#METABOLOMICS WORKBENCH boudreaulab_20240602_073820 DATATRACK_ID:4886 STUDY_ID:ST003246 ANALYSIS_ID:AN005317 PROJECT_ID:PR002016 VERSION 1 CREATED_ON June 5, 2024, 7:06 am #PROJECT PR:PROJECT_TITLE Effects of mitoregulin loss on cardiac and mitochondrial lipids in mice PR:PROJECT_SUMMARY We and others discovered a highly-conserved mitochondrial transmembrane PR:PROJECT_SUMMARY microprotein, named Mitoregulin (Mtln), that supports lipid metabolism. We PR:PROJECT_SUMMARY reported that Mtln strongly binds cardiolipin (CL), increases mitochondrial PR:PROJECT_SUMMARY respiration and Ca2+ retention capacities, and reduces reactive oxygen species PR:PROJECT_SUMMARY (ROS). Here we extend our observation of Mtln-CL binding and examine Mtln PR:PROJECT_SUMMARY influence on cristae structure and mitochondrial membrane integrity during PR:PROJECT_SUMMARY stress. We demonstrate that mitochondria from constitutive- and inducible PR:PROJECT_SUMMARY Mtln-knockout (KO) mice are susceptible to membrane freeze-damage and that this PR:PROJECT_SUMMARY can be rescued by acute Mtln re-expression. In mitochondrial-simulated lipid PR:PROJECT_SUMMARY monolayers, we show that synthetic Mtln decreases lipid packing and monolayer PR:PROJECT_SUMMARY elasticity. Lipidomics revealed that Mtln-KO heart tissues show broad decreases PR:PROJECT_SUMMARY in 22:6-containing lipids and increased cardiolipin damage/remodeling. Lastly, PR:PROJECT_SUMMARY we demonstrate that Mtln-KO mice suffer worse myocardial ischemia-reperfusion PR:PROJECT_SUMMARY injury, hinting at a translationally-relevant role for Mtln in cardioprotection. PR:PROJECT_SUMMARY Our work supports a model in which Mtln binds cardiolipin and stabilizes PR:PROJECT_SUMMARY mitochondrial membranes to broadly influence diverse mitochondrial functions, PR:PROJECT_SUMMARY including lipid metabolism, while also protecting against stress. PR:INSTITUTE University of Iowa PR:LAST_NAME Boudreau PR:FIRST_NAME Ryan PR:ADDRESS 4334 PBDB, 169 Newton Rd, Iowa City, IA 52242 PR:EMAIL ryan-boudreau@uiowa.edu PR:PHONE 3193535573 #STUDY ST:STUDY_TITLE Effects of mitoregulin loss on cardiac and mitochondrial lipids in mice ST:STUDY_SUMMARY Cardiac lipidome analysis in aged (21 to 23-months old) male wildtype and mtln ST:STUDY_SUMMARY knockout mice ST:INSTITUTE University of Iowa ST:LAST_NAME Boudreau ST:FIRST_NAME Ryan ST:ADDRESS 405 Galway Dr, Iowa City, Iowa, 52246, USA ST:EMAIL ryan-boudreau@uiowa.edu ST:PHONE 3193535573 #SUBJECT SU:SUBJECT_TYPE Mammal SU:SUBJECT_SPECIES Mus musculus SU:TAXONOMY_ID 10090 #FACTORS #SUBJECT_SAMPLE_FACTORS: SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Raw file names and additional sample data SUBJECT_SAMPLE_FACTORS - 1102-3 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_08_+_1102-3.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_110_-_1102-3.mzML SUBJECT_SAMPLE_FACTORS - 1116-1 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_16_+_1116-1.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_106_-_1116-1.mzML SUBJECT_SAMPLE_FACTORS - 1116-4 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_06_+_1116-4.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_105_-_1116-4.mzML SUBJECT_SAMPLE_FACTORS - 1134-1 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_17_+_1134-1.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_117_-_1134-1.mzML SUBJECT_SAMPLE_FACTORS - 1134-2 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_15_+_1134-2.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_120_-_1134-2.mzML SUBJECT_SAMPLE_FACTORS - 1134-3 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_19_+_1134-3.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_108_-_1134-3.mzML SUBJECT_SAMPLE_FACTORS - 1134-4 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_07_+_1134-4.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_109_-_1134-4.mzML SUBJECT_SAMPLE_FACTORS - 1134-5 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_10_+_1134-5.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_116_-_1134-5.mzML SUBJECT_SAMPLE_FACTORS - 1153-1 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_21_+_1153-1.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_114_-_1153-1.mzML SUBJECT_SAMPLE_FACTORS - 2191-1 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6545_20190605_11_+_2191-1.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6545_20190605_118_-_2191-1.mzML #COLLECTION CO:COLLECTION_SUMMARY Mtln-KO and WT mice were fasted for 4-6 h, and while under deep CO:COLLECTION_SUMMARY ketamine/xylazine anesthesia, the heart apex was snipped off and immediately CO:COLLECTION_SUMMARY snap-frozen by LN2 immersion. CO:SAMPLE_TYPE Heart #TREATMENT TR:TREATMENT_SUMMARY No treatment. #SAMPLEPREP SP:SAMPLEPREP_SUMMARY Lipid extraction. Lipid extraction, based on Matyash et al.72, was performed as SP:SAMPLEPREP_SUMMARY follows. All solutions were pre-chilled on ice. Tissues or mitochondrial pellets SP:SAMPLEPREP_SUMMARY were transferred to labeled bead-mill tubes (1.4 mm, MoBio Cat# 13113-50) where SP:SAMPLEPREP_SUMMARY lipids were extracted in a solution of 250 µL PBS, 225 µL MeOH containing SP:SAMPLEPREP_SUMMARY internal standards, and 750 µL MTBE (methyl tert-butyl ether). Internal SP:SAMPLEPREP_SUMMARY standards were Avanti SPLASH LipidoMix (Lot#12) at 10 µL per sample and SP:SAMPLEPREP_SUMMARY Cambridge Isotope laboratories NSK-B and NSK-B-G1 (deuterated carnitines) at 10 SP:SAMPLEPREP_SUMMARY µL per sample. The samples were homogenized in one 30 s cycle using the Omni SP:SAMPLEPREP_SUMMARY Bead Ruptor followed by a rest on ice for 1 h. An addition of 188 µL PBS was SP:SAMPLEPREP_SUMMARY made to induce phase separation. After centrifugation at 16,000 g for 5 minutes SP:SAMPLEPREP_SUMMARY at 4 °C, the upper phases were collected and evaporated to dryness under a SP:SAMPLEPREP_SUMMARY