#METABOLOMICS WORKBENCH boudreaulab_20240604_145401 DATATRACK_ID:4899 STUDY_ID:ST003247 ANALYSIS_ID:AN005319 PROJECT_ID:PR002016 VERSION 1 CREATED_ON June 6, 2024, 8:24 am #PROJECT PR:PROJECT_TITLE Effects of mitoregulin loss on cardiac and mitochondrial lipids in mice PR:PROJECT_SUMMARY We and others discovered a highly-conserved mitochondrial transmembrane PR:PROJECT_SUMMARY microprotein, named Mitoregulin (Mtln), that supports lipid metabolism. We PR:PROJECT_SUMMARY reported that Mtln strongly binds cardiolipin (CL), increases mitochondrial PR:PROJECT_SUMMARY respiration and Ca2+ retention capacities, and reduces reactive oxygen species PR:PROJECT_SUMMARY (ROS). Here we extend our observation of Mtln-CL binding and examine Mtln PR:PROJECT_SUMMARY influence on cristae structure and mitochondrial membrane integrity during PR:PROJECT_SUMMARY stress. We demonstrate that mitochondria from constitutive- and inducible PR:PROJECT_SUMMARY Mtln-knockout (KO) mice are susceptible to membrane freeze-damage and that this PR:PROJECT_SUMMARY can be rescued by acute Mtln re-expression. In mitochondrial-simulated lipid PR:PROJECT_SUMMARY monolayers, we show that synthetic Mtln decreases lipid packing and monolayer PR:PROJECT_SUMMARY elasticity. Lipidomics revealed that Mtln-KO heart tissues show broad decreases PR:PROJECT_SUMMARY in 22:6-containing lipids and increased cardiolipin damage/remodeling. Lastly, PR:PROJECT_SUMMARY we demonstrate that Mtln-KO mice suffer worse myocardial ischemia-reperfusion PR:PROJECT_SUMMARY injury, hinting at a translationally-relevant role for Mtln in cardioprotection. PR:PROJECT_SUMMARY Our work supports a model in which Mtln binds cardiolipin and stabilizes PR:PROJECT_SUMMARY mitochondrial membranes to broadly influence diverse mitochondrial functions, PR:PROJECT_SUMMARY including lipid metabolism, while also protecting against stress. PR:INSTITUTE University of Iowa PR:LAST_NAME Boudreau PR:FIRST_NAME Ryan PR:ADDRESS 4334 PBDB, 169 Newton Rd, Iowa City, IA 52242 PR:EMAIL ryan-boudreau@uiowa.edu PR:PHONE 3193535573 #STUDY ST:STUDY_TITLE Effects of mitoregulin loss in aged female mice ST:STUDY_SUMMARY Cardiac lipidome analysis in aged (21 to 23-months old) female wildtype and mtln ST:STUDY_SUMMARY knockout mice ST:INSTITUTE University of Iowa ST:LAST_NAME Boudreau ST:FIRST_NAME Ryan ST:ADDRESS 4334 PBDB, 169 Newton Rd, Iowa City, IA 52242 ST:EMAIL ryan-boudreau@uiowa.edu ST:PHONE 3193535573 #SUBJECT SU:SUBJECT_TYPE Mammal SU:SUBJECT_SPECIES Mus musculus SU:TAXONOMY_ID 10090 SU:GENDER Female #FACTORS #SUBJECT_SAMPLE_FACTORS: SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Raw file names and additional sample data SUBJECT_SAMPLE_FACTORS - 1066-23 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_25_+_1066-23_WT.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_118_-_1066-23_WT.mzML SUBJECT_SAMPLE_FACTORS - 1066-4 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_11_+_1066-4_WT.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_125_-_1066-4_WT.mzML SUBJECT_SAMPLE_FACTORS - 1074-34 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_19_+_1074-34_WT.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_115_-_1074-34_WT.mzML SUBJECT_SAMPLE_FACTORS - 1103-12 Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_24_+_1103-12_WT.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_112_-_1103-12_WT.mzML SUBJECT_SAMPLE_FACTORS - 1133-1 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_14_+_1133-1_KO.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_114_-_1133-1_KO.mzML SUBJECT_SAMPLE_FACTORS - 1143-2 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_15_+_1143-2_KO.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_107_-_1143-2_KO.mzML SUBJECT_SAMPLE_FACTORS - 1143-3 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_13_+_1143-3_KO.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_123_-_1143-3_KO.mzML SUBJECT_SAMPLE_FACTORS - 1145-2 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_26_+_1145-2_KO.