M351_180" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_7_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_7; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_182,VT_180711_M351_184,VT_180711_M351_186" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_12_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_12; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_188,VT_180711_M351_190,VT_180711_M351_192" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_15_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_15; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_194,VT_180711_M351_196,VT_180711_M351_198" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_30_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_30; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_200,VT_180711_M351_202,VT_180711_M351_204" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_31_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_31; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_206,VT_180711_M351_208,VT_180711_M351_210" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_32_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_32; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_212,VT_180711_M351_214,VT_180711_M351_216" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_48_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=hc_48; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_218,VT_180711_M351_220,VT_180711_M351_222" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_60_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=hc_60; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_224,VT_180711_M351_226,VT_180711_M351_228" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_62_2 INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_62; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_230,VT_180711_M351_232,VT_180711_M351_234" SUBJECT_SAMPLE_FACTORS Serum Study Sample hc_64_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=hc_64; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_236,VT_180711_M351_238,VT_180711_M351_240" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_106_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M Sample Matrix=Serum; Event Name=ncf_106; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_242,VT_180711_M351_244,VT_180711_M351_246" SUBJECT_SAMPLE_FACTORS Serum Study Sample NCF_108_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_108; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_248,VT_180711_M351_250,VT_180711_M351_252" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_110_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_110; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_254,VT_180711_M351_256,VT_180711_M351_258" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_112_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_112; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_260,VT_180711_M351_262,VT_180711_M351_264" SUBJECT_SAMPLE_FACTORS Serum Study Sample ncf_114_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F Sample Matrix=Serum; Event Name=ncf_114; CF genotype=-; Volume (uL)=200; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_266,VT_180711_M351_268,VT_180711_M351_270" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2e_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_272,VT_180711_M351_274,VT_180711_M351_276" SUBJECT_SAMPLE_FACTORS Serum Study Sample chearplasma_2f_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Serum; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Serum; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_278,VT_180711_M351_280,VT_180711_M351_282" SUBJECT_SAMPLE_FACTORS Quality Control Q-Std Plasma pool_2b_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_284,VT_180711_M351_286,VT_180711_M351_288" SUBJECT_SAMPLE_FACTORS Quality Control NIST SRM 1950_2_2 INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Sample Matrix=Plasma; Event Name=-; CF genotype=-; Volume (uL)=-; combine="Column_Ionization_type: C18neg; Date Analyzed->10523=Date Analyzed->6853; Batch->1=Batch->2; CHEAR_Project_ID->2018_PF02=CHEAR_Project_ID->2018_PF02; Sample.Matrix->Plasma=Sample.Matrix->Plasma; Raw files->VT_180710_M351_001,VT_180710_M351_003,VT_180710_M351_005"=Raw files->VT_180711_M351_290,VT_180711_M351_292,VT_180711_M351_294" #COLLECTION CO:COLLECTION_SUMMARY Blood plasma samples were collected from nonfasting participants in the CO:COLLECTION_SUMMARY Aspirin/Folate Polyp Prevention Study [1, 2] at enrollment (baseline) and after CO:COLLECTION_SUMMARY three years of study treatment. Blood samples were collected in tubes containing CO:COLLECTION_SUMMARY EDTA and after centrifugation aliquots of plasma were transferred to 1.8 ml CO:COLLECTION_SUMMARY freezer tubes and stored in a -70C freezer. The samples were shipped on dry ice CO:COLLECTION_SUMMARY from the clinical centers to the Dartmouth biorepository storage facility and CO:COLLECTION_SUMMARY subsequently to the metabolomics analysis lab at Emory University. CO:SAMPLE_TYPE Serum CO:STORAGE_CONDITIONS Described in summary #TREATMENT TR:TREATMENT_SUMMARY Samples were received frozen in aliquouts of <250uL. Prior to analysis, samples TR:TREATMENT_SUMMARY were thawed and prepared for HRM analysis using the standard protocols described TR:TREATMENT_SUMMARY in the Sample Preparation section. #SAMPLEPREP SP:SAMPLEPREP_SUMMARY Samples were prepared for metabolomics analysis using established SP:SAMPLEPREP_SUMMARY methods(Johnson et al. (2010). Analyst; Go et al. (2015). Tox Sci). Prior to SP:SAMPLEPREP_SUMMARY analysis, plasma aliquots were removed from storage at -80 degrees C and thawed SP:SAMPLEPREP_SUMMARY on ice. Each cryotube was then vortexed briefly to ensure homogeneity, and 50 SP:SAMPLEPREP_SUMMARY microliters was transferred to a clean microfuge tube. Immediately after, the SP:SAMPLEPREP_SUMMARY plasma was treated with 100 microliters of ice-cold LC-MS grade acetonitrile SP:SAMPLEPREP_SUMMARY (Sigma Aldrich) containing 2.5 microliters of internal standard solution with SP:SAMPLEPREP_SUMMARY eight stable isotopic chemicals selected to cover a range of chemical SP:SAMPLEPREP_SUMMARY properties. Following addition of acetonitrile, urine was equilibrated for 30 SP:SAMPLEPREP_SUMMARY min on ice, upon which precipitated proteins were removed by centrifuge (14,000 SP:SAMPLEPREP_SUMMARY rpm at 4 degrees C for 10 min). The resulting supernatant (100 microliters) was SP:SAMPLEPREP_SUMMARY removed, added to a low volume autosampler vial and maintained at 4 degrees C SP:SAMPLEPREP_SUMMARY until analysis (<22 h). SP:SAMPLEPREP_PROTOCOL_ID HRM_SP_082016_01 SP:SAMPLEPREP_PROTOCOL_FILENAME EmoryUniversity_HRM_sample_preparation_082016_01.pdf SP:SAMPLEPREP_PROTOCOL_COMMENTS Date effective: 30 July 2016 SP:EXTRACTION_METHOD 2:1 acetonitrile: sample followed by vortexing and centrifugation #CHROMATOGRAPHY CH:CHROMATOGRAPHY_SUMMARY The C18 column is operated parallel to the HILIC column for simultaneous CH:CHROMATOGRAPHY_SUMMARY analytical separation and column flushing through the use of a dual head HPLC CH:CHROMATOGRAPHY_SUMMARY pump equipped with 10-port and 6- port switching valves. During operation of CH:CHROMATOGRAPHY_SUMMARY the "C18 method, the MS is operated in negative ion mode and 10 μL of CH:CHROMATOGRAPHY_SUMMARY sample is" injected onto the C18 column while the HILIC column is flushing CH:CHROMATOGRAPHY_SUMMARY with wash "solution. Flow rate is maintained at 0.4 mL/min until 1.5 min, CH:CHROMATOGRAPHY_SUMMARY increased to 0.5" "mL/min at 2 min and held for 3 min. Solvent A is 100% CH:CHROMATOGRAPHY_SUMMARY LC-MS grade water, solvent" B is 100% LC-MS grade acetonitrile and solvent C CH:CHROMATOGRAPHY_SUMMARY is 10mM ammonium acetate in "LC-MS grade water. Initial mobile phase CH:CHROMATOGRAPHY_SUMMARY conditions are 60% A, 35% B, 5% C hold" "for 0.5 min, with linear gradient to CH:CHROMATOGRAPHY_SUMMARY 0% A, 95% B, 5% C at 1.5 min, hold for 3.5" "min, resulting in a