gentle nitrogen stream at room temperature. Lipid samples were reconstituted in SP:SAMPLEPREP_SUMMARY 500 µL IPA (isopropyl alcohol) and transferred to an LC-MS vial with insert SP:SAMPLEPREP_SUMMARY (Agilent 5182-0554 and 5183-2086) for analysis. Concurrently, a process blank SP:SAMPLEPREP_SUMMARY sample and pooled quality control (QC) sample was prepared by taking equal SP:SAMPLEPREP_SUMMARY volumes (~50 µL) from each sample after final resuspension. #CHROMATOGRAPHY CH:CHROMATOGRAPHY_SUMMARY Negative Mode RP LCMS CH:CHROMATOGRAPHY_TYPE Reversed phase CH:INSTRUMENT_NAME Agilent 1290 Infinity CH:COLUMN_NAME Waters ACQUITY UPLC CSH C18 (100 x 2.1mm,1.7um) CH:SOLVENT_A 40% water/60% acetonitrile; 10 mM ammonium formate CH:SOLVENT_B 90% isopropanol/9% acetonitrile/1% water; 10 mM ammonium acetate CH:FLOW_GRADIENT The chromatography gradient for both positive and negative modes started at 15% CH:FLOW_GRADIENT mobile phase B then increased to 30% B over 2.4 min. It sequentially increased CH:FLOW_GRADIENT to 48% B from 2.4 – 3.0 min, 82% B from 3 – 13.2 min, and 99% B from 13.2 CH:FLOW_GRADIENT – 13.8 min where it’s held until 16.7 min and returned to the initial CH:FLOW_GRADIENT conditions and equilibrated for 5 min. CH:FLOW_RATE 0.4 mL min CH:COLUMN_TEMPERATURE 65 #ANALYSIS AN:ANALYSIS_TYPE MS #MS MS:INSTRUMENT_NAME Agilent 6545 QTOF MS:INSTRUMENT_TYPE QTOF MS:MS_TYPE ESI MS:ION_MODE NEGATIVE MS:MS_COMMENTS For negative mode, the source gas temperature was set to 300 °C, with a drying MS:MS_COMMENTS gas flow of 11 L/minute, a nebulizer pressure of 30 psig, sheath gas temp of 350 MS:MS_COMMENTS °C and sheath gas flow 11 L/minute. VCap voltage was set at 3500 V, nozzle MS:MS_COMMENTS voltage 75 V, fragmentor at 175 V, skimmer at 75 V and octopole RF peak at 750 MS:MS_COMMENTS V. For data processing, Agilent MassHunter (MH) Workstation and software MS:MS_COMMENTS packages MH Qualitiative and MH Quantitative were used. The pooled QC (n=8) and MS:MS_COMMENTS process blank (n=4) were injected throughout the sample queue to ensure the MS:MS_COMMENTS reliability of acquired lipidomics data. For lipid annotation, accurate mass and MS:MS_COMMENTS MS/MS matching was used with the Agilent Lipid Annotator library. Results from MS:MS_COMMENTS the positive and negative ionization modes from Lipid Annotator were merged MS:MS_COMMENTS based on the class of lipid identified. Data exported from MH Quantitative was MS:MS_COMMENTS evaluated using Excel where initial lipid targets are parsed based on the MS:MS_COMMENTS following criteria. Only lipids with relative standard deviations (RSD) less MS:MS_COMMENTS than 30% in QC samples are used for data analysis. Additionally, only lipids MS:MS_COMMENTS with background AUC counts in process blanks that are less than 30% of QC are MS:MS_COMMENTS used for data analysis. The parsed excel data tables are normalized based on the MS:MS_COMMENTS ratio to class-specific internal standards, then to sum prior to statistical MS:MS_COMMENTS analysis. #MS_METABOLITE_DATA MS_METABOLITE_DATA:UNITS counts normalized to total lipid signal MS_METABOLITE_DATA_START Samples 1134-2 1134-3 1134-4 1134-5 1153-1 1102-3 1116-1 1116-4 1134-1 2191-1 Factors Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue PC 20:1_22:6 58152.35479 39476.00335 49428.5252 41805.66853 50483.66331 41447.02867 34347.63657 38014.22912 38633.93697 43521.47096 SM 34:2;O2 54965.53584 48590.51153 52092.7648 48544.44908 44234.69884 55588.89612 57981.17399 51819.4412 59471.45623 51754.63272 SM 39:2;O2 87600.35685 92340.03719 98330.88849 75867.03116 83435.35667 70973.38604 68452.22892 64800.54306 85530.95135 83131.14566 FA 18:1 188643.3638 144762.1431 156266.8388 179180.5405 183756.0618 208741.4212 196822.9913 178443.2738 177244.9112 215440.1062 PC 20:0_22:6 128226.0239 121702.553 128052.4741 111461.2334 104218.1166 122335.6693 111784.7438 95161.90754 86043.69951 91981.9718 PE 19:0_20:4 133568.1083 143811.0042 171783.5471 146620.3138 117761.8822 128439.0508 120647.6211 125822.6801 102740.3333 131316.098 PE 19:0_22:6 294544.2392 270071.763 244824.447 226283.9057 267070.89 236457.684 244402.8493 246461.048 206491.412 230616.5529 PE 20:0_20:4 27159.6448 31055.95687 36166.03775 33934.47589 35748.4267 31281.80271 25761.32733 26399.17709 25678.66354 32544.31891 PE O-18:2/18:2 74632.13962 86765.78242 72376.89753 66436.99221 78777.69568 80408.33208 80283.41553 79792.81923 90055.53097 97675.45855 PC 18:2_18:3 45756.44323 70740.8923 39921.65584 44076.07278 75882.95864 80414.42961 64357.45791 73334.36666 67509.06225 69081.35168 PC O-16:1/18:1 55689.93756 45749.57617 57642.70884 62523.00108 35944.66203 102601.4185 65858.6469 137390.3471 66843.52872 43754.2808 PC 19:0_22:5 21053.8913 19676.1866 24897.50218 24852.24803 18593.68913 19921.01568 22167.49938 19478.15718 14027.1061 12812.57736 PC 20:0_20:4 28309.59992 27027.93506 35046.84562 30154.38282 29256.61728 29482.6766 28854.18324 23207.12293 22030.34112 27419.46792 SM 38:1;O2 1370077.154 1444456.934 1373169.352 1126550.313 1080966.106 1239589.343 897148.2262 1126055.602 1215695.565 1051923.38 PE 20:0_22:6 91594.29485 94860.4856 110098.5889 110235.2641 112274.1446 106643.2651 92947.46219 96449.73565 70530.70016 87635.90004 PG 22:6_22:6 95977.38976 105402.2322 105910.8012 184591.0065 111447.0307 131916.8664 274186.3886 189988.7015 90616.86674 246250.6819 PC 18:0_18:1 1741662.827 1923665.634 2199676.376 2152630.605 1898389.195 2866707.58 2187867.5 2661913.115 1791086.228 2209265.868 PC 14:0_22:6 101392.6155 80088.00883 54404.81158 112050.4117 99139.83385 108911.3999 164263.4452 111898.7403 101731.261 96516.42117 PG 18:2_20:4 18984.2592 21437.72723 22983.20265 31091.08324 17249.94878 18115.10513 20254.75146 18803.40625 18675.82218 11252.97833 PE O-40:6 826314.828 840265.0809 907540.2786 1071174.471 1099152.076 1008397.821 684910.178 753446.8868 