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_124_-_1145-2_KO.mzML SUBJECT_SAMPLE_FACTORS - 1152-1 Genotype:KO | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_07_+_1152-1_KO.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_108_-_1152-1_KO.mzML SUBJECT_SAMPLE_FACTORS - WTF Genotype:WT | Sample source:heart tissue RAW_FILE_NAME(Raw file name POS mode)=6530_20190815_18_+_WTF_WT.mzML; RAW_FILE_NAME(Raw file name NEG mode)=6530_20190815_106_-_WTF_WT.mzML #COLLECTION CO:COLLECTION_SUMMARY Mtln-KO and WT mice were fasted for 4-6 h, and while under deep CO:COLLECTION_SUMMARY ketamine/xylazine anesthesia, the heart apex was snipped off and immediately CO:COLLECTION_SUMMARY snap-frozen by LN2 immersion. CO:SAMPLE_TYPE Heart #TREATMENT TR:TREATMENT_SUMMARY No treatment. #SAMPLEPREP SP:SAMPLEPREP_SUMMARY Lipid extraction. Lipid extraction, based on Matyash et al.72, was performed as SP:SAMPLEPREP_SUMMARY follows. All solutions were pre-chilled on ice. Tissues or mitochondrial pellets SP:SAMPLEPREP_SUMMARY were transferred to labeled bead-mill tubes (1.4 mm, MoBio Cat# 13113-50) where SP:SAMPLEPREP_SUMMARY lipids were extracted in a solution of 250 µL PBS, 225 µL MeOH containing SP:SAMPLEPREP_SUMMARY internal standards, and 750 µL MTBE (methyl tert-butyl ether). Internal SP:SAMPLEPREP_SUMMARY standards were Avanti SPLASH LipidoMix (Lot#12) at 10 µL per sample and SP:SAMPLEPREP_SUMMARY Cambridge Isotope laboratories NSK-B and NSK-B-G1 (deuterated carnitines) at 10 SP:SAMPLEPREP_SUMMARY µL per sample. The samples were homogenized in one 30 s cycle using the Omni SP:SAMPLEPREP_SUMMARY Bead Ruptor followed by a rest on ice for 1 h. An addition of 188 µL PBS was SP:SAMPLEPREP_SUMMARY made to induce phase separation. After centrifugation at 16,000 g for 5 minutes SP:SAMPLEPREP_SUMMARY at 4 °C, the upper phases were collected and evaporated to dryness under a SP:SAMPLEPREP_SUMMARY gentle nitrogen stream at room temperature. Lipid samples were reconstituted in SP:SAMPLEPREP_SUMMARY 500 µL IPA (isopropyl alcohol) and transferred to an LC-MS vial with insert SP:SAMPLEPREP_SUMMARY (Agilent 5182-0554 and 5183-2086) for analysis. Concurrently, a process blank SP:SAMPLEPREP_SUMMARY sample and pooled quality control (QC) sample was prepared by taking equal SP:SAMPLEPREP_SUMMARY volumes (~50 µL) from each sample after final resuspension. #CHROMATOGRAPHY CH:CHROMATOGRAPHY_SUMMARY Negative Mode RP LCMS CH:CHROMATOGRAPHY_TYPE Reversed phase CH:INSTRUMENT_NAME Agilent 1290 Infinity CH:COLUMN_NAME Waters ACQUITY UPLC CSH C18 (100 x 2.1mm,1.7um) CH:SOLVENT_A 40% water/60% acetonitrile; 10 mM ammonium formate CH:SOLVENT_B 90% isopropanol/9% acetonitrile/1% water; 10 mM ammonium acetate CH:FLOW_GRADIENT Started at 15% mobile phase B then increased to 30% B over 2.4 min. It CH:FLOW_GRADIENT sequentially increased to 48% B from 2.4 – 3.0 min, 82% B from 3 – 13.2 min, CH:FLOW_GRADIENT and 99% B from 13.2 – 13.8 min where it’s held until 16.7 min and returned CH:FLOW_GRADIENT to the initial conditions and equilibrated for 5 min. CH:FLOW_RATE 0.4 mL min CH:COLUMN_TEMPERATURE 65 #ANALYSIS AN:ANALYSIS_TYPE MS #MS MS:INSTRUMENT_NAME Agilent 6530 QTOF MS:INSTRUMENT_TYPE QTOF MS:MS_TYPE ESI MS:ION_MODE NEGATIVE MS:MS_COMMENTS For negative mode, the source gas temperature was set to 300 °C, with a drying MS:MS_COMMENTS gas flow of 11 L/minute, a nebulizer pressure of 30 psig, sheath gas temp of 350 MS:MS_COMMENTS °C and sheath gas flow 11 L/minute. VCap voltage was set at 3500 V, nozzle MS:MS_COMMENTS voltage 75 V, fragmentor at 175 V, skimmer at 75 V and octopole RF peak at 750 MS:MS_COMMENTS V. For data processing, Agilent MassHunter (MH) Workstation and software MS:MS_COMMENTS packages MH Qualitiative and MH Quantitative were used. The pooled QC (n=8) and MS:MS_COMMENTS process blank (n=4) were injected throughout the sample queue to ensure the MS:MS_COMMENTS reliability of acquired lipidomics data. For lipid annotation, accurate mass and MS:MS_COMMENTS MS/MS matching was used with the Agilent Lipid Annotator library. Results from