total CH:CHROMATOGRAPHY_SUMMARY analytical run time of 5 min. During the flushing" "phase (HILIC analytical CH:CHROMATOGRAPHY_SUMMARY separation), the C18 column is equilibrated with a wash" "solution of 0% A, CH:CHROMATOGRAPHY_SUMMARY 95% B, 5% C until 2.5 min, followed by an equilibration" "solution of 60% A, CH:CHROMATOGRAPHY_SUMMARY 35% B, 5% C for 2.5 min." CH:CHROMATOGRAPHY_TYPE Reversed phase CH:COLUMN_NAME Thermo Higgins C18 (50 x 2.1mm, 3um) CH:COLUMN_NAME size," "Product #TS-0521-C183; Thermo Accucore C18 guard column with holder, CH:COLUMN_NAME Product" #17126-014005 CH:FLOW_RATE 0.4 mL/min for 1.5 min; linear increase to 0.5 mL/min at 2 min held for 3 min CH:COLUMN_TEMPERATURE 60C CH:METHODS_FILENAME 20160920_negC18120kres5min_ESI_HILICposwash.meth CH:SOLVENT_A LC-MS grade water CH:SOLVENT_B LC-MS grade acetonitrile CH:METHODS_ID 10mM ammonium acetate in LC-MS grade water CH:SAMPLE_INJECTION 10 uL CH:ANALYTICAL_TIME 5 min CH:SAMPLE_LOOP_SIZE 15 uL CH:SAMPLE_SYRINGE_SIZE 100 uL CH:CHROMATOGRAPHY_COMMENTS Triplicate injections for each chromatography mode CH:INSTRUMENT_NAME Thermo Dionex Ultimate 3000 #ANALYSIS AN:ANALYSIS_TYPE MS AN:LABORATORY_NAME Clinical Biomarkers Laboratory AN:OPERATOR_NAME Vilinh Tran AN:DETECTOR_TYPE Orbitrap AN:SOFTWARE_VERSION Xcalibur 3.0.63 AN:ACQUISITION_DATE Jan-15 AN:ANALYSIS_PROTOCOL_FILE EmoryUniversity_HRM_QEHF-MassSpec_092017_v1.pdf AN:DATA_FORMAT Profile #MS MS:INSTRUMENT_NAME Thermo Q Exactive HF hybrid Orbitrap MS:INSTRUMENT_NAME Thermo Q Exactive HF hybrid Orbitrap MS:INSTRUMENT_TYPE Orbitrap MS:MS_TYPE ESI MS:ION_MODE NEGATIVE MS:MS_COMMENTS None MS:ACQUISITION_DATE Jan-15 MS:CAPILLARY_TEMPERATURE 250C MS:COLLISION_GAS N2 MS:DRY_GAS_FLOW 45 MS:DRY_GAS_TEMP 150C MS:MASS_ACCURACY < 3ppm MS:SPRAY_VOLTAGE -4000 MS:ACTIVATION_PARAMETER 5.00E+05 MS:ACTIVATION_TIME 118ms MS:INTERFACE_VOLTAGE S-Lens RF level= 55 MS:SCANNING_RANGE 85-1275 MS:MS_RESULTS_FILE ST001079_AN001762_Results.txt UNITS:Peak Area #MS_METABOLITE_DATA MS_METABOLITE_DATA:UNITS Peak Area MS_METABOLITE_DATA_START Samples NIST SRM 1950_1_2 Q-Std Plasma pool_1a_2 chearplasma_1a_2 chearplasma_1b_2 3_Baseline_2 4_Baseline_2 5_Baseline_2 6_Baseline_2 7_Baseline_2 8_Baseline_2 8_Visit_2_2 9_Baseline_2 10_Visit_2_2 10_Baseline_2 11_Baseline_2 12_Baseline_2 14_Baseline_2 15_Baseline_2 23_Visit_2_2 25_Baseline_2 26_Baseline_2 27_Baseline_2 28_Baseline_2 29_Baseline_2 chearplasma_1c_2 chearplasma_1d_2 30_Baseline_2 31_Baseline_2 32_Baseline_2 33_Baseline_2 35_Visit_2_2 35_Baseline_2 36_Baseline_2 37_Baseline_2 38_Baseline_2 38_Visit_2_2 42_Baseline_2 43_Visit_2_2 43_Baseline_2 44_Baseline_2 45_Baseline_2 47_Baseline_2 49_Baseline_2 50_Baseline_2 51_Baseline_2 52_Baseline_2 chearplasma_1e_2 chearplasma_1f_2 Q-Std Plasma pool_1b_2 Q-Std Plasma pool_2a_2 chearplasma_2a_2 chearplasma_2b_2 54_Baseline_2 55_Baseline_2 58_Baseline_2 59_Baseline_2 60_Baseline_2 61_Baseline_2 63_Baseline_2 64_Baseline_2 65_Baseline_2 67_Baseline_2 67_Visit_2_2 68_Baseline_2 69_Baseline_2 71_Baseline_2 72_Baseline_2 73_Baseline_2 74_Baseline_2 75_Baseline_2 76_Baseline_2 78_Baseline_2 chearplasma_2c_2 chearplasma_2d_2 79_Baseline_2 80_Baseline_2 ncH_001_2 NCH_002_2 NCH_003_2 hc_7_2 hc_12_2 hc_15_2 hc_30_2 hc_31_2 hc_32_2 hc_48_2 hc_60_2 hc_62_2 hc_64_2 ncf_106_2 NCF_108_2 ncf_110_2 ncf_112_2 ncf_114_2 chearplasma_2e_2 chearplasma_2f_2 Q-Std Plasma pool_2b_2 NIST SRM 1950_2_2 Factors INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:1 | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:1 | CF? 1=Yes 0=No:1 | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:1 | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:M INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:F INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- INFANT? 1=YES 0=CHILD:- | Smoke exposure? 1=Yes 0=No:- | CF? 1=Yes 0=No:- | Gender:- Serine 5203776.3 8367836.1 4473966.6 4207841.3 4363812.8 452348.2 10024444 7451299.5 4191158.3 5532325.6 8468322.8 7749282.9 5567039.6 7431616.1 6843184.3 7854770.7 10310960.1 2448130.7 6544412.5 6083656.2 5680581.5 7162699.6 8048081 7802528.4 3762874.5 3968346.4 8222324.5 9332065.1 7108676.7 7236218.6 6486604 8956129.9 9142928 9711375.3 4630495.5 5345522.1 5766704.5 7822744 5978373.2 5569644.7 6008213.2 6040390 6108863.1 5012859.7 6848359.5 5357444.9 3633749.1 3327387.5 5355080.7 5652875.2 4659314.3 4386714.9 6454886 6424232.5 6694193.2 8082169 8107441.4 8221666.2 7157688.4 5619029.7 6769057 4424825.6 7840754.2 6725580.8 7543858.2 8871634.4 6921681.6 9396540.5 8134511 8634136.3 6450803.4 7108761.7 4045736.7 4404799 10037755.8 6970313.6 4604197.4 5323733.4 5709696.6 6376542.1 7204871.8 5606036.6 5685640.1 5086260.4 6555070.4 8881313.1 8743939.2 6841147.6 4924484.3 1249155.2 1411475.3 936283.7 0 1556387.5 5486263.9 4380955.6 3249458.2 5192665.6 Glyceric acid 32666193.7 24986020.6 30855626.4 26868947 33655816.4 0 63060218.5 42844597.6 22835807.9 0 33369916.6 491224.4 66863995.5 67893474.6 28226562.8 49418003.2 37040335.9 22291364 83079058.7 9292749.5 39626066.7 57028750.1 82808127.7 36819308.1 32159255 31814405.9 112527627.9 48945263.5 91554322.6 51190408.3 31685655.4 0 97795158.2 55934759.4 0 76914781.5 84914835.6 77801895.3 44080745 39775511.1 62309946.1 45340404.1 42552542.6 32923447.7 36980449.8 58411396.1 20906908.4 24870423.8 20311824 28067786.2 12838398 27537585.7 35094537.9 31238648.9 29952481.6 22464060.9 34295781.7 36732471.2 29516930.7 45907350.8 24784953.3 14711440.7 45116511.2 49957362 48953986.9 39700538.1 53198810.4 68962841.4 49680545.5 45004466.4 66108603.9 47672276.5 26675763.1 29819561.2 45501316.9 62159785 168207723.2 242139366.9 210987334.4 29710691 35645289 20054842.7 38010400.1 46945007.8 39555623 37645355.6 41642476.6 21327656.1 23238602.8 18268642.5 21053631.4 17932283.9 15148376.3 18610677.3 25948707.7 25325255.4 24242255.9 27129644.8 Creatinine 4042161.4 10160703 6088129.6 4906824.8 2844930 1438739.1 2680249.5 2345121.5 1244135.3 1406670.1 4879988.7 1608037.9 2517351 2233233.8 3289113.3 3291709.4 2901645.7 1686412.1 2912908.3 3545205.7 2676320.9 2213724 2273843 2710445.2 6094555.1 6000247.5 2955623.3 1883960.2 1869812.7 4293675.4 2031186.1 1487578.1 2431621.4 2104120.1 1477982.6 2688480.3 2578325 2923507.5 1177360.2 2126800.9 2286876.8 2117374.8 3180493.8 3156788.8 2979347.8 1413380.6 6576533.5 6590270.6 6248568.3 5603441.4 5871986.4 6261729.6 3488816.7 1883450.8 5683501.5 6392671.8 2388180.2 2059275.9 2369930.6 2187501.7 1759763.6 1736984.7 2120409.4 1650122.3 3059806.3 3125408.1 2742609.8 1749398.4 1779440.6 2872821.2 2672772.1 2416168.6 5607142.8 6847170.4 1702135.1 1434107.9 2420159.4 2452090 1736243.6 2228177.8 1510181.4 2736525.9 1721385.3 1707782.8 3027727.8 1835497 2870625.8 2003405.6 2343109.2 3040835.2 1668646.8 1656205.1 2103992.4 1702246.7 6488393.4 6253296.3 5638886.3 7410818.2 Mesoxalic acid 292948.2 1631694.5 332560.8 379049.2 281502 1577496.2 300072.5 292981.6 5176239.2 2125435.1 157281.8 5163291 270877.2 279007.2 142701.3 201370.5 141399 185560.6 172052.6 147159.4 164205.5 186862 63593.4 184248.9 183029.8 105153.9 344383.3 237238.4 166875.3 179945.2 164317 3293728.3 143059.7 170200 2982161.4 148093.9 152778.3 186845.8 229831.1 143989.9 172093.8 153377.5 123212.6 150983 148394.8 155995 104294 594822.6 104746.7 114744.7 0 0 186390.4 231938.6 0 923584.1 131204.4 103876.8 1015321.5 5015.8 0 3238435.7 247455.7 0 0 0 192737.8 99130.1 187638.3 2189270 99878.5 142048.8 0 0 0 0 145791.7 0 109310 0 0 174476.7 975400.1 74423.4 24880.5 2851420.9 231326.1 0 50328.5 0 0 0 0 1020502.9 0 0 0 0 4-Hydroxybenzaldehyde 7899825.7 27799801.4 125587837.7 120687759.8 131998121.6 96212195.4 21980263.2 108273670.3 5304613.9 4378971.3 40027179.7 6178976.7 30314623.4 25996261.6 22454568.3 5538865.3 22272973 5169260.2 72586039.3 24870904.7 5922811.2 5971512.1 4962355.5 25268208.5 111758807.6 144933348.8 4121256.4 3452514.2 35118990 4047592.2 13157731.4 15688142.3 31203789.7 39608794.9 5916232.4 23544974.1 10201409.2 25944432.7 23474429.2 5678843.1 6098651 7045221.9 26710020.7 