812265.3007 811069.7402 PG 18:1_18:2 117520.3269 154366.27 180098.8264 231524.3211 98663.77088 102085.9252 123748.0095 103102.1056 158157.2319 51677.58996 PE 18:1_22:6 7231732.042 6942790.71 6854507.283 6432385.932 6539825.842 6315583.181 6551008.101 6459294.638 6806964.356 6524357.626 PG 18:1_18:1 77770.98417 76211.99416 118164.0976 150777.4432 54657.31914 52243.97296 67965.24494 68443.95662 94562.54556 31670.83351 PE 18:2_18:2 144700.2886 249910.7851 152155.6071 163373.9545 239917.8162 288052.8498 206175.8616 194221.402 209492.7995 291251.6099 PC 18:0_22:5 398645.3806 393278.5312 440941.4201 462428.8568 283633.5145 339218.7878 393299.9229 332856.8662 359829.9309 287312.8287 PE O-16:1/18:2 164348.4328 197240.6236 149078.1803 156467.2215 221409.0414 237256.7775 162567.3519 195269.9106 196324.7481 276450.4437 PE O-18:1/22:4 60840.39991 51334.67918 49562.76974 64861.6668 57797.04761 51442.19681 44254.01596 44306.96811 53908.7708 59768.62993 PC 17:0_18:1 57593.8209 60101.44924 47007.22016 46829.77402 49656.41223 74085.72957 56604.67038 70193.26204 48486.91785 53585.48957 PE 20:1_22:6 107653.2569 89869.31149 93525.47309 81201.30393 132506.9704 85691.4389 60773.99393 82230.94762 78279.03069 111960.6509 PE 18:0_22:5 699594.0578 741990.2279 828162.669 973631.5153 864791.8046 721132.1504 725806.2594 748142.0754 746975.2893 814256.516 PE 16:0_22:6 10082782.35 9510295.692 8802668.06 8529704.117 9529301.913 10019917.22 9833395.476 9294123.149 9476204.593 9977073.435 PC 16:0_20:3 1185773.078 1196694.793 1160687.286 1093110.03 1285538.574 1391932.725 1131069.285 1245241.24 1218340.045 1299515.919 PG 16:0_18:1 3832231.198 3673109.114 4656063.427 4983002.243 4241840.371 3627164.253 3946292.498 4285567.218 4000330.447 3669305.561 PG 18:2_20:3 6639.390114 9552.1521 13910.69056 15251.41039 10374.18345 8910.170864 10481.07425 10953.52116 8024.923371 4247.766388 PC O-16:1/18:2 55486.62299 74647.08056 48470.23957 41255.1198 63149.01361 69225.74092 59435.20285 49659.63333 75994.89906 86306.66166 PC 18:2_20:4 476453.0061 500159.7681 535079.1592 523430.4777 471771.486 599269.2788 605029.2217 483087.6683 446605.1581 632248.6549 PC 20:5_22:6 8427.922566 8161.839557 11175.93995 18441.02586 15163.98921 15334.11673 24033.4792 16309.00439 10027.70144 15561.28853 PE O-16:1/22:4 90767.393 78523.30049 93451.04522 130897.5062 107275.679 65821.19918 94159.16328 99109.02896 92997.6881 76887.93076 PC 18:3_22:6 93380.84833 95727.17452 93638.75656 127915.9267 105102.1023 114814.7505 164846.4182 125505.0687 111748.288 90478.83068 PE O-14:1/20:4 7738.712142 6956.13925 6574.318111 9267.824194 9445.128727 9431.401415 10182.82689 8585.398647 6854.526605 10782.54334 PC 16:0_18:1 2838542.759 2747746.779 2953913.56 2954271.741 3014452.002 3520760.61 2782537.847 3914479.666 2818428.045 2945542.339 PE O-18:1/20:4 1127869.87 1047784.438 1046988.571 1260566.587 1136745.937 1167171.94 943562.2829 888034.748 992429.8255 1176240.529 PE 18:1_20:4 1387592.558 1475722.231 2036995.394 1727451.225 1439028.873 1425553.788 1502729.504 1517201.761 1316333.136 1515361.757 SM 40:2;O2 377417.1813 386082.0092 427655.6532 412525.3629 293545.1764 304856.5354 412925.3106 364242.2224 313876.8566 314400.2271 PC 22:5_22:6 25312.41702 21832.22218 27490.75072 45441.85111 30440.97758 33233.62114 45113.35067 36330.89167 28342.60091 36639.74347 PC 17:0_18:2 51614.36471 64054.37176 39973.6503 34617.93634 54042.67363 67681.78852 48885.71063 49616.7698 54815.8595 60646.27322 SM 42:3;O2 220488.7113 199642.0639 196247.8381 189941.5801 164541.025 164635.6542 242311.8688 202518.7688 271840.707 209058.4883 PC 18:1_18:2 1157665.355 1165220.101 1113995.597 1069015.344 1256671.902 1347303.253 1083254.917 1191204.698 1190430.609 1266183.988 PC 18:1_22:5 83727.71511 57525.19113 100949.094 114764.1534 79950.96448 63187.42088 91575.27123 85803.49115 73934.7479 51647.02681 Cer 18:2;O2/18:0 88927.49637 103258.089 100871.1509 118165.8717 67012.99523 84246.12553 147076.1408 108122.145 163375.8194 81172.72609 PC 19:0_18:1 43375.81228 45473.77055 44304.65039 43631.35082 37601.01778 62212.74859 48009.84675 52437.80853 34268.02669 44309.55293 PC 18:0_20:2 175267.3837 196186.8055 169226.561 169554.3504 183733.404 226915.4022 199027.002 159697.8282 171582.5814 211448.7758 PC 19:0_22:6 383496.2425 291618.9728 272955.2362 267809.4082 206332.3301 245834.9264 315664.7737 246789.514 226230.2098 194470.4655 LPC 22:6 51640.03581 46911.74645 63719.10456 65778.89283 47803.47034 52195.50667 82521.58576 75038.57457 48826.9514 58849.64319 SM 38:0;O2 28851.29477 27222.25121 24807.54489 22366.4472 22058.03347 27444.59824 20575.41715 22733.61717 23041.60851 22044.56445 SM 40:1;O2 2005745.056 1946838.613 1880139.939 1902289.148 1528328.153 1913746.191 1636010.854 1931034.534 1641690.045 1533333.162 SM 42:2;O2 1314720.961 1080373.669 1258475.444 1306059.372 1044423.35 1139508.695 1416219.909 1426556.123 1290587.99 1165583.354 PC O-16:2/22:6 78801.93109 85824.67209 112222.4047 80531.00332 83542.76935 114306.3875 146426.6136 89941.24998 80646.64617 81582.30352 PE O-18:3/18:2 39024.56704 51118.40539 29914.01523 27581.95212 45203.14433 48068.59396 39424.74688 34427.98892 44588.41579 55936.06074 PC 14:0_18:2 30095.33347 31091.51925 36927.01551 34739.95229 57101.55024 43840.02247 40422.12621 49679.32357 39238.61105 43648.27438 PC 38:5 365759.6355 363848.1055 417003.8751 428857.3114 320247.8031 394014.8062 367920.6478 384013.687 312879.6633 302641.4294 LPE 18:0 29256.29519 34043.29414 30649.13316 30756.46188 35162.54956 31326.2345 30147.68637 31808.72162 38025.22502 39347.26551 PE 16:0_18:0 35642.6093 31572.92622 43206.59908 53822.0668 35550.4332 32573.75932 34448.2505 42086.80266 35997.4406 33794.04721 PC 18:2_18:2 659100.1119 988114.0572 606454.0363 500240.2485 792942.7952 939130.3511 660113.0855 693089.1091 901252.7956 840831.3777 PE 15:0_22:6 30870.48867 39537.64503 