6547661.3 4553558.1 24025915.4 115692921.2 102961337.3 23169802.9 17939376.2 104993387.4 107829614.3 20375148.1 72538237.8 22214476.2 28202614.9 282322.3 0 0 0 869883.7 1191845 23889945.6 0 32721427.6 22151424.6 22311311.8 23638663.2 33628610.3 710233.4 15291047 30881684.7 120745104 133937811.3 22257263.7 54626101.7 2637870.7 0 38748271.7 69616076.9 54029503.9 24762538.2 28970604.8 2616054.9 19861138.5 1029552.6 15547197.8 79430202.2 16830006.2 10870225.5 10388385.2 67695701.9 0 33282578.9 135609177.8 119345000.4 126026450.6 21763266.8 Ureidopropionic acid 1610673.2 706070.7 1266535.4 1183865.8 5631082.6 0 7045014 1138694.3 758901.9 0 1594860.8 0 3841341.1 3316865 6562129.8 8171418.9 7372445.8 329625.9 2778441.4 4587661.1 3194384.2 7591732.6 8294200.8 6763886.5 1141072.3 1924616.4 10547112.1 7060105.1 7501923.2 7492778.1 6854059 553479.9 7419548 7276055.3 306376.9 6664240.8 6842686 8727888.6 5677134.2 5164976.1 6540617.4 5292273.9 3356788.6 5990441.2 5783440.5 8200101.1 2174224.7 2609756 1751321.2 1442884.1 1568574.3 1814702 6774065.3 6729201 7619394 5375703.4 7247492 6694065.5 3879513.6 3226184.4 7416988.9 0 8132392 7022198.2 7132447.1 6065596.1 8444866.5 8542353 6431061.3 5814853 12325636.5 8570552.5 1712735.1 753070.3 6082083.4 5923679.1 3065399.3 4718286.2 2240313.9 3387132.5 2987717.1 1106554.6 1165005.4 2529080.8 4948447.6 8892955.2 6942489 5101025.4 4104990.1 637179.6 909024.3 911568.1 2887405.5 2392615.6 2083607.5 2764817.5 2758016.5 3563671.2 Aspartic acid 0 42844133.6 22934915.7 22079207.5 13217476.4 49165455.2 42558808.9 35076933.8 13918700.3 20307526.9 12112353.8 36959977.9 27805365.1 34690295.6 37912147.8 39625265.8 33702269.3 5204551.2 30718867.6 23021056.1 51136972.1 25304174.3 15830589.1 48580773.2 19596927.4 25119870.7 5927058.9 42333212.3 23825994.4 17486980.3 24413904.3 25811572.7 46985951.3 24884134.6 7773851.5 17901893 24391518.1 30011407.8 42297822.1 30672074.9 30025406.1 17449947.8 18416337.3 25129251.6 25616148.4 17412756 20028835.8 20316441.6 37853582.5 33546312.3 21481599.4 20169294.2 14335333.6 18124696.8 18806571.6 13435673.6 21089089.2 25557833 30405972.6 14834095.1 21378469 12803703.8 24502547.4 36147654.3 16142317.1 39967987 22464452.5 20619942.3 20100705.2 24348622.8 18809214.6 40196381.5 22425404 25865045.4 32117875.1 16391982.9 45337458.3 92775415 52757159.8 16033686.1 12551486.6 11602427.9 17282145 14592117.8 17794566.7 17728249.8 19055615 15952015.6 13714705.8 35780900 39317447.8 44105624.1 30387579.8 27886721.8 17963723.7 23301762.7 21995413.2 33170990.4 Hypoxanthine 6943619.7 113311803.8 41729200.6 48422608.4 126903231.9 8918467.3 414848394.2 341565199.6 201020182.1 203399778 177275426.3 309178186.5 156322850.6 221446904.6 234805119.8 248214258 321921763.5 56874196.4 279048628.7 139005496 423918611.3 250448431.1 248190173.8 271869917.8 17735758.8 24480294.3 239924818.3 154849186.6 315374307.1 164435064.4 210526772.6 443720167.4 416844982.1 224191849.2 197533294.8 286343027.5 311584450.7 280209230.7 457169939.4 223212076.7 238043068.1 211864106.2 155095807.5 161462313.2 137888360.6 248552306.9 43196770.1 33273780.5 125390303.3 125313272.2 62117208.7 62807959.6 157088444.5 98692785.3 184573512.5 148620571.2 276242761.2 318355622.7 142911641.9 347386754.6 171798679.9 219546313.6 368629105.2 546917098.9 288298914.4 373296948.1 302265534.6 398660116.2 269129518.4 254608805.5 317864288.8 397115241.6 67776768.5 69854386.6 415883853.9 297394971.5 126042913.4 251691477.1 204356688.4 212389892.1 236691965.7 170445628.8 216137518.1 209017933.4 286152179.5 235811778.2 259920343.1 197500849.5 165608141.2 43933848 48309797.6 29706410.3 28303289.8 46354586.8 63094100.5 62264600.1 53982285 144701533.2 Phenylacetic acid 1683658.4 2417118.6 6691526 5759868.8 1844895.6 1755763.1 1635982.4 1744065.2 1477307.4 1816617.5 628236.9 1761853.6 1669540.4 1856156.6 2717752.8 1776892.8 2545067.7 1819527.1 1592491.4 3106140.3 1756806.7 1724624 2902846.4 2304779.9 5515214.4 2020706.2 1140392.5 3255978.4 3480458.5 1131742.5 2299060.6 1771827.5 1695152.3 5034192.6 1733184.6 1827950.8 2904484.9 1993047.9 1027278.7 2714760.2 1793998.1 1239951.6 891883.7 2170325.8 3478367.3 1346284.2 5314169.6 5386454.7 1616624.1 1640132.3 3729417.2 4280641.5 2414216.7 2499793.8 1691654.7 1960642.6 2598327.5 2343599.7 2901419.6 733222.2 7395823.7 2068556.5 2035913 1560570.2 3041828.9 1856784.7 1892694.9 1934343.2 1897602.5 1860867.7 1759891.1 1786835.1 4171086.6 4884843.1 1997852 1827625.9 1953739.8 1821493.9 1894584 2157862.3 2071420.1 2000883.1 9921155.2 1354651.9 1836013.1 2553912.3 1827522.4 1932024 1908052.2 1712497.8 2023297.3 1919682.6 1630039.3 1645457.3 4315664.7 4264476.3 3079401 1598380.4 Salicylamide 1162004.8 2147486.9 2244115.7 1977129.2 5321718.4 8661545.4 1504765.8 1535032.6 1275881.4 4225985.9 1215138.3 4451058.2 1305811.9 2556035 1218419.3 3415236.3 1242416.5 2753098.3 1239484.7 1470108.7 1266277.3 1261095.2 1191771.3 1180118.2 1694879 1412811.5 2782482.7 1264848.8 1320094.6 1238945.5 4051695.1 4227635.3 1247971.4 2731447.3 4900896.8 1192840 1163616.8 3399460.1 1146511.2 1201350.2 1145111.9 3261675.6 1126820.6 2238765.5 2369819.2 3359579.5 1399628.4 1433249.2 1350539.2 1487449.7 1602098.3 1534982.5 3139197.4 1005712.1 2793850.5 4461353.1 3246319.8 977403 1135207.9 3422603.2 1170272.2 3630060.2 1242071 4041020.8 1428353.2 1554130.8 862057.4 4693232.8 1193365.2 1085458.9 978843.8 1077747.5 1592626.8 1804136.9 1155175.6 1027997.1 1168117.4 2975793.1 1064117.4 3067038 1358387.1 1251970.1 5189900.2 1270799.1 3164918.4 1053713.8 1153753.3 1043046.6 1095895.3 1003858 3110674.5 3910326.4 3879261.1 2737527.3 1281090.1 1335342.5 1291289.8 1459411.4 Caprylic acid 10287291.4 78989246.3 1973432.5 2360374.1 2135968.2 2377256.3 5967420.6 1590489.4 4010272.9 7486857.7 1875938.2 8769801.4 2131415.7 2862184.9 1823786.8 1890097.9 1427835.8 4975786.7 2109672.3 1120729.2 2249402.7 2092850.5 2402277.9 1057483.7 2590750 1155723.7 2397087.8 2100958.3 1998488.3 1943424.5 1832432.3 3741807.3 32837653.6 3441052.4 1713591.6 4206259.5 2219570.3 6162367 1460651.9 2140803.3 2351262.1 1104436 2090126.2 2091331.2 1615756 1213920.6 956335.7 1030869 24792977.2 27459407.9 529813 0 160573.3 5228359.3 1036496 541908.2 20169338 8102341 1129398.5 0 0 9345792.9 298428 1089804.2 0 457260.9 16798218.5 11676357.9 18284033.6 1622933.5 62054497.5 3543192.4 1065689.4 0 12952955.5 2661685 3447889.9 3154010.2 15181756.7 0 0 769075.1 0 0 0 9298986 804369.9 0 0 147668.1 0 402055.6 92001.1 520235.7 0 532095 0 31569973.7 Oxoglutaric acid 12012796.2 19610657.5 32989472.1 32108952.5 21385981.9 0 18489006.4 12549796.4 0 5082903.5 15630472.6 365095.4 12782003.4 23421016.3 12014897.9 7756998.9 10911731.1 0 14799517.4 10551849.6 7677805.9 19027454 8391687.6 12760488.5 39480945.9 41725517.6 8795506.4 10415218 13086737.1 11420912.3 17463113 537702.4 12360854.2 12228486.9 4900163.1 12837369.5 12803601.5 14913460.1 6688552.5 5473994.6 14006211.1 10348919.1 12318395.7 11409592.6 9786655.8 11541625.9 36717469 35420102.7 33814342.3 29490626.2 29630424 33075322.3 10034294.6 6046025.6 14644218.7 3611243.9 12882317.4 6565116.1 14098121 11552299.7 11852856.9 4644555.2 10497853.4 8988126.1 12671680.3 10125556.8 19794481.5 16040170.3 18062805.5 15129200.1 14377964.1 11932961.8 37167888.7 42538539 9466846.5 10841170 13320867.5 17494711 24858159.3 14051949.9 13377173.4 8865412.5 11430195 9787136.4 9267680.7 8295612.6 14802334.1 9610254.1 10256147.4 1186134.1 1335166.5 1257561.3 845109.1 1039243.5 39703125.2 40952133.2 33978998.8 28888715.6 Glutamine 82453190.9 36178504.3 44962644.3 42313134.3 63182753.4 4386794 130881508.3 89959903.7 32041111.5 6640118.3 88717867.3 7777909.5 86180217 82127743.3 92684331.2 100110226 88398876 5768435.6 68934020 94623154.4 70464544.9 77685174 120669287.2 89000635 45998172.3 50176982.5 104293704.9 87926491.5 86207088.2 87168052 70039096.1 8153019.3 99585747.7 99564833.5 4508343.6 91557367.3 70929614.6 84182021 91895640.1 76571612.9 85998115.5 85920289.9 82400673.3 97519207.5 85813075.1 75233381.6 46524911.6 49810580 