19095.18975 29844.82579 32151.22506 33599.67253 34968.15451 32801.03941 31762.42647 34008.02462 PG 22:5_22:6 140657.542 191944.3034 212996.5732 363527.087 217530.0596 281832.5922 315638.352 332085.2117 147893.7404 281428.3769 PE O-38:7 8924490.085 9198013.185 9531088.101 9513719.412 9561172.464 8704578.417 9472831.233 9743132.475 10045578.4 10074327.27 PC O-16:0/22:5 96512.50398 92594.25744 157987.605 149777.7076 89968.2099 91430.22073 123881.1108 108722.8161 111545.6226 71029.3129 PG 36:2 593630.8012 742906.8336 416615.3619 592608.0803 751886.6861 800408.1743 627866.8128 559722.5669 644787.5463 831448.7646 PG 16:0_16:0 70510.02964 78820.74643 96745.92246 95636.28226 97862.79584 99266.95028 86623.72342 96729.03305 91755.81835 92284.17306 PG 18:1_20:4 12620.12329 10142.27724 19244.46999 34616.895 9331.653621 9782.02056 18255.12736 15661.98603 13142.27297 5696.50809 PE 17:0_20:4 84626.78737 100859.8421 96841.63385 85689.72189 82670.6287 83894.73207 86492.98712 78401.2062 83149.10569 97520.31081 PI 18:0_20:4 3363179.511 3020429.785 2841243.681 1293839.623 4140360.09 3549507.127 2511993.293 3870972.19 3387686.816 3576681.537 PE 20:2_22:6 133757.7532 94402.23803 105129.2943 126874.5363 115457.6061 110629.9036 153104.1574 138723.9267 113171.748 108053.358 PC 18:1_18:1 670270.7017 259534.8406 397686.5635 517837.0396 1044251.087 360214.8322 376272.5816 449598.3258 487458.8033 618681.2797 PG 20:5_22:6 4257.999083 5643.396206 6790.192865 8791.04302 7711.078005 7807.493815 9080.513427 8662.974491 3977.424516 8716.755786 PC 16:0_22:4 60293.13758 53206.38046 70947.99807 70098.6727 66379.33147 57537.44496 63263.37125 69758.70227 52675.56114 60185.54622 HexCer 18:1;O2/20:0 42106.68426 41751.13782 38966.57964 42603.62606 40232.70167 43054.09918 30919.59335 46005.24847 35646.51404 39307.76752 PC 16:0_22:5 1273342.577 1063302.992 1528182.167 1566252.494 1290415.535 1295664.083 1415232.772 1481959.579 1070220.831 927076.2402 PE 18:3_22:6 64710.54853 69635.36314 58313.60895 87607.15073 113323.492 81718.13215 91485.57092 83847.8753 87433.21479 87425.86922 PC 16:2_22:6 11101.00618 8087.549372 7635.56492 10135.16478 7106.423134 8992.679713 13260.87008 9407.906305 11398.22953 6291.958475 PC 18:2_22:5 101698.4217 117852.0274 124000.8102 135948.28 135788.9676 128889.8261 120725.6685 118953.5957 111789.2609 107171.3421 PC 34:3 151040.0966 146214.9553 180506.3043 158169.7964 181988.3725 167732.7706 166375.8426 191325.3922 175466.2346 153231.2465 SM 39:1;O2 552972.3049 494188.8045 512508.0672 504050.5684 301434.34 432526.6874 467279.5581 542853.0616 397429.8391 306494.9615 PE 18:0_20:1 22735.21317 22167.73597 21548.85102 25987.51376 36783.85594 23139.02721 20293.56873 20089.14104 22473.12813 30561.23091 SM 32:1;O2 9558.101961 7577.618467 10137.79485 9343.494072 7625.443307 8441.277625 11873.65649 10455.07126 8625.03673 8133.042506 PS 18:1_20:2 45605.75207 42776.97805 55543.36801 62760.10455 48828.57613 53471.23194 52177.50146 64443.96535 48983.21954 52852.91776 Cer 18:0;(OH)3/20:0 55212.98695 50153.98084 71344.65945 87668.14524 40486.93856 72386.56195 38435.87839 73407.35564 39679.96379 38117.90772 PE O-18:1/18:2 411772.9309 438649.695 296749.5912 363984.2265 527077.6508 594648.3139 327372.0821 332566.9669 418953.8125 638028.7129 PE O-18:3/22:6 3777675.7 4442481.241 3704123.697 3861595.656 2618349.027 3732385.938 5272485.209 3864339.761 3892245.536 3253155.299 PS 18:0_22:6 142622.0791 113083.6773 110890.0318 66962.56751 131309.1213 122233.4571 109798.5575 151483.1923 106494.8021 128878.3494 PC 18:0_22:4 122167.766 110188.8988 160662.8841 207037.4564 87274.17051 104803.5298 161160.3596 132742.4658 117812.4703 84022.6447 PE 20:3_20:4 290417.3916 172815.2349 248885.1707 349140.692 498472.0949 214465.1435 309568.2697 265576.2997 317003.5518 250730.0004 PC O-16:0/20:4 68217.13027 52131.51718 61180.26474 60325.4517 47771.24644 58720.57394 68758.15977 56611.84733 60054.43618 59559.4185 PE 18:1_22:5 2468555.982 906413.6141 1184739.058 1527589.753 4223985.793 1107624.873 1101817.839 1529545.159 2274209.052 2104978.429 PC 18:0_18:2 2599142.928 3255561.058 2707006.599 2039563.727 2823235.538 3239704.69 2466805.016 2378072.36 2904119.439 3370982.99 PC 16:0_18:2 2552716.9 3430376.34 2577005.866 2066304.536 3292336.772 3438095.182 2382951.804 2777291.633 2938832.063 3430339.184 Cer 18:0;(OH)3/24:0 22210.08201 19944.82005 26142.84638 37975.86528 15116.94083 27026.45425 19771.97442 29778.56803 13669.51074 15201.65399 Cer 18:2;O2/24:1 506186.1338 488439.6222 675026.0829 841245.8773 362368.894 594012.6291 804342.6771 716052.1363 661927.1588 424069.9634 PE 20:4_22:6 51584.96682 38744.22759 48010.36955 87545.54971 54893.63881 46600.26607 75932.89216 59491.25955 67817.29098 60663.86513 PE O-18:1/18:1 62678.03095 42715.86945 44093.48822 59592.3387 63448.87453 56233.26963 41719.37622 45093.31293 51840.89558 60153.8557 PC 19:0_20:4 94333.88719 79796.66248 103870.8619 88429.1609 64572.60477 87184.84221 102096.6007 73364.89046 59675.00152 79195.37436 PC O-18:0/22:6 61602.74107 46839.62953 41538.65692 42476.38154 41677.40832 43139.66732 47694.31946 37741.2541 51711.63654 40858.38685 PE O-18:2/22:6 6031766.859 5650099.387 6658755.125 6610705.255 4749594.168 4355509.628 6519040.332 6329468.027 6149615.187 4729996.926 PC O-40:7 108062.4399 86781.05496 73339.08403 85381.42041 85187.98186 80603.50547 85478.78698 71725.52067 101504.0091 78088.86887 PC 16:0_16:1 101334.0651 85975.41751 130387.0119 142487.9388 131633.9229 122043.9035 145563.8297 149207.508 103210.8757 111140.4759 PC 20:2_22:6 42564.61569 28222.75157 28983.51594 29902.81045 26732.38405 31219.22478 44435.08695 31623.84788 32373.33153 27770.47373 PE 16:0_18:2 138785.27 212712.273 132998.4331 122518.0732 249780.9502 209751.1532 134332.1823 160785.4011 177176.3895 266890.9306 PC 22:6_22:6 132657.5204 97516.98588 136623.828 253335.6299 114373.9234 