41242364.3 26372705.9 38311566.8 34932143.5 87687355.9 77752805.5 105086259.7 96579069.6 112732254 86052529.9 63291953.6 74469733.9 82037229.5 0 73867250.1 95645343.3 85353962.2 101414174.5 104952420.8 115379684.9 94277345.5 113801738.9 68711457.9 80173029.3 40605007 40893916.5 118400446.6 95394363.6 71228116.3 102334784.4 89395377.2 86675526 99814171.5 90228008.2 83790948.3 66840073.1 95112195.2 66419560.5 123742791 91274982.4 77409651.9 33085433.6 32345403.8 25058133.7 25253793.3 28720733.7 38336796.4 39502575.4 40009244 22708819.7 trans-Cinnamic acid 0 2310582 0 0 792405.6 150099.1 1677070.1 1846230.5 0 0 1416161.9 0 1655326.6 1295060.1 1114293.4 1270096.3 1265194.5 156034.2 1764264.1 1714678.6 2306368.5 1353120.9 3155865.8 452120.1 0 0 5347303.3 967526.5 3612022.9 3703891.8 1982051.7 151493.6 0 1591483.1 0 1636962.3 2014808.9 2749339 1755021.2 433046.1 2340796 676713.5 341132 682166 1313897 1957159.4 6442190.9 0 0 0 0 0 947826.9 2591038.3 3160181.1 4160230.5 3100834.2 4154984.6 2158996.2 1702480.9 1585054.6 0 652652.5 0 1634928.7 3493120.7 3378760.9 1433402.8 1189793.3 1669161.3 2859104.5 2053412.5 89290.7 0 2248030.2 1368036.6 0 0 0 1635292.5 2091240.7 2870211 1396718.4 2083997.3 1653776.8 1294325.9 1666860.6 1453453 1132271.5 2334349.7 81950.9 0 10366.8 674649.2 0 0 805852.4 0 Methionine 4714270.2 6817686.2 5000120 4652333.7 1948174.9 0 5321783.8 4957293.5 1597336.7 3777523.3 3555914.2 4827927.2 2575987.1 4076745.3 6503323.4 6921346 7784876.6 2857799.6 4986234.9 6572483.3 2044746.4 3581715.5 10282018.8 4935099 5263354.6 4828858 9404355.8 6178291.4 5158791.9 7044354.4 2851885.6 3751607.8 6694290.6 6880025.3 4053975.8 3393603.8 3590393 9164880.9 4667810.9 2555856.3 3561611.6 3363098 4936136.1 4345559.4 3140100.1 3198885.9 4778903.9 5491263 6299644.4 5669292.8 5160911.6 4695067.2 3413925.8 6945267.6 7375713.6 6710061.5 8622338.1 7734889.1 4549978.5 4211138.6 4279006.4 2653110.4 8403700.2 3185275.1 4729183.9 4891981.7 9006471.5 5920325.5 4129930.9 4314861.7 8286709.7 3924437.5 4969898 4699006.7 7490712.3 5403759.4 2059553.5 5577238.2 3945806.8 2960943.3 3583971.3 6778458.8 2064921.3 3465797.9 3946726.1 6316572.9 6121384.4 2610870.8 1910988.6 3039948 2132374.7 3188085.9 2857307.3 4496447.6 5950169.6 4806046.5 5017119.3 6241233.5 Xanthine 0 2469667.2 0 1026368.3 3753929 6604196.6 7649432.5 7589287.4 1937340.3 1454463.8 4884028.9 4569265.4 6380400.9 8351135.2 4367496.2 6452094.2 2149945.3 2921143.5 4379121 4521604.7 6116340.7 6017458.5 9241543.9 4343534.1 2259824.1 8263697.9 3147146.9 7739516 5350215.9 4714201.7 4417299 6237956.8 9242837.7 5870805.4 6598264.9 5240956.8 4634182.2 4992199.7 4196450.7 3220644.7 4033801.9 7161252.5 4141819.3 5682553.4 3204286.6 5821653.1 5508795.5 0 3073687.5 2775607 8864844.6 3145705.1 3888433.8 5439192.4 5083729.2 4398999 3883397.8 3510381.5 4942058.2 3867083.9 4085180.1 2887597.9 4859588 4718830.2 3853544.3 6676586.5 4449450.5 4900716.6 8159727.8 8796108.9 5376666.4 5406112 15211027.8 6896102.1 5298583 4138980 2680528.5 0 4132609.9 6007419.9 5278666.3 3776241.2 5823175.9 5102719.7 6667972.5 4128903.5 8051560.6 4837399 4457616.8 4589021.6 0 0 0 0 3169360.9 2420987.2 2494116.5 3584957.9 Histidine 31707820.3 37245270 34451477.2 28242354.7 24137165.6 2065339.9 41330898.7 33050758 7874613.2 10260430.3 33581310.6 13068106.8 32857214.1 32789182.5 37162338.5 47494818 35495178.7 7555879.4 24106006.4 30261490.6 22785367.4 34823373.6 53400484 34880347.6 34284526.8 32951652 47953195.8 44325573.3 46775655.1 46995031 30994943.6 11570424.6 38443507.6 41552565.3 11323443.1 35844785.2 36006635.2 50157264.8 40516843.4 29654365.1 39063733.4 31086930.6 32531718.4 49069177.3 35651733.4 40916703.4 32414477.3 20514501.7 32661344 34801967.9 23208505 22655523.8 37116106 36684764.6 54042339.2 39156286.2 37741143.8 44931486.5 28134699 30118889.4 39479547.8 12558928.4 60177112 38949036.9 31923257.2 42743494.8 50413705.5 44960831.9 29859049.5 38126934.8 36384139.5 37120558.5 22100391.1 23972812.9 45534995.2 32039945.9 24846813.9 25142596.9 25303650.6 26647257.9 36653357.1 31956947.1 29331175.2 32993257.7 28901871 36103887.3 37351964.1 26802125.3 29451389.7 11432354.2 8537785.5 11936396.3 9411671.2 8748087.9 19723650 19277966.3 17126873.4 30572809.1 Pelargonic acid 2245210.7 26209617.5 3470830.3 2146893.1 2788734.5 3242756.5 2427554.3 2706865.2 3480818 2406277.2 1900173.1 3853966.5 1527812.3 4619353.6 3358545.2 1892613.2 1608113.1 2103508.2 1803577.4 2179970 4897191.9 2372565.1 2051946 4082315.7 1163404 1242172.4 1700470.6 3380983.2 2568644.4 1275416.1 1564426.6 11456130.5 6429501 2358633.9 5348048.1 3444846.5 3130203.6 4543572.5 3318604.2 3081463.4 2196712.4 3377509 2688388.3 2015224.7 2689792.6 2509915.6 1112056.6 1439664.4 1447889 1422173.5 806455.4 507958.6 1933543.1 2629921.5 1297719.3 2301021.5 4401675.4 6350804.2 21110053.5 1744468.9 4852621.6 6266548.3 3847617.8 8097892.4 2729711.2 8544889.9 3294781.6 1551688.8 3175692.3 1490683.8 2206006 3879212.6 1049283.5 1812299.1 5743426.1 844469.1 998280.2 1318737.5 1227730.5 2970901.2 1755213 1754980.6 1748942.1 2381065.1 3229336 3374322.8 2972827.5 3389302.4 2813011.6 1333998.8 2010215.7 1195809.9 1176867.3 1187027.2 919429.5 967190.3 1178480.8 1600833.4 Indoleacetaldehyde 1156384.8 1779453.3 538286.1 592922.1 954414 747927.9 995463.6 746043 665811.8 1011403.9 816132.4 462777.1 771847.3 636612.3 1023060.5 1129571.7 1094674.9 926838.4 535083.2 732033.7 168167.2 910447.2 339990.5 695823.3 548435.7 478333.9 1459169.5 1654859.4 1068659.2 978802.4 872561.1 1013314.6 941944.3 1064174.2 915143.6 849477.3 906522.3 1517999.3 1003039 931882.3 1375017.9 994836.1 1018734.1 729671.4 1000459.1 1024073.8 603545.2 589858.7 691402.5 666583 545323.4 612746.5 978899.2 889784.2 997069.8 347855.7 1055357.9 986176 1017584.2 950748 1461108.7 630672.9 1080117.3 1194888.3 360895.6 1102752.3 1686521.7 378792.8 1090594.6 1082249.7 1251338.4 874450.5 775147.1 819138.7 1536641.6 285222.4 644329.8 865415.8 917033.2 1149839.6 1402521.6 1040714.1 1090015.9 1113369.1 1083238.5 1164167.2 1876486.6 1073265.1 1033543 823332.5 721607.8 730236 729324.7 841271.6 551081.1 577131.7 687015.4 768576.6 Aminoadipic acid 641397.2 1877035.4 601165.2 495366.8 592053.2 411625.1 1212433.3 862087.2 2014354.8 1143708.9 870749.4 1800882.7 1419228.2 999824.1 851394.4 820883.7 1200406.9 316664.6 518237.7 801573 1097129.7 1090325 1051690.4 1134105 708891 753235.9 825832.9 967329.5 868377.8 892052.9 1234794.7 1599625.2 1914864.8 911766.8 1109539.4 1126978 921229.9 1255532.1 905404.1 1075253.6 2498154.4 1135478.6 974804.3 1336789.2 1528277.7 640585.2 775288.2 844140.1 943581.3 958463.7 744917.1 709991.9 878102.3 666695.4 1226123.7 1005287.2 1032712.2 910061.9 867704.8 946540.5 1253336.7 977476.8 1335294.7 1059801.7 763498 1149394.5 2301110.4 1777637 1100585.3 1286274.4 1756450.1 1044229.8 787447.6 1120026.2 1235593.9 1084610.5 2352013.1 1561122.1 2152097.9 1039203.9 1175093.8 1537298.7 1347851.2 1182487.9 1077928 1057274 1180714.3 726198.1 1197506.7 449640.3 325145.4 354187.4 324903 284652.3 1116241 904956.7 744396.3 1118857.3 Phenylalanine 30880708 63821888.9 28815124 29350263.6 26852512.6 5751196.4 47815505.3 39717693.4 27437719.1 12315668.1 34089832.2 27873267.1 33608382.1 40995701.7 68850537.7 63715385 54484480.4 19002911.8 56778728.1 27610209.9 54531805.7 53461465.4 60548797.6 41632152 30641541.5 32911768.6 71025854.1 67969927.6 62107296.5 56428521.4 37777698.8 23706858.8 54338388 40374218.8 14224853.9 35000063.6 47052227.8 70981863.1 52031668.2 44554305 38526555.3 28752142.6 38372804.7 43881808.3 40400165.1 39614620.9 32169812.8 31331514.3 43857134.7 44749033.6 29641487.1 31117041.5 51064031.5 56248096.7 65110365.7 77227812.2 65374694.1 48666364.3 53503040 30252718.6 43878362.8 27532775.6 75883228.5 46229402.5 40624507.7 35031602.2 52401230.4 44612150.6 33016679.7 30808809.9 66263801.5 65518445.6 31087005.6 34402414.1 63157578.1 39905241.1 24883401.5 38338353.2 29241698.5 35180231.3 27597962.9 32826508.6 31136944.3 27702274 33078750.4 52243914.8 39495336 20797621.6 29998918.5 