113537.6913 261338.4862 162522.104 173323.9364 125657.8934 PG 18:2_22:6 1090303.115 1791254.954 1267556.994 1769356.058 1330730.806 1633850.282 1740964.944 1511472.243 1324447.409 1454538.001 PE O-16:1/20:4 1308365.676 1505870.52 1543843.287 1549938.104 1327708.134 1377686.598 1517960.715 1604641.006 1424507.272 1484140.539 Cer 18:0;(OH)3/22:0 35316.13787 29111.98054 38610.12825 59457.76852 24513.30578 45853.83152 24229.89541 50954.02451 19793.34265 23503.90216 HexCer 42:2;O2 37069.00608 34303.07535 31909.74326 45473.50592 27340.44025 27595.78203 35887.78067 45517.4961 43966.62774 34516.00091 PE 18:0_18:2 394902.141 699759.012 469773.3786 392712.1157 752210.0389 639272.2281 459813.1225 463835.7747 560188.4871 854655.7731 Cer 18:1;O2/23:0 621473.6423 729790.2894 746369.5481 1098549.595 262928.2795 744153.6723 644791.2051 929553.2307 378015.563 326929.3311 PC O-16:0/16:0 104437.9766 40765.04918 49890.58167 47495.02492 61275.76904 60384.20701 44991.65726 46130.81069 55973.67384 66306.07109 Cer 18:1;O2/24:0 502889.5833 416190.209 597796.8617 778935.1956 320022.1751 623054.0313 404728.5339 710953.9567 316675.4619 275613.1594 SM 34:1;O2 297646.1529 297332.5514 254024.1226 219521.7733 235820.0021 269618.8546 216237.952 262968.0386 292452.4283 320529.7476 PE O-38:6 149678.6802 177630.5723 201179.2205 179295.5409 203046.4256 179845.7951 144773.5813 165979.9327 160788.834 220502.9845 PG 16:0_20:4 33840.44306 33156.8885 31722.18741 41647.06577 27395.71111 31165.67362 39796.35351 35432.27168 36188.595 31878.47309 PC 24:0_18:2 27809.73156 45235.10471 23561.61851 27374.93043 27753.55001 40852.52473 36271.33885 31074.15273 16097.60496 41824.88427 Cer 18:1;O2/22:0 1005856.254 1061453.515 1164092.036 1432969.513 744574.9939 1317426.313 710387.559 1517052.413 770685.5199 590640.4676 PC 18:3_20:4 93824.22343 66799.95252 99591.60779 126042.9749 153921.0874 108920.5603 138574.2855 119432.186 103745.8185 107095.0837 PE 20:3_22:6 97819.92365 67544.71687 87815.33422 162221.5151 118273.3743 99193.05218 157125.5008 130295.0239 94558.23719 99342.71282 PE O-18:2/22:5 5826580.537 5864848.514 4660192.965 5459320.293 7032030.04 5765722.716 4653437.602 4529195.884 6040181.917 6586131.308 PG 16:0_18:2 409693.1917 746340.69 511152.3232 545413.8826 925569.9378 806790.8951 501405.2204 567842.86 649215.5808 879523.1254 PC 18:2_22:6 3278774.835 3679649.715 3097202.88 2770955.735 3218973.164 3473607.907 3242709.6 2847457.254 3398889.54 3517212.028 SM 40:0;O2 32392.50711 31870.64168 26317.66888 28219.04064 22906.85099 31036.2144 24657.36552 29288.66536 26533.5024 25305.77493 HexCer 18:1;O2/22:0 64210.16412 64441.30479 65309.73455 85315.40947 61691.1266 66969.15281 54086.27321 84015.94616 57615.645 63016.95265 PE O-18:1/22:6 5826580.537 5864848.514 4660192.965 5463819.457 7007710.041 5782167.058 4662108.528 4534741.897 6032251.866 6586131.308 PE 18:2_22:5 129589.7576 167446.5947 154811.6118 211320.4449 251192.8711 184198.7259 168549.6327 170660.7139 180340.8206 161606.48 PG 18:0_18:1 244608.0623 292993.6508 347549.5114 380426.3387 244192.2957 288284.6926 326113.26 348230.7725 239844.4549 227202.7367 PE 18:0_20:5 306048.8431 388004.3761 399595.2622 361269.3984 455782.2541 406854.3072 275238.4112 353768.0887 312914.2431 469868.7885 LPC 18:2 130803.2546 138552.4594 167767.0297 180892.8066 107984.5589 163705.2897 171148.1334 227981.6463 95972.50232 122486.7365 PC 16:0_20:4 2761034.451 2615672.894 3042152.591 2956018.988 2632782.721 2856134.149 3192253.447 2830947.371 2514015.701 2904178.191 PG 18:0_20:3 27775.90859 27827.14177 24498.59452 32301.93542 30283.99298 27167.89486 28093.93005 27002.68167 30817.79824 33356.29928 PC O-18:1/16:0 119257.3312 82569.81407 103060.7732 85921.58077 79255.14091 94136.392 98446.55923 99536.57224 102645.9001 91406.51786 PE 16:1_20:4 20612.84014 20536.43316 40263.44623 35054.86555 36706.52928 24731.75366 29740.77159 28958.16645 22184.39915 37532.43899 PE O-16:1/18:1 132146.1468 106170.8177 154536.9725 164983.6337 129722.6402 137821.3739 138827.1699 168100.4615 132088.251 135352.5875 PC 18:1_22:6 2008495.496 1512215.047 1984164.927 1800073.185 1171268.805 1493949.82 1981708.283 1712168.872 1675258.052 1201813.744 PE 18:2_20:4 157771.8454 203926.7699 210961.8853 202791.997 214129.9265 202582.6517 180530.4894 170005.3318 197895.3814 282573.0475 PE O-18:1/16:0 18978.9029 14005.65012 17292.65178 21124.33106 25225.4749 18267.30023 15413.10082 16928.72479 19678.58332 22043.90128 FAHFA 2:0_18:0 37193.83928 45655.38713 35574.00533 31893.76793 49691.22281 38435.43878 40536.62649 36368.015 43320.06642 48974.94507 SM 41:2;O2 141750.8292 162500.3733 186320.0269 190734.5144 100290.6356 154642.2957 229818.5628 192441.5037 118970.619 135570.4917 PE 18:2_22:6 2347836.954 2534012.149 2053393.526 2122403.673 2605031.003 2315458.273 2308895.752 2175240.842 2583374.564 2533185.092 SM 42:1;O2 1328319.817 1444143.915 1419901.666 1355759.846 1118876.18 1486473.774 1288700.002 1453765.575 1257607.915 1320250.155 PG 18:0_22:6 2344979.274 2101366.689 1975561.811 3759664.701 1267383.303 1869234.993 3152397.383 2215202.177 1948299.282 1299942.553 PC 17:1_22:6 130524.2799 78448.84627 66630.40577 77913.9037 73077.90834 79997.87531 118995.3312 84387.38919 105637.4062 65732.71024 PE 17:0_22:6 444379.0812 448852.9846 274717.1224 298885.5166 378411.8105 363117.1018 369267.4642 326861.9503 357507.3194 359196.7552 PC O-16:0/22:6 830912.7684 726774.4516 966682.7759 974167.389 593272.8738 608886.0871 993019.3477 783410.5472 944655.548 546965.1677 CL 72:8 44931.28662 82170.54008 28548.82814 17087.34982 131249.112 84847.53707 28136.23112 41296.12965 54222.39685 152306.4858 PE 22:4_22:6 83600.69751 57679.33593 77317.28019 155453.7004 51307.78571 70361.59587 146495.7207 104910.6483 81854.45378 65231.72349 PC O-18:2/22:6 213098.0251 157745.4588 210640.1182 226259.2017 103794.5543 106834.4392 256123.8813 