21398526.6 20465218 20425195.1 17344053.2 18377668.6 33356123.5 30520575.4 33105633.4 52782947.7 3-(2-Hydroxyphenyl)propanoic acid 7720249.2 8113116.3 5570844 6356107.8 9584227.1 2528908.4 15674207.1 72815034.8 4474743.5 4829236 30137407 13359816.8 15260231 9934773.7 16840435.8 18283334 21839610.7 9065130.4 27401089.1 32190775.2 28718319.1 24153083.8 23069695.3 16097215.5 6741452.2 7474973.7 15127014.9 16134382.7 25644999 25165181 9446330.6 11584150 22455888.5 20464056.8 17602580.6 15334127.2 21397458 22806141.3 12550788 31927214.1 16709768.3 19008453.8 12506505.3 11913044.3 11037310.2 16443646.6 4772862.4 4838789.1 11178174.4 9027493.6 7906240.1 8014000.4 16176707.2 16700761.6 16714482.6 25131413.3 33479697.9 16307262.8 22519690 16244856.1 27913755.8 13292254.1 18408480.7 17026457 34683141.3 15721528.9 23373153.8 8960390.1 31791085.9 20985115.8 11853580 15243059 7843940.1 8777482.4 77785777 8852532.8 6250224.2 5500628.9 6430986.3 23771270 33864285.4 16617859.5 14324795.2 23874403.2 23487067.1 18134790.9 22511410.7 19095663.2 12532831.4 6419207.4 5936696.5 5115156.4 4448540.8 6575062.8 6650489.6 7817370 5246461.3 11435521.1 Uric acid 311963113.2 315902258.1 276475848.9 284885745.9 281131815 101920543 205508729 238227669.3 119351373.8 138176359.7 336563569.9 260047119.7 392915174.4 539319403.5 306407131.2 398592958.9 427203964.5 68132402 233415311.3 438070129.4 302757671 425697261.8 265318733 460808737.8 296478441.2 308782514 264582756.7 238528763.8 400743671.7 388478243.8 466358589.8 151929611.7 350075664.3 419603778.7 143325654.9 286699744.6 431096735.3 267858800.8 379145587.6 338928501.8 386651872.3 329590954.8 291470864.5 368975061.5 383024959.4 382788967 320702054.4 304598984.1 337889643.9 326029470.6 305931277 305161655 446019884 530837089.4 416218077.6 289013804.7 232338489.3 133587076.7 189881512.4 444683027.3 297015887.3 138123303.7 324293216 449752651.6 277859795 384587310.3 393033215.9 283474077.8 266136505.6 383712884.6 266438336.9 310775358.4 326959741.4 359897090.7 299113457.7 260972136.9 326128753.7 305537152 295455771.4 452749907.3 335572068.1 280953466.4 375791067.4 509611799.3 413863232 424168372.3 310691890.1 284944495.4 334987126.5 208003330.5 129142447.2 190052783.8 65629542.5 103893082.1 339538680.6 333714138.1 307658452.4 335798052.6 N-Acetylasparagine 116492.9 559376.3 953666.4 232003.4 102170.1 0 109330.5 0 159062.9 202030.1 0 192897.3 144847.7 137706.4 105754.9 128746.4 0 51702 819937.1 1350343.1 0 183400.2 575689.6 0 217505.8 142591.8 118766.8 1024199.2 0 129456.4 46194.1 125870.6 409060.1 152568.8 117769.8 93956.2 2033526 90726.3 186578.6 0 176141.1 121428.7 0 158870 145440.9 1294787.9 355462.5 431280.4 508149.9 306693.1 161754 207387.6 0 95730.2 169418 286413.4 0 0 0 0 253932.2 125019.9 226843.7 123938.6 187897.1 142543.9 219821.6 256706.4 128034.8 227149 111284.8 0 277698.4 195994.2 252834.7 0 1214933.8 2553645.1 1253874.5 194764.2 552034.2 265476.2 230627.3 322781.6 110350.3 308281.8 136673.5 272563.9 0 413010.5 499710.7 362746.8 97232.8 145203.6 278742.5 720664.2 261093.3 225146.9 Suberic acid 0 2493280 1411678.6 931004.2 1609508.8 60418247.2 8325725.8 10677825 4538264.8 4771419.2 4106304.8 10297419.8 3733155.5 13765300.9 13910411.6 6597556.7 7006182.2 826390.9 464387.1 9431160.4 10176383.4 4526392.7 1052693.4 11822498.7 692555.6 1006053.1 1040842.3 4745014.3 5320595.5 1209971.1 11555736.2 19697191.2 17410077.6 5262549.9 2875280.5 7134095.8 4858045 15120140.2 6426418.7 5374149.4 3567644.2 5697266.5 3707226.2 1429440.4 4676008.3 5651795.3 403363.6 581497.7 265719.1 2734953.4 3066488.3 3415597.1 3010890.9 3656338.7 4913157.1 3605189.6 4646478.4 6675687.8 68914140.1 4701207.1 5787354.4 3492085 4484843.9 5995431.2 3017140.6 14948219.6 3769336.7 3748511.1 4511497 6312648.6 7179779.4 15502739.7 1793002.7 1764696.5 7041210 3734742.8 2847069.8 3367636.8 3295149 7307060.7 4040883.3 3957933.6 4048847.4 3750416.2 6479918.8 5906105.8 5474578 8168605.8 3559340 2666880.6 2863826.8 2331322.4 2702600.8 2768085.9 1986079.4 1724100.1 3634487.8 3007666 N-Acetyl-L-aspartic acid 732321.7 10618438.6 10418609.9 6085852.8 602572.6 0 1116491.5 797578.7 4872864.4 5935729.6 501914.2 2600402.8 490498.7 838498.2 1027996 0 1681397.3 355883.9 465390.9 470800.6 452472.9 562232.4 488583.6 899232.2 8928797.3 11752140.4 617397.1 495675.5 442603 396080.3 4425110 2082769 1060283.9 489378 882588.7 358979 3392169.9 1531699.1 479399.5 0 378558.1 437402.5 0 503182.6 352957.4 307742.3 8260098.7 11183209.7 10561703.3 9828241.6 4675455.7 4682898.3 466490 279262.7 578713.9 454887.5 317027.6 667505.4 350918.7 344257.1 517170.8 618328 672732.6 542321.2 434812.2 620960.7 867124 1541673.7 851174.1 661990.3 523136.4 790653 6964854.2 8602615 736599.3 503389.5 13297186.1 15565307 15519465.9 686848.6 639699.2 796893 450434.5 673765.8 539949.1 412730.1 520663 417597 369391.4 3980647.9 6541907.8 4807882.3 2776065.6 4843977.7 7508076.2 7715843.4 6561131 7989070.1 Indoleacetic acid 8216775.2 10653006.2 6677949.5 7131840.7 3760271.7 22514836.7 5282191.2 7107205 2044016.2 4115893.1 5816553.8 3560446 18429034.8 3828843.3 11457771 9615409.6 13568458.4 1487644.7 13981983.2 11468911.9 4746536 9344441.5 11674620 6230736.7 6697511.2 8918118.2 9781326.6 8770163.2 7611258.8 12699984.9 8388246.5 4550473.7 10778794.5 4846374.2 2979732.7 5873553.7 12379817.7 10956361.2 7765051.5 25110396.6 10711048.4 61963325.4 34226682.6 8700812.7 13428036 31488807.6 5643512.3 5942428.7 7544017.8 7508500.1 5469132.8 5844360.1 4408378.6 15350371.3 15453785 12615912.3 11668671.3 6788255.9 10832983.9 16853539.4 59984454 2094241.8 23473024.5 10264960.6 23121991.7 8146561.9 20728580.6 11794468.6 7501184.7 11825394 6503749.8 7339562.4 6451673.7 6827499.4 36188530.4 9367945.4 14051813.2 4036738.5 7732005.2 6925427.9 12119119 10706724.1 7357316.8 12660090.5 8635726.9 6169317.1 4698896.2 5809178 8110139.6 3904457.6 1376293.5 1612047.6 1330414.6 2325080.4 6141786.8 6156271.3 6136769.5 9357467.1 Citrulline 5250945.4 1339658.8 3602526.1 2198936.2 4356453.2 5088095.9 2598931.9 4428937.1 2957816.4 1803112.5 1881238 2891775.1 7228682.3 6975444.1 3773678 5777757.1 7384914.9 1177438.7 1970752.9 5069816.5 5945861.9 6064817.6 2597753.8 5720653.4 2652191.7 3381785.4 6016655.4 3520286.4 7993363.7 7869446.2 2491461.2 4029394.7 2911957 5163801.2 2312536.1 4773430.3 2951168 3214324 6785976.4 709435.7 5446497.7 6772811.6 2889501.4 6827936.6 7361793.6 5942072.4 2577390.4 3285321.3 1427536.6 2218440 2946285.2 2713240.6 7690713 6783568.1 6301558.2 4677996.4 7267212.4 4492185 7114551.4 1828855.3 8721163.9 3371931.1 7454355.2 5761022.3 6386380.3 4150377.5 7051464.6 3695203.7 3220990.3 4716847.5 2869334 1507617.4 4281496.6 2974322.3 3823942.6 7467056.9 1892356.8 3675206.1 3879691.1 3032532.8 3288355.4 3628626.8 2701567.1 1571757.2 2714180.9 2716477.4 2728269.9 3181075.8 6980791.4 1852813.2 1421276.6 2001847 2525061.9 2112041.7 4254783.5 3516173 4201827.9 2664349.4 Hippuric acid 35082698.1 60533288.1 35982489.7 36086519.6 18914228.6 6206893.6 8734230.4 8127842.7 10564038.7 15146961.6 46635261.6 12447408.1 77007745.4 15990473.4 26105081.2 23189306.6 40883251.4 15351598.2 45059401.1 11007310.3 8653938.5 68108981.2 106686057 12714134.6 36963926.2 41404104.6 16488471.1 16110254.8 26700731.1 23600656.5 59506996.5 11292736 22046483.9 9947672.9 18172231.9 7066773.6 17268910.9 30493970.8 13253834.8 77632093.5 9125496.3 418826584.1 62834359.9 12873899.3 8447180 11093417.4 39853209.8 37610091 99597261.1 124330920.8 47621265.2 48161206.7 3257808.5 12981341.6 18028415.8 19697145.5 4851565 136067817.4 0 40911049.5 20110654.2 12132680.9 22301159.5 12836610.2 53210079.4 0 18433918.8 6055202.9 5978752.7 7999641 63417895.6 54158637.4 52627231.2 58493173.7 19059445.2 0 0 36524792 18014558.9 0 20557458 254571265.5 48194911 0 148926466.2 0 0 7857242 2012213.6 7028839.2 0 51788284.4 0 17504125.6 47482389 52555454 37834902.3 171339027 Tyrosine 21427853 38923140.2 23880178.8 25386074.6 22940581.1 7598763.4 31068643.7 13157631.1 18310088.1 16836709 12156856.4 36160640.8 21132367 16932329 39180135 47349761.1 38830631.5 17279132 10647195.1 27551169.6 37212663.4 29347541 86624180.8 26264567.1 24582952.3 25647631.8 53758289.4 39707433 28711940.7 39910372.1 16438790.8 12790287.7 37296357.1 21704542.3 15148530 15031692.6 25275253.5 38330652.6 20172007.1 21333796.8 27060422.8 18993673.3 20722311.7 25800986.7 27015780.8 18228122.7 23609096 25185594.3 30103921.3 29904096.5 24159484.6 23467546.7 35692250.3 45448083 43790082.7 42598392 49512981.8 29233461.6 31801911.1 19469840.3 32868597.8 17733039.3 43351763.7 22139743.9 44192736.4 16889801.6 33371036.8 36917960 21278189.8 23833757.2 44744155.1 18193825.3 22064720.1 26235239.3 43654097 36096886.7 11454734.6 32466147.3 26335037 15206438 24278241.2 20694110.3 17732394.5 13588658.9 22446090 46911737.2 37116802.2 8892160.9 14160237.9 8505592.5 7840680 6440248.2 1894728.3 8639221.8 24943436 23044913.4 22790477 36208449.8 N-Acetylglutamic acid 2265661.7 4831889.4 4431207.6 3823427.9 545141.3 0 339512.7 0 649704.1 946701.8 757861.7 861308.7 0 2499797.2 2586211.3 0 0 0 363254.8 441142 327221.4 3944881.3 12501019.6 0 0 0 8953115 392455.8 316476.5 0 450075.2 704067.7 5063258.8 406348.5 396350.1 456208.6 329437.6 400881.9 301031.5 1826836.5 493852.1 6274460 3397692.5 3680615.9 494029.9 1701860.9 0 0 0 4761714.2 4586371.3 4470987.9 2781168.1 0 5191111.1 0 1342777.3 7783087.1 0 0 2492874.7 167439.8 375546.1 101730.4 322086.9 478640.1 4811178.8 418478 598741 432274.2 9722945 0 4585610.9 1681758.2 0 0 0 425420 544705.6 159823.6 511497.1 285798.7 147449 0 2116817.2 0 385836.6 259644.7 107116.9 60395.5 80203.1 0 97556.6 21226.4 5026291 0 182572.6 5150674.3 5-Hydroxyindoleacetic acid 0 0 0 0 0 345259.5 0 0 6567647.3 2031242.8 0 0 0 0 0 0 0 2296118.1 0 0 0 0 0 0 0 0 0 0 0 0 1526625 0 0 0 0 0 0 0 0 1639007.6 1728197.4 0 0 1539809 0 2058025 0 0 0 0 0 0 0 1348811.3 1536865.1 0 0 0 0 0 0 4167749.9 1762437.8 0 726209.9 2366382.6 4441154.1 0 3616285.2 1901653.7 2873277.6 2427636.6 0 0 1460910.2 1359072.6 0 0 5313627.4 0 1130927 1283939.4 908676.9 950724.6 3262465.7 1371502.7 1245977.7 0 977529.9 0 0 0 0 0 0 0 0 6131019.9 Quinic acid 2403535.2 2573671 637136.8 447011.4 6108461.6 661021.9 664752.9 415551.1 702277.4 424514.7 9559395.5 445894.7 517926.2 584310.8 422998 326193.8 359654.5 494409 404905.3 492275.4 419859 602846.4 458832.7 580497.1 561493 1948457.8 386474.3 783891.3 4885160.8 3356677.1 3177876.9 703518.5 540861 505144.1 369550.5 411974.9 935491.6 2843131.4 370872.4 4051068.9 3254002.5 386380.2 411916 476080.6 388779.8 663062.3 563020.2 892520.7 1394267.7 1500012.2 813255.2 873124.7 517180 636393.8 6912014.4 630066.6 532292.7 600352.6 620122.3 629608.3 583036 612644 808244.8 589069.2 6861537.4 493524.6 590805.1 523862.6 509322.8 947147.7 603369.2 482306 1188745.8 1334189.1 663234.4 521930.4 615932.2 559815.7 650922.9 550029.5 597574.7 605940.1 666723.2 479593.9 749843.8 497898.3 527581.6 693192.5 716117.9 8883700.5 707303.6 512978.2 580561.6 491935.1 1755768 1950666.5 1682818.8 2671462.5 12-Hydroxydodecanoic acid 3569811.7 5187725.5 5449893 5731851.6 5297540.9 4604951.8 20572746 29088771.9 9193504.3 5073012.2 9331238.1 9371449.2 12133251.8 25202123.1 17982810.6 9887991.8 12525795.8 5561373.1 6639568.6 22349138.4 18239202.2 7262938.4 10236185.3 18334544.2 4033669.7 3720843.1 6151158.9 5705902.1 6989215.1 3415507.3 7166279.5 16490081.4 20745948.2 10150958.9 19279574 20130229.6 8783368 12312222.2 17958587.5 9349284.8 4678327.2 12483256.5 9198788.7 23880398.5 14659654.1 5879300.6 3569619.2 3419651.8 3894740.9 5301818.4 5104875.3 5594723.7 10613570.8 8938510.4 10843565.3 6283879.2 47630566.6 11408767.9 24575678.8 5622808.7 12146571.4 8108599.7 11460191 20174872.7 5474844.6 25161567.8 12953932 11593904.1 12149321.8 22038726 6453235.5 14243729.6 5238277.8 5682588.7 15201803.1 5220974.2 7329210.9 3995194.6 14872554.5 19035128.4 15470147.5 9262705.6 11145689.6 14635146 14237024.5 14185758.9 13332997.8 12765254.8 14204802.8 6169436.4 11253987.3 2247371.3 5212150.1 4573579.4 5288855 5239717.7 5020536.1 6153239.1 Pantothenic acid 0 0 0 0 0 1217106.2 0 295067.4 0 306273.7 0 1898479.3 267480.6 211494.5 0 0 0 573375.8 467753.1 0 0 0 227325.3 0 0 0 1320289.2 0 0 502087.9 0 1025233.1 3088483.4 0 1162196.3 0 0 0 0 0 0 0 0 2038878.9 0 0 0 0 0 0 0 0 0 0 396774.4 529403.5 780463.6 664635.2 0 615054.2 0 548264.2 0 0 0 0 1746845.9 702354.8 5633924.9 227510.1 727351.6 1131761.4 0 1015773.4 0 0 1126497.4 0 0 0 0 0 506713.6 520159.2 373665.6 329810.7 335627 827217.6 0 0 0 0 0 0 0 0 0 0 Myristic acid 231211685.1 157240526.3 256693418 245924637.2 61095917.4 111893633.2 316989832.7 604943090.7 147689861.5 150464675.1 337281437.8 198018945.9 946202899.6 1019552966 155426408.4 165999137 201979317 159213578.1 92994966.2 772683979 209549918 72143381.4 441341461.7 364045660.6 236312754.7 251481062 53513738.6 121490717.6 87318885 157884852.9 59120663.7 210960872.6 148786545.1 353986999.5 515703906.3 418890733.7 63502846 716220249.5 430124014.7 108797421.1 88201446.6 127939961.5 57481444.6 698695559.4 417660550.2 47153183.2 232753024 224842488.1 89530614.1 51344130.8 181270607 193738589.3 485615227.9 93309059 672285539.7 152490378.3 56754295.5 29371609.2 262160054.8 2784767.9 192507221.4 270572817.9 163953317 622748245.8 74341534.3 551654081.6 317816794.9 470859026.2 71567275.1 489912035 22442906.4 97139184.7 185143300.4 211344262.6 250087320.2 125082518.6 205021234.8 50570683.3 385213601.3 1051023372 687297816.2 155813842.7 450594353 562102729.6 487162873.5 181001267.8 240379838.2 355672366.2 725886456 148550011 549567935.1 23525684.1 201144703.7 196531723.7 191786853.1 178922532.2 187153967.2 63212730.1 Ribose 5-phosphate 101168.4 220563.3 1568930.7 90721.3 0 230250 0 0 985439.4 129817.4 0 237949.2 0 0 0 0 0 0 218271.1 0 822013.1 0 0 175412.4 120282.4 117930.3 0 0 0 0 0 205498.9 338400.1 0 197406.4 0 0 133697.6 89433 0 0 0 0 0 0 0 0 0 326382.7 0 134335.4 0 0 0 0 0 121024.7 0 0 0 0 0 0 0 0 0 0 0 113964.7 0 0 0 165740.2 178531.9 197845.5 1854842.8 750562.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 225091.4 0 262421.1 Cystine 4278613.4 1517205.7 0 1271567.4 3782841.5 0 4449427.4 6338076.6 7074132.5 13353199.6 3154322 20733865.6 12251808.1 14712473 7035349 6689696.9 5641199.5 9720115.2 5213840.6 9261300.6 6669542.1 3971784.6 4875161.7 9232473.2 6084738.9 945871.9 4161563.8 3893317.9 6908517.6 8124712.3 4163547.5 15122226.2 8108069.5 5993024.9 18504986.6 6802015.5 3865157.8 3238695.7 8574507.7 3612778.6 5245848.1 3392590.5 7428994.2 9076917.5 11620021.2 4011385 1455665 3041836.8 1243588.6 2721662.2 6875338.2 7354613.2 8021348.3 5716209.8 9484007.5 4788448.8 7203803.4 4535405 3562520.3 5038973.4 6414162.6 10920379.2 5179641.1 7959138.2 5281652.7 7328782.5 7141773.8 8906514 5242689.2 5663897.4 8484841.7 5413311.8 2624501.5 2752481.4 5971300.7 4424142.2 12132003.2 2490149.8 4064332.6 21899146.8 11904701.6 5648780.5 17551909.8 12854004.1 9708886.5 4003660.7 4878189.2 4887581.3 23204016.2 4031067.9 3390653.1 4094461.1 2618077.8 2498890.4 3234126.2 2158888.1 2022116.5 2229503.3 Uridine 5278420.3 6068084.3 3059320.6 3936578.7 4587740.7 3863889.6 12723000.5 7954315.6 2426159.5 3842409.9 8904608.6 3796763.1 8439751.6 6844171.5 5623048.5 4710441.5 4867500.2 2089266.6 4169776.1 4967709.1 5035555.5 6098561.7 4898791.2 4299483.5 4131544.4 3178883 0 4297569.5 4531206.7 5951271.9 8514302.2 5011277.8 10198120.4 4046271.8 5210781.4 6541984.7 4950332 5690879.3 6429155.5 6189486 4253292 4288020.5 6135648.4 6079171.3 5507118.9 8388208.6 4471619.1 4772616.1 3887141.6 3807905.9 3579509.6 4246081.9 3868352 3778134.5 6855161.4 3963653.4 4769221.5 3704003.3 5059902.3 6339980.4 4899918.1 4232729.9 6873293.5 7196355.3 4173404.5 7904885.3 8108307.9 7217494.3 6549608.6 5982531.4 5726979.5 5987021.5 3598042.8 4516246.9 11691273.8 4961528.8 6745144.9 5996776.4 6434743.1 5932476.3 6584289.6 10771388.3 7357233.6 10760037.2 7830393.4 8405559.6 6146411 6654819.1 5214479.6 4188275.6 3617068.1 4353938.6 2220852.4 2869048.4 4592665.4 3327289.4 3430391.7 3238195.4 Palmitoleic acid 834624194.2 347268359.5 