188674.4434 190537.1069 102652.0127 PC O-18:0/18:2 71752.80443 19588.6252 20116.0364 14002.21629 32328.55576 30244.94678 17830.85946 18248.28263 30592.2357 40507.41471 PE 16:0_20:5 22404.82173 34896.73378 40150.62996 34923.13088 39564.00432 41559.79603 31025.90743 33122.47572 27715.83746 46535.48226 PE 18:0_18:1 179994.2564 168276.6491 241934.7571 303236.6259 197990.3862 229351.5169 228775.1123 284172.1768 193177.165 205187.9167 LPE 16:0 17365.40312 24833.98663 21244.22122 26031.61116 19971.43207 21093.92873 18352.72539 24636.78725 20871.77757 21338.23172 PG 20:4_22:6 93832.25012 56181.07274 82445.36202 162423.0663 67282.37468 89915.50536 121950.4915 123186.5191 64227.79544 97092.28474 PE 18:0_20:4 4755814.698 5541271.447 6171819.695 5569803.247 5554594.401 5273062.798 5153071.743 5087193.177 5223783.01 6347405.07 PC 20:4_22:6 104759.141 73788.36644 108699.8626 196842.2699 96980.19311 93963.36947 186125.2009 110380.1388 132120.0639 99243.27009 PC O-18:1/22:6 142975.6772 112117.2083 150143.021 141036.5796 69569.05032 77933.0332 171686.1289 120728.6868 138923.5952 70040.44874 PC 16:0_16:0 1657102.5 1810211.914 1962801.289 1688214.03 1722604.514 1703285.189 1659149.202 1919287.565 1820377.583 1622561.278 PE 16:0_18:1 136793.8146 122909.2119 159349.8897 183365.9002 145059.4484 148143.6865 135255.2141 183640.8949 146811.014 152649.2104 PC O-16:1/22:6 1464259.966 1232872.213 1400566.685 1431962.759 957141.1007 1068619.921 1728603.3 1338834.197 1524465.074 1057247.198 LPC 16:0 619299.2676 737381.7927 816290.8006 924539.3881 535466.1888 724062.6921 782974.7707 885031.1656 505339.003 597789.2441 PE 18:0_22:4 102063.035 100096.3919 128823.6206 204803.5865 99716.05069 95745.72182 148538.755 145489.0647 114691.2153 98516.23074 PC O-16:1/20:4 209337.9542 165633.875 224332.1782 257252.8643 151926.1036 181409.1357 297397.9304 198191.1259 194827.5045 177449.4694 PC 19:0_18:2 68901.21919 89665.03922 63005.416 40546.11112 62248.18029 89466.69264 60638.7222 52067.46074 57733.82956 79049.39611 SM 36:1;O2 259013.8999 282788.3691 257230.713 211895.9627 212495.5719 245687.932 220456.6948 235232.3471 275687.4361 269814.2737 PC 16:0_18:0 376856.2904 387238.3064 483926.975 474645.3165 357382.1168 376758.0159 438644.8343 430312.8605 429698.4708 363954.7079 SM 43:1;O2 25350.21377 26843.81891 26639.30649 30970.13236 18610.99835 27800.07259 28080.89808 30481.21562 21427.21575 23997.75907 PC 17:0_22:6 402792.6736 340279.7907 247923.1256 257268.4047 219224.1047 254154.2586 360210.0896 264082.9605 316317.76 223374.3822 PG 35:1 69581.94948 72964.18292 55197.13547 68037.03455 65436.78656 63758.50535 69001.42436 67106.92901 59954.79072 67457.70652 Cer 18:2;O2/24:0 179234.6111 247292.0939 310153.5147 329596.4417 150138.6143 301922.8766 341035.2386 285934.5498 175879.1405 167335.2482 LPC 20:4 26932.62878 23376.3238 42201.75581 60103.35581 25495.57902 32438.70822 53285.58762 52895.39192 20138.75474 30074.48899 PE 17:1_22:6 140192.7922 107696.216 94341.85523 125429.7209 113622.6907 103732.344 129530.8519 112134.8609 131923.3277 91957.37224 PC 18:0_22:6 12057995.4 11614592.6 11078861.72 10023775.84 10539580.36 11306469.06 11313900.68 10174968.53 11787520.54 11214034.82 SM 37:1;O2 109823.0562 92194.78368 87983.64455 78805.18097 68415.49211 96436.23475 77701.54289 110459.8281 93897.7766 69116.99105 PE 18:0_20:3 100637.0774 100303.4788 140926.5501 140012.9445 148810.7041 119499.0665 137514.9984 144530.1709 109014.6909 132125.8431 LPC 18:0 44674.32484 25828.97301 43766.37057 47116.48879 26993.15494 32380.92714 46964.87207 43083.2745 32948.80395 27314.20704 Cer 18:1;O2/24:1 1050022.22 811671.119 1136093.623 1336293.646 789674.3775 998051.3454 1080475.569 1300912.82 1103886.848 768282.0232 PC 16:0_22:6 12573168.28 11829277.84 11514191.5 10224577.52 11321873.18 11400288.46 11385346.31 11759259.78 12294447.97 11031455.72 SM 33:1;O2 48719.2904 25768.01066 33738.66749 30773.01404 25274.81342 29754.83563 39282.94209 34521.46887 30120.54528 26113.26635 PC O-18:3/22:6 54518.3837 50414.87802 40379.09999 43007.37002 30773.01494 33275.06108 57834.29064 40035.84638 50387.89982 31999.01448 FA 18:0 1954496.982 1983650.545 1714455.055 1475784.214 2091765.56 1862383.249 1460061.894 1709994.505 1976970.312 2081706.39 PE O-18:0/20:4 139054.2825 117177.1604 113971.3103 127311.2323 100166.9769 138690.0942 114560.7297 101096.4603 103170.8155 132050.0354 PC 16:1_22:6 617757.3515 344917.1835 590348.0018 623417.6331 395930.7064 377390.2484 712954.8637 550666.0452 541600.232 315393.8104 PG 18:0_20:4 46817.83239 45158.24797 45853.24748 58647.95846 45056.9848 48256.11094 46324.08276 47935.29685 48822.4492 48175.34529 PE 18:0_20:2 31973.91681 30936.4276 31311.50394 37927.95993 43566.76589 33558.03151 33253.51388 32123.45175 35484.46022 39277.05345 PC 15:0_22:6 233197.6981 228794.2326 124630.1849 162648.443 146010.0003 165344.5192 223307.0302 191169.0691 194924.3949 139111.129 Cer 18:0;O3/24:1 15371.44031 11086.02908 17343.14679 24392.82631 13695.9019 20171.90392 14884.19376 20457.2863 12721.4808 11621.24384 PG 22:4_22:6 4585.784109 3486.272111 5198.279988 8217.964322 3696.333022 3278.018679 7255.686187 7507.961041 3526.061223 4473.818467 PC 18:0_20:1 76410.16642 82175.43455 77925.95799 80852.99748 98870.36872 91363.15653 67801.48514 79380.91624 73172.5671 99690.62121 PE 19:0_18:2 14278.88651 20892.71054 14792.37786 11970.97196 17795.87495 19606.79913 14164.5171 14971.38345 12372.01743 20030.27864 HexCer 18:1;O2/23:0 23012.22693 24471.04076 22436.43512 31570.54218 19460.67572 23905.05512 22437.40075 35422.31876 15849.18458 20920.33448 LPC 18:1 56066.75283 47400.44984 104381.0607 134188.2023 45324.71362 64234.8658 85550.34282 133809.1355 34850.35483 53434.55514 PG 20:3_22:6 8859.661195 7555.965267 12164.34384 18615.35124 9967.013893 10953.60011 16552.07027 15601.34874 7007.088381 8728.666355 PC 16:1_20:4 76638.24969 