736622049.3 688572536.8 131790952.5 363470379.6 464803060 866801594.8 102605846.3 95964033.1 449852273 125022355.4 2681993147 1424346239 135226093 122120109.6 379922844 154293226.6 410434431 3000543804 541836523.5 159045649.5 426862425.4 980694288.6 724994544 768618594.4 84218761.5 147562375.2 144011392.5 226055783.9 97737233.9 261221816.5 101309795.8 94689551 561447517 125290744.6 116147443.6 417429952.3 1212169773 167640155.4 101266750 319553265.7 87573779.6 1721303633 924733194 72240686.4 748498649.7 669282508.5 265330416.2 204735706.3 650425891.1 688101937.8 475084609 51022054.8 1033170088 198887132.1 18678624.1 17200080.4 567874561.9 0 666279817.7 134173533 226441265.3 1851744458 96931119.2 468149279.9 42698520.2 158180158.3 76570774 628490856.7 21644401.5 38887260.9 651705029.6 768555269.2 28457072.3 36262395.9 742363948.7 4931948.3 206444695.2 2367705869 1345009900 206019194.4 407618996.3 1421350734 464746599.6 9604493.6 291669649.4 915928457.1 2609026605 478215812.4 1658878939 131759653 623385236.2 219998908.4 672580113.6 604568047.1 635788286.4 234461573.2 Palmitic acid 2643797763 1893645785 3050829222 3005814599 615685968.9 862056340.2 1685530235 3372391293 1368406323 1145997025 1732976135 1695526483 5541696510 4492084777 1245494310 917325163.7 2778616863 1512949407 957381861.2 4816991358 2027914834 1019301531 2671657436 2745683800 2826944939 3076289936 494270052.7 831139463.1 741827161.4 1177455556 821481290.7 2749666137 939622309.3 1646587559 3508037579 1423265467 644317378 2317909517 3496702896 878157214.7 535936313.7 1210995609 533068699.8 4995588136 3142553073 425606436 2613687220 2573958262 1066691564 1308869152 2518099303 2532688056 2755243127 506693302.3 2944189913 1145452620 418796635.6 480119558.6 2348370380 270869749.9 1467049758 2247691644 2016745902 4848494279 718411664.5 2322145029 1153088760 1378844299 896918628.6 3305687361 575669238.5 747302240.5 2501666368 2812490696 970680310.3 1369147990 2374018247 783536189.3 1344197601 4637110309 3421036046 1305334160 2354938339 3898278133 2174756863 689566870.4 1093843082 2644050254 6406251699 1953189546 4184306014 886490424.1 2395893222 1168849520 2619547444 2336048504 2338226141 1259756726 Heptadecanoic acid 61816361.3 34837237 69239662.5 65665907 15527108.1 13594001.1 19598051.3 79559899.8 21366509.3 15776412.2 29462920.2 22315233 179908329 131522920.3 37745819.1 27773351.6 101610719.2 17728705.5 13688701.6 113046795.8 41438635.2 17728426.4 92450527.8 80908817.3 65731480.6 71142383.5 13008970.2 26872079.1 19746323.1 42046165.3 11745199.7 27398537.4 16636094 17722308.4 64162223.7 19466075.7 14329703 116938948.6 79541717.1 34711508 8242419.1 28289812.8 13209827.3 161973365.3 72806206.3 13318009.9 62413892.4 58673403.3 22603445.2 24778293.9 61138483.4 58213940.3 99605663.3 15491073.3 116902306.5 59188085.1 9323029.4 12637809.4 57922891.1 8736771.3 42481199.4 23173856.7 57843952.5 111233764.7 30117293.6 85446579.7 15083405 16723088.3 27572337.8 60209698.7 14267669.9 10116913.7 60007317.6 69892487.5 11892895.2 10552892 21141551.8 7887884.7 12931002.9 67903246.2 90537979.2 12644549.7 38681349.3 42598214.1 26330694.7 10268681.5 25236192 91235809.1 220611014.1 59215957 120895741.4 15748456.6 51692953.6 26660761.2 61474800.3 57580714.4 58473289.4 28032968.5 Gamma-Linolenic acid 403706463.5 361965112.3 556892327.4 545306310.4 194006861.4 161720817.7 433486161.1 605105036.5 56375244.4 140624472.6 323343844 194325408.6 1230022171 855994314.1 138904199.4 100161893.3 1454306042 144319196.7 125890445.3 932172173.9 607860320.3 351653258.2 391434423.6 460972382.4 521145774.2 542991280.5 106870723.8 120141001 309604458.9 141593665.4 203231036.1 281358094.8 275901889.7 437170446.9 427012303.3 661893299.4 183193862.4 163432387.6 770434382.4 129467112.9 109840705.3 381888927.8 204645545 1274663384 1054270552 76337432.6 521332549.6 504045524.2 266004443.9 208684974.5 443435491.5 466510603 640605433.9 39377200.7 432478105.6 106501965.5 194411283.2 153513701.6 1075589538 47446479.9 146566278.6 298435143.4 881878089.8 1048314613 20001159.8 287380979.4 483753473.2 556986564.6 69340703.9 594567293.3 119228337.3 100866130.3 452218370.2 507562085.2 292366921.1 237636105.4 564334031.2 147789866 515200743.2 1133340508 491567802.6 198423087.9 482955465.1 1259180758 503885879.5 260508934.9 236259066.9 337097217.7 1247678642 385087951.7 1130252474 140417856.8 372632276.6 154412132.6 456627344.6 439505384.8 446851266.8 236912344.8 Linoleic acid 4222039109 3451624094 5625526959 5295826670 1593416560 2287054312 3743750331 4909295084 811797244.1 2289295881 3650678014 3964892813 8168266229 7439168849 1602998451 908724319.8 8424888656 2143758003 1121005366 8120749744 4999008681 2013551035 3953103136 4794721933 4848371026 4969073139 825275271.5 1561601178 2225336160 1226271010 1409707025 3524325065 2078932784 3609447251 5899886409 5207685701 1495464377 1164664275 5133714330 1338452634 786964189.4 2997181153 1428890089 8468082445 8374661223 932999085.1 4698785421 4448818410 2449810597 2167033992 4133237413 4270350280 4942601454 475867796.7 3661277926 1249784843 1135072827 943567877.7 8112693030 611109729.9 2599152204 4092210549 4790394141 6839017909 248282711 3961832176 3823055175 4598338672 1428505848 5195027064 1103773436 1033131804 4422745540 4705864935 2777659733 2189782125 4262931964 1380132271 4439014397 8932819061 5212687728 1832987177 4734251773 8292264663 5213463347 2535886212 2176681141 3917330680 11033022330 3866962510 7115170789 1169887949 3557113044 1677285490 4698014646 4293912476 4418937686 2530905610 Stearic acid 1027337165 922214406.5 1283566223 1263238972 312822141 899250512.9 639738085 1384597764 674775351.4 524235362.4 746578341 663047831.7 1960190978 1916423844 693809411.1 441801051.1 1615728901 491505272.1 475786069.3 1761292140 723481856.9 590976118.2 1318394331 1049101019 1211955425 1244748854 337473707.7 418055153 404407399.7 585084103.8 356216658.6 855486064.3 536681735.3 751703416.3 1241821840 850302936.7 412599659.5 970226305.8 1159222690 575895561.2 364917140.5 613762964.2 403054756.8 2484645027 1154704448 289022353.1 1117340073 1068191227 549795872.3 700589876.3 1097023505 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544373.3 800384.1 322630.7 845120 2120215.4 1340812.8 891573 1753456.2 409028.4 1002703.5 409871.3 372756.2 910004.4 826746.5 1487148.6 1083160 1321168.7 716744 615950.9 2052620.5 745251.3 439503.5 707952.9 190605.8 836823.9 692528.1 737055.5 0 0 0 319887.3 0 414682.8 800050.4 690889.3 1148235.6 Arachidic acid 0 1805365.5 2731070.9 1307842.9 311608.6 0 375028 369924.3 298250.4 0 0 897064.2 0 260394.1 510414.4 485068.3 384251.5 0 0 544744.1 0 0 817019.6 0 455874.8 0 0 0 874195.1 0 653437.8 0 0 0 0 0 0 0 0 0 0 0 0 1422637.9 0 0 335826.4 0 0 293152 0 249860.1 434419.8 0 1046662.3 790540.1 0 0 0 1256343.9 0 0 446589.4 0 324381.8 0 0 0 0 0 0 0 0 0 0 2149731.3 576359.2 0 95830.8 0 0 0 0 0 0 0 0 0 0 540769.1 1323693.7 566886.5 278882.8 410106.6 581969.7 439411.7 500167.5 0 Docosahexaenoic acid 272057071.8 286938265.9 491860586 473234307.5 75628930.5 188274034.8 278053613.7 934124362.6 21491616 92285734 197800776.9 119230145.9 626216188.5 641453378.9 154023232.6 133493925.6 615755574.5 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4722309.2 4251869 0 8331365.9 7744633 4664248.1 11410085.7 4523343.8 0 4311838.8 5357303.1 4355741.3 11995269.1 4661871.5 4279820.2 4694021.8 4616614.5 4240000.7 4333490.5 68879993.8 71861315.5 0 4347250.2 4443842.2 0 0 7201908.2 4298735.7 0 8188973.7 4271318.7 4542332.4 0 4342732.8 0 0 0 0 0 0 0 72211912.4 80087017.9 162929655 118658644 55817233.9 54498507.4 0 0 0 0 0 0 1321207.7 0 0 13297325.5 0 0 0 0 0 0 0 0 0 0 61199878.8 76887669.