56898.35288 89480.85101 102583.0145 111952.2832 74771.7 101032.3466 92712.15829 67277.1243 95101.44995 PE 16:0_20:4 910785.6318 1050018.846 1408750.928 1294901.569 986228.133 1067037.861 1157176.463 1136025.578 988810.0934 1242965.287 PE 16:1_22:6 243162.6465 196004.2137 307603.6584 344991.175 327122.6957 270637.8518 329346.7132 300700.5987 235815.8384 300451.6698 PS 20:2_20:4 159023.3909 145931.6225 115802.51 77595.28231 169356.2468 113388.8394 101959.5024 119089.4533 164771.9219 181194.4337 PE O-18:0/18:2 93221.48999 46888.12653 35348.39553 30651.84105 60215.25985 63747.85867 35087.83646 35276.8996 51326.54378 73780.68884 PE 18:1_18:2 161268.312 206270.2348 160703.9543 143193.4978 244145.9631 192385.1605 137014.1519 161184.5704 185834.1667 250207.1245 HexCer 42:1;O2 32599.81014 33900.18182 32159.90952 44534.54676 35522.73938 34775.07338 30111.73744 44925.48956 29755.88596 37751.28908 PE 18:1_20:3 47758.03699 56975.68799 62598.24999 62596.68885 50458.18571 58921.72629 55099.46116 63600.73947 50376.12302 53861.43488 PI 18:0_22:6 29806.53585 22468.0615 19827.80716 10550.17552 38273.52082 21870.59676 15471.75744 28238.99679 28384.95953 28868.41327 Cer 18:2;O2/22:0 1008592.257 1273885.521 1448173.324 1805506.486 752339.6039 1418754.626 1554445.338 1673591.032 838416.1785 709438.9602 SM 41:1;O2 693915.241 651068.3575 671840.9432 744926.2147 470166.632 684166.1371 724041.0446 783901.1399 514533.4895 547913.3067 PG 18:1_22:6 69912.49885 74441.81173 89629.25058 141524.1863 70473.3531 75716.47773 117212.4714 103178.1214 77837.50371 76410.9607 Cer 18:2;O2/23:0 523068.1288 698905.6603 792212.1959 1168461.163 400190.554 821599.6099 1000203.298 942709.9646 402975.9971 454382.8625 PC 20:3_22:6 60202.34731 37656.70227 67908.34911 91964.8035 49201.98268 49187.19237 89365.25175 67185.11549 54012.59367 44589.43964 PE 20:3_22:5 47663.77352 33630.63636 61250.71862 134176.0318 53288.11611 59602.72273 106000.8384 79866.68798 47601.02866 40103.19166 PC 18:0_20:4 3251753.86 3179129.772 3924027.539 3537725.956 3008020.616 3513998.872 4005258.777 2887199.997 2937636.615 3595065.315 PI 18:0_22:3 19602.48659 22642.55425 23163.00687 14916.49275 26021.42625 18767.74749 16699.84053 16431.56736 23180.09491 31701.97528 PE 18:0_22:6 15260194.47 15769245.09 14275426.14 13344346.69 17125935.13 14919366.14 13925387.38 14368017.9 16015761.14 16645813.88 PC O-16:1/22:5 206623.218 204896.6057 289651.396 293685.0683 156856.825 226428.0508 314108.8069 243744.2116 224117.5227 140144.0518 PC 18:0_20:3 265241.097 248161.6251 403521.3681 376581.7148 310826.9997 352209.9096 373497.6148 337007.8661 226643.7255 316546.546 PC O-18:1/20:4 17328.63773 13622.03729 14629.27769 17185.99282 14406.17771 16698.896 16708.10129 11443.24544 16302.32072 16068.62409 PG 16:0_22:6 21741.43671 19011.05955 18883.21127 29864.0602 19829.10337 17424.27087 27827.7167 23475.41051 21699.6339 18844.2233 PE 39:4 38175.70987 33802.15466 29883.2495 49722.95593 40219.218 29437.86577 42583.83458 42992.17608 43121.33951 33661.23489 MS_METABOLITE_DATA_END #METABOLITES METABOLITES_START metabolite_name Formula m/z Retention time PC 20:1_22:6 C50H86NO8P 904.6056 7.629 SM 34:2;O2 C39H77N2O6P 745.5489 5.989 SM 39:2;O2 C43H85N2O6P 801.6117 7.778 FA 18:1 C18H34O2 281.2491 4.47 PC 20:0_22:6 C50H88NO8P 906.6221 8.458 PE 19:0_20:4 C44H80NO8P 780.5547 8.541 PE 19:0_22:6 C46H80NO8P 804.5556 8.29 PE 20:0_20:4 C45H82NO8P 794.5698 8.96 PE O-18:2/18:2 C41H76NO7P 724.5276 7.947 PC 18:2_18:3 C44H78NO8P 824.5423 5.955 PC O-16:1/18:1 C42H82NO7P 788.58 8.193 PC 19:0_22:5 C49H88NO8P 894.6211 8.294 PC 20:0_20:4 C48H88NO8P 882.6215 8.713 SM 38:1;O2 C43H87N2O6P 803.6302 8.571 PE 20:0_22:6 C47H82NO8P 818.5697 8.702 PG 22:6_22:6 C50H75O10P 865.5024 4.947 PC 18:0_18:1 C44H86NO8P 832.6099 8.641 PC 14:0_22:6 C44H76NO8P 822.5289 5.905 PG 18:2_20:4 C44H75O10P 793.5005 5.369 PE O-40:6 C45H80NO7P 776.5611 8.548 PG 18:1_18:2 C42H77O10P 771.5179 5.943 PE 18:1_22:6 C45H76NO8P 788.5256 7.065 PG 18:1_18:1 C42H79O10P 773.5328 6.514 PE 18:2_18:2 C41H74NO8P 738.5084 6.817 PC 18:0_22:5 C48H86NO8P 880.6083 7.876 PE O-16:1/18:2 C39H74NO7P 698.5128 7.768 PE O-18:1/22:4 C45H82NO7P 778.5743 9.126 PC 17:0_18:1 C43H84NO8P 818.5898 8.206 PE 20:1_22:6 C47H80NO8P 816.5539 7.893 PE 18:0_22:5 C45H80NO8P 792.5563 8.429 PE 16:0_22:6 C43H74NO8P 762.5099 6.919 PC 16:0_20:3 C44H82NO8P 828.5739 7.48 PG 16:0_18:1 C40H77O10P 747.5203 6.997 PG 18:2_20:3 C44H77O10P 795.5159 5.6 PC O-16:1/18:2 C42H80NO7P 786.5644 7.494 PC 18:2_20:4 C46H80NO8P 850.5617 6.383 PC 20:5_22:6 C50H78NO8P 896.5435 5.514 PE O-16:1/22:4 C43H78NO7P 750.5435 8.275 PC 18:3_22:6 C48H78NO8P 872.5443 5.654 PE O-14:1/20:4 C39H70NO7P 694.4804 6.761 PC 16:0_18:1 C42H82NO8P 804.5782 7.753 PE O-18:1/20:4 C43H78NO7P 750.5458 8.516 PE 18:1_20:4 C43H76NO8P 764.5261 7.273 SM 40:2;O2 C45H89N2O6P 829.6446 8.715 PC 22:5_22:6 C52H82NO8P 924.5742 6.062 PC 17:0_18:2 C43H82NO8P 816.5741 7.499 SM 42:3;O2 C47H91N2O6P 855.6595 8.683 PC 18:1_18:2 C44H82NO8P 828.5777 7.181 PC 18:1_22:5 C48H84NO8P 878.5898 7.075 Cer 18:2;O2/18:0 C36H69NO3 608.5257 8.055 PC 19:0_18:1 C45H88NO8P 846.6215 9.066 PC 18:0_20:2 C46H88NO8P 858.6226 8.766 PC 19:0_22:6 C49H86NO8P 892.6077 8.024 LPC 22:6 C30H50NO7P 612.3297 1.605 SM 38:0;O2 C43H89N2O6P 805.6413 8.905 SM 40:1;O2 C45H91N2O6P 831.6618 9.459 SM 42:2;O2 C47H93N2O6P 857.6771 9.412 PC O-16:2/22:6 C46H78NO7P 832.5502 6.878 PE O-18:3/18:2 C41H74NO7P 722.5117 7.167 PC 14:0_18:2 C40H76NO8P 774.525 6.258 PC 38:5 C46H82NO8P 852.5767 7.299 LPE 18:0 C23H48NO7P 480.3094 3.446 PE 16:0_18:0 C39H78NO8P 718.5382 8.83 PC 18:2_18:2 C44H80NO8P 826.562 6.519 PE 15:0_22:6 C42H72NO8P 748.4926 6.523 PG 22:5_22:6 C50H77O10P 867.5198 5.136 PE O-38:7 C43H74NO7P 746.5154 7.358 PC O-16:0/22:5 C46H84NO7P 838.5956 7.487 PG 36:2 C42H79O10P 773.5345 7.182 PG 16:0_16:0 C38H75O10P 721.5022 6.885 PG 18:1_20:4 C44H77O10P 795.5166 5.827 PE 