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 56147656.6 57267697.8 60027586.6 148613842.6 Cholic acid 1927930.2 1239512.5 1581001.6 1505138.6 2950037.8 8588298.8 146783976.1 1946813.5 1510313.8 1044821.3 1765281.3 3872497.2 3098678.5 1223925.8 1248882 3022382 5054381.7 15055247.5 7572558.8 4814379.2 2351558.5 5860185.3 4413500.6 2017155.4 1803381.2 1721953.3 3332373.5 1927211.7 14471231.4 1622392.8 1005473.5 2066858.2 2152868.3 1000083.3 4845747.8 1353681.4 1332470.7 846836.2 1271906.8 5830732 4396852.4 999656 4345606.1 1715432.5 59593023.3 4867160.9 1872884.2 1823361 1242809.1 0 257411.2 228120.2 2632944.1 0 9016347.1 1011176.1 113335003.1 8451602.1 11118795.5 14853779.6 54070113.2 2423507.5 59350742 0 3720591.8 0 4268965.5 3964683.5 1130620.6 2894205.5 0 482361.3 808164.7 716596.9 7544405.1 0 0 919558 7636607.7 0 0 477018.9 0 0 0 0 1110916.7 0 0 569909.3 0 0 0 0 332344.7 418619.8 447643.7 0 Glycocholic acid 2528125.1 1528749.9 9011577.4 7817244 159710218.4 9204981.5 106604172.2 104349691.9 8472834 65727464.2 94495198.9 213522607.7 0 240142503.1 16339162.7 61502333.1 69545061.1 25763996 357915980.6 0 60310547.8 75734606.9 72468304.2 10652575.1 9080278.3 4418909.6 17641960.6 3483819.3 24735703.5 56005829.1 38741509.8 75511858.2 131592778.2 27573009.7 29193038.5 79661948.2 36990396.4 87630368.9 18966301.8 0 74544663.1 19711499.9 22360899.4 0 34564417.8 113212461.3 6742669 6000615.3 1480757.8 11088263.6 15216529.9 15496719.6 75249035 246916106.9 130332358.1 17393550.3 43203523.2 17120713.6 46762224.2 26341468.9 28905568.9 134432384.5 125439271.2 32362144 45348996.5 15248650 405961396.9 172395543.1 85300899.6 226257777.6 39717001.2 75689300.7 16809557.4 15948806.8 153670356.3 27909129.2 13369093.3 36166882.4 154821767.6 9047392.5 13707570.9 10232639.5 5329485.3 7236379.4 7047463.9 70383054.7 15734126.4 13107697.9 7529414.9 36790487.6 9194993.2 9402822.3 0 6834356.5 16751896.9 15827499.5 14558218 12391047.2 Biliverdin 5603784 4379899.1 5995250.7 6368412.1 2495466.6 577230.3 3235097 1870926.6 0 0 3115791 0 2447499.6 2005857.9 2624318.5 4714677.2 7408438.5 176481.4 1964756.8 5368967 3316910.4 2697951.8 1021522.8 2420040 6774798.9 6550758.9 4562553.4 1618281.3 2856429.6 1764652.1 1807268.8 0 1181406.7 3269284.6 0 1379644.6 3338330.3 2155862 1329019.3 3914724.7 4396037.2 3066469.1 2858037.5 2084522 1960938 3011319.8 5134819.6 3710996.7 2583700.5 3938937.1 5758364.1 5544293.3 3666097.3 3548909.7 2558832.3 2197291.1 4375977 2007255.3 1351638.7 3695887.1 3311617.5 0 2037928.7 3237818 4677338.5 0 1748171.9 2686494.1 5747915.3 1255338.5 1302730.6 1657035.3 6016012.4 6918201.1 2077148.1 591452.6 1918819 617867.6 994916.1 443672.1 6677568 4658431.7 3618321.7 3765719.2 2762433.1 1689823.9 1511868.5 2451151.2 3964611.7 4643224 3755378.7 1670892.8 1645424.6 2560807.9 5273723.6 5268197.6 5477488.9 3404588.9 Thyroxine 1119194 1120535.4 700734.3 538497 1245480.8 0 1464606.4 1973252.5 0 0 2789455.2 0 1842480 2612302.4 1369934.2 1138167.1 1467627.5 594598.7 1344329 926103.9 1636592.7 1247144.9 1318440.5 1629413.9 904651.5 1005687.2 740177 1428114.6 1283077.6 956067.3 869993.6 0 2000320.7 1278937.3 304479.7 1580605.1 1615705.2 1939501.9 1047086.9 1267342.5 1580939.2 1453180.3 1413820.9 1363654 1365632.8 1348353.6 759437.6 1078974.5 1173387.2 1368133.4 656815.1 875214.2 1240843.5 796858.3 1834527.7 943001 1120567.8 1119526.1 1011146.4 1022730 1148211.6 596534.7 1764399.5 1420256.6 1675140.4 1604808 2160878.7 1756767.4 2202195.3 1347021 1211789 1533759.4 1159281.4 740862.1 1740411.7 1938493.7 2309710.1 1146198.7 1900715.6 1069854.7 1362572.1 1862843.4 1684664.9 1403579.1 1536858.4 1585289.4 2295111.3 2319692.9 2151094.5 870397.8 888842.7 1014044.9 1005261.9 370449.9 0 826671.3 791889.5 1182963.3 MS_METABOLITE_DATA_END #METABOLITES METABOLITES_START metabolite_name chemical_ID InChiKey quantified m/z rtimes MSIcategory Adduct Serine HMDB00187 InChIKey=MTCFGRXMJLQNBG-REOHCLBHSA-N 104.0352 25.6 1 M-H Glyceric acid HMDB00139 InChIKey=RBNPOMFGQQGHHO-UWTATZPHSA-N 105.0193 35 1 M-H Creatinine HMDB00562 InChIKey=DDRJAANPRJIHGJ-UHFFFAOYSA-N 112.0516 25.2 1 M-H Mesoxalic acid HMDB31522 InChIKey=XEEVLJKYYUVTRC-UHFFFAOYSA-N 116.983 17.8 1 M-H 4-Hydroxybenzaldehyde HMDB11718 InChIKey=RGHHSNMVTDWUBI-UHFFFAOYSA-N 121.0295 47.8 1 M-H Ureidopropionic acid HMDB00026 InChIKey=JSJWCHRYRHKBBW-UHFFFAOYSA-N 131.0462 23.4 1 M-H Aspartic acid HMDB06483 InChIKey=CKLJMWTZIZZHCS-UWTATZPHSA-N 132.0302 33.6 1 M-H Hypoxanthine HMDB00157 InChIKey=FDGQSTZJBFJUBT-UHFFFAOYSA-N 135.0302 35.3 1 M-H Phenylacetic acid HMDB00209 InChIKey=WLJVXDMOQOGPHL-UHFFFAOYSA-N 135.0452 39.5 1 M-H Salicylamide HMDB15687 InChIKey=SKZKKFZAGNVIMN-UHFFFAOYSA-N 136.0404 45.9 1 M-H Caprylic acid HMDB00482 InChIKey=WWZKQHOCKIZLMA-UHFFFAOYSA-N 143.1078 72 1 M-H Oxoglutaric acid HMDB00208 InChIKey=KPGXRSRHYNQIFN-UHFFFAOYSA-N 145.0143 32.6 1 M-H Glutamine HMDB00641 InChIKey=ZDXPYRJPNDTMRX-VKHMYHEASA-N 145.0619 23.8 1 M-H trans-Cinnamic acid HMDB00930 InChIKey=WBYWAXJHAXSJNI-VOTSOKGWSA-N 147.0452 36.5 1 M-H Methionine HMDB00696 InChIKey=FFEARJCKVFRZRR-BYPYZUCNSA-N 148.0439 25.2 1 M-H Xanthine HMDB00292 InChIKey=LRFVTYWOQMYALW-UHFFFAOYSA-N 151.0262 24.5 1 M-H Histidine HMDB00177 InChIKey=HNDVDQJCIGZPNO-YFKPBYRVSA-N 154.0623 27.2 1 M-H Pelargonic acid HMDB00847 InChIKey=FBUKVWPVBMHYJY-UHFFFAOYSA-N 157.1234 91.6 1 M-H Indoleacetaldehyde HMDB01190 InChIKey=WHOOUMGHGSPMGR-UHFFFAOYSA-N 158.0612 60.1 1 M-H Aminoadipic acid HMDB00510 InChIKey=OYIFNHCXNCRBQI-UHFFFAOYSA-N 160.0616 21.1 1 M-H Phenylalanine HMDB00159 InChIKey=COLNVLDHVKWLRT-QMMMGPOBSA-N 164.0717 27.4 1 M-H 3-(2-Hydroxyphenyl)propanoic acid HMDB33752 InChIKey=CJBDUOMQLFKVQC-UHFFFAOYSA-N 165.0557 36.1 1 M-H Uric acid HMDB00289 InChIKey=LEHOTFFKMJEONL-UHFFFAOYSA-N 167.0211 21.1 1 M-H N-Acetylasparagine HMDB06028 InChIKey=HXFOXFJUNFFYMO-BYPYZUCNSA-N 173.0569 20 1 M-H Suberic acid HMDB00893 InChIKey=TYFQFVWCELRYAO-UHFFFAOYSA-N 173.082 31.5 1 M-H N-Acetyl-L-aspartic acid HMDB00812 InChIKey=OTCCIMWXFLJLIA-BYPYZUCNSA-N 174.0407 23.8 1 M-H Indoleacetic acid HMDB00197 InChIKey=SEOVTRFCIGRIMH-UHFFFAOYSA-N 174.0561 39 1 M-H Citrulline HMDB00904 InChIKey=RHGKLRLOHDJJDR-BYPYZUCNSA-N 174.0885 21.8 1 M-H Hippuric acid HMDB00714 InChIKey=QIAFMBKCNZACKA-UHFFFAOYSA-N 178.0511 31.5 1 M-H Tyrosine HMDB00158 InChIKey=OUYCCCASQSFEME-QMMMGPOBSA-N 180.0667 26.3 1 M-H N-Acetylglutamic acid HMDB01138 InChIKey=RFMMMVDNIPUKGG-UHFFFAOYSA-N 188.0565 20.6 1 M-H 5-Hydroxyindoleacetic acid HMDB00763 InChIKey=DUUGKQCEGZLZNO-UHFFFAOYSA-N 190.051 34.1 1 M-H Quinic acid HMDB03072 InChIKey=AAWZDTNXLSGCEK-RKGSPJAZSA-N 191.0562 18.2 1 M-H 12-Hydroxydodecanoic acid HMDB02059 InChIKey=ZDHCZVWCTKTBRY-UHFFFAOYSA-N 215.1652 80.9 1 M-H Pantothenic acid HMDB00210 InChIKey=GHOKWGTUZJEAQD-UHFFFAOYSA-N 218.1031 21.9 1 M-H Myristic acid HMDB00806 InChIKey=TUNFSRHWOTWDNC-UHFFFAOYSA-N 227.2016 224.1 1 M-H Ribose 5-phosphate HMDB01548 InChIKey=KTVPXOYAKDPRHY-SOOFDHNKSA-N 229.0121 20.5 1 M-H Cystine HMDB00192 InChIKey=LEVWYRKDKASIDU-IMJSIDKUSA-N 239.0162 31.3 1 M-H Uridine HMDB00296 InChIKey=DRTQHJPVMGBUCF-XVFCMESISA-N 243.0621 24.6 1 M-H Palmitoleic acid HMDB03229 InChIKey=SECPZKHBENQXJG-FPLPWBNLSA-N 253.2172 233.8 1 M-H Palmitic acid HMDB00220 InChIKey=IPCSVZSSVZVIGE-UHFFFAOYSA-N 255.2328 253.1 1 M-H Heptadecanoic acid HMDB02259 InChIKey=KEMQGTRYUADPNZ-UHFFFAOYSA-N 269.2484 270 1 M-H Gamma-Linolenic acid HMDB03073 InChIKey=VZCCETWTMQHEPK-QNEBEIHSSA-N 277.2173 223 1 M-H Linoleic acid HMDB00673 InChIKey=OYHQOLUKZRVURQ-HZJYTTRNSA-N 279.2329 239.9 1 M-H Stearic acid HMDB00827 InChIKey=QIQXTHQIDYTFRH-UHFFFAOYSA-N 283.2641 288.6 1 M-H All-trans-retinoic acid HMDB01852 InChIKey=SHGAZHPCJJPHSC-YCNIQYBTSA-N 299.2012 212.5 1 M-H N-Acetylneuraminic acid HMDB00230 InChIKey=SQVRNKJHWKZAKO-PFQGKNLYSA-N 308.098 21 1 M-H Arachidic acid HMDB02212 InChIKey=VKOBVWXKNCXXDE-UHFFFAOYSA-N 311.2956 298.3 1 M-H Docosahexaenoic acid HMDB02183 InChIKey=MBMBGCFOFBJSGT-KUBAVDMBSA-N 327.2328 228.5 1 M-H Leukotriene B4 HMDB01085 InChIKey=VNYSSYRCGWBHLG-AMOLWHMGSA-N 335.2229 114.7 1 M-H Cholic acid HMDB00619 InChIKey=BHQCQFFYRZLCQQ-OELDTZBJSA-N 407.2796 79.1 1 M-H Glycocholic acid HMDB00138 InChIKey=RFDAIACWWDREDC-MZMBZMQMSA-N 464.3016 43.5 1 M-H Biliverdin HMDB01008 InChIKey=RCNSAJSGRJSBKK-YKSNQIBWSA-N 581.2402 79.4 1 M-H Thyroxine HMDB00248 InChIKey=XUIIKFGFIJCVMT-LBPRGKRZSA-N 775.6824 77.3 1 M-H METABOLITES_END #END