17:0_20:4 C42H76NO8P 752.5237 7.662 PI 18:0_20:4 C47H83O13P 885.5522 6.877 PE 20:2_22:6 C47H78NO8P 814.5385 7.165 PC 18:1_18:1 C44H84NO8P 830.5905 7.794 PG 20:5_22:6 C48H73O10P 839.4859 4.713 PC 16:0_22:4 C46H84NO8P 854.5875 7.569 HexCer 18:1;O2/20:0 C44H85NO8 800.6244 8.921 PC 16:0_22:5 C46H82NO8P 852.5778 7.009 PE 18:3_22:6 C45H72NO8P 784.4921 5.835 PC 16:2_22:6 C46H76NO8P 846.5277 5.527 PC 18:2_22:5 C48H82NO8P 876.5754 6.432 PC 34:3 C42H78NO8P 800.5431 6.399 SM 39:1;O2 C44H89N2O6P 817.6448 9.023 PE 18:0_20:1 C43H84NO8P 772.5848 9.703 SM 32:1;O2 C37H75N2O6P 719.5335 5.859 PS 18:1_20:2 C44H80NO10P 812.5413 8.91 Cer 18:0;(OH)3/20:0 C38H77NO4 656.5823 9.355 PE O-18:1/18:2 C41H78NO7P 726.5451 8.674 PE O-18:3/22:6 C45H74NO7P 770.5153 6.823 PS 18:0_22:6 C46H78NO10P 834.5325 6.85 PC 18:0_22:4 C48H88NO8P 882.6223 8.456 PE 20:3_20:4 C45H76NO8P 788.5241 6.837 PC O-16:0/20:4 C44H82NO7P 812.5789 7.466 PE 18:1_22:5 C45H78NO8P 790.5395 7.658 PC 18:0_18:2 C44H84NO8P 830.5943 7.983 PC 16:0_18:2 C42H80NO8P 802.5632 7.098 Cer 18:0;(OH)3/24:0 C42H85NO4 712.6447 10.976 Cer 18:2;O2/24:1 C42H79NO3 690.6049 9.835 PE 20:4_22:6 C47H74NO8P 810.5075 6.199 PE O-18:1/18:1 C41H80NO7P 728.5589 9.356 PC 19:0_20:4 C47H86NO8P 868.6064 8.282 PC O-18:0/22:6 C48H86NO7P 864.6101 8.094 PE O-18:2/22:6 C45H76NO7P 772.5305 7.448 PC O-40:7 C48H84NO7P 862.5958 7.954 PC 16:0_16:1 C40H78NO8P 776.5425 6.886 PC 20:2_22:6 C50H84NO8P 902.5895 6.894 PE 16:0_18:2 C39H74NO8P 714.5078 7.352 PC 22:6_22:6 C52H80NO8P 922.5606 5.811 PG 18:2_22:6 C46H75O10P 817.5049 5.152 PE O-16:1/20:4 C41H74NO7P 722.5149 7.635 Cer 18:0;(OH)3/22:0 C40H81NO4 684.6138 10.174 HexCer 42:2;O2 C48H91NO8 854.671 9.745 PE 18:0_18:2 C41H78NO8P 742.5402 8.253 Cer 18:1;O2/23:0 C41H81NO3 680.6215 11.003 PC O-16:0/16:0 C40H82NO7P 764.5796 8.24 Cer 18:1;O2/24:0 C42H83NO3 694.6367 11.372 SM 34:1;O2 C39H79N2O6P 747.5659 6.752 PE O-38:6 C43H76NO7P 748.5313 7.681 PG 16:0_20:4 C42H75O10P 769.5008 6.25 PC 24:0_18:2 C50H96NO8P 914.6845 10.49 Cer 18:1;O2/22:0 C40H79NO3 666.6057 10.577 PC 18:3_20:4 C46H78NO8P 848.5443 5.845 PE 20:3_22:6 C47H76NO8P 812.5226 6.834 PE O-18:2/22:5 C45H78NO7P 774.543 8.03 PG 16:0_18:2 C40H75O10P 745.5038 6.411 PC 18:2_22:6 C48H80NO8P 874.5631 6.169 SM 40:0;O2 C45H93N2O6P 833.6736 9.759 HexCer 18:1;O2/22:0 C46H89NO8 828.656 9.783 PE O-18:1/22:6 C45H78NO7P 774.5462 8.256 PE 18:2_22:5 C45H76NO8P 788.5253 6.658 PG 18:0_18:1 C42H81O10P 775.549 7.867 PE 18:0_20:5 C43H76NO8P 764.524 7.549 LPC 18:2 C26H50NO7P 564.3302 1.771 PC 16:0_20:4 C44H80NO8P 826.5635 6.95 PG 18:0_20:3 C44H81O10P 799.5478 7.459 PC O-18:1/16:0 C42H84NO7P 790.5954 8.307 PE 16:1_20:4 C41H72NO8P 736.4918 6.442 PE O-16:1/18:1 C39H76NO7P 700.5284 8.491 PC 18:1_22:6 C48H82NO8P 876.5783 6.819 PE 18:2_20:4 C43H74NO8P 762.5078 6.621 PE O-18:1/16:0 C39H78NO7P 702.5434 9.289 FAHFA 2:0_18:0 C20H38O4 341.2702 3.649 SM 41:2;O2 C46H91N2O6P 843.6594 9.143 PE 18:2_22:6 C45H74NO8P 786.5108 6.388 SM 42:1;O2 C47H95N2O6P 859.6925 10.3 PG 18:0_22:6 C46H79O10P 821.5371 6.867 PC 17:1_22:6 C47H80NO8P 862.5599 6.453 PE 17:0_22:6 C44H76NO8P 776.5251 7.409 PC O-16:0/22:6 C46H82NO7P 836.5822 7.218 CL 72:8 C81H142O17P2 1447.9634 12.092 PE 22:4_22:6 C49H78NO8P 838.5348 6.835 PC O-18:2/22:6 C48H82NO7P 860.5811 7.154 PC O-18:0/18:2 C44H86NO7P 816.6115 8.5 PE 16:0_20:5 C41H72NO8P 736.4915 6.618 PE 18:0_18:1 C41H80NO8P 744.555 8.91 LPE 16:0 C21H44NO7P 452.2781 2.269 PG 20:4_22:6 C48H75O10P 841.5044 5.12 PE 18:0_20:4 C43H78NO8P 766.5411 8.094 PC 20:4_22:6 C50H80NO8P 898.5599 6.006 PC O-18:1/22:6 C48H84NO7P 862.5959 7.275 PC 16:0_16:0 C40H80NO8P 778.5624 7.686 PE 16:0_18:1 C39H76NO8P 716.5234 8.02 PC O-16:1/22:6 C46H80NO7P 834.5674 7.069 LPC 16:0 C24H50NO7P 540.3317 2.213 PE 18:0_22:4 C45H82NO8P 794.569 8.703 PC O-16:1/20:4 C44H80NO7P 810.5655 7.324 PC 19:0_18:2 C45H86NO8P 844.6048 8.412 SM 36:1;O2 C41H83N2O6P 775.5938 7.675 PC 16:0_18:0 C42H84NO8P 806.593 8.559 SM 43:1;O2 C48H97N2O6P 873.7049 10.701 PC 17:0_22:6 C47H82NO8P 864.5766 7.152 PG 35:1 C41H79O10P 761.533 7.411 Cer 18:2;O2/24:0 C42H81NO3 692.6198 10.695 LPC 20:4 C28H50NO7P 588.3298 1.701 PE 17:1_22:6 C44H74NO8P 774.5096 6.652 PC 18:0_22:6 C48H84NO8P 878.5939 7.581 SM 37:1;O2 C42H85N2O6P 789.6087 8.137 PE 18:0_20:3 C43H80NO8P 768.5538 8.464 LPC 18:0 C26H54NO7P 568.3633 3.338 Cer 18:1;O2/24:1 C42H81NO3 692.6216 10.521 PC 16:0_22:6 C46H80NO8P 850.5625 6.714 SM 33:1;O2 C38H77N2O6P 733.5495 6.288 PC O-18:3/22:6 C48H80NO7P 858.5641 6.497 FA 18:0 C18H36O2 283.2662 5.145 PE O-18:0/20:4 C43H80NO7P 752.5584 8.646 PC 16:1_22:6 C46H78NO8P 848.5455 6.036 PG 18:0_20:4 C44H79O10P 797.533 7.103 PE 18:0_20:2 C43H82NO8P 770.5689 8.988 PC 15:0_22:6 C45H78NO8P 836.5447 6.297 Cer 18:0;O3/24:1 C42H83NO4 710.6292 10.111 PG 22:4_22:6 C50H79O10P 869.5335 5.55 PC 18:0_20:1 C46H90NO8P 860.6421 9.447 PE 19:0_18:2 C42H80NO8P 756.554 8.669 HexCer 18:1;O2/23:0 C47H91NO8 842.6713 10.182 LPC 18:1 C26H52NO7P 566.346 2.417 PG 20:3_22:6 C48H77O10P 843.5164 5.338 PC 16:1_20:4 C44H78NO8P 824.5433 6.232 PE 16:0_20:4 C41H74NO8P 738.5098 7.2 PE 16:1_22:6 C43H72NO8P 760.4931 6.202 PS 20:2_20:4 C46H78NO10P 834.5259 8.095 PE O-18:0/18:2 C41H80NO7P 728.5585 8.802 PE 18:1_18:2 C41H76NO8P 740.5233 7.441 HexCer 42:1;O2 C48H93NO8 856.6872 10.583 PE 18:1_20:3 C43H78NO8P 766.538 7.697 PI 18:0_22:6 C49H83O13P 909.5479 6.674 Cer 18:2;O2/22:0 C40H77NO3 664.59 9.866 SM 41:1;O2 C46H93N2O6P 845.6764 9.879 PG 18:1_22:6 C46H77O10P 819.5175 5.656 Cer 18:2;O2/23:0 C41H79NO3 678.6042 10.325 PC 20:3_22:6 C50H82NO8P 900.5749 6.365 PE 20:3_22:5 C47H78NO8P 814.5393 6.852 PC 18:0_20:4 C46H84NO8P 854.5944 7.834 PI 18:0_22:3 C49H89O13P 915.598 6.65 PE 18:0_22:6 C45H78NO8P 790.5411 7.871 PC O-16:1/22:5 C46H82NO7P 836.5807 7.441 PC 18:0_20:3 C46H86NO8P 856.6076 8.207 PC O-18:1/20:4 C46H84NO7P 838.5948 8.226 PG 16:0_22:6 C44H75O10P 793.5011 6.064 PE 39:4 C44H80NO8P 780.5539 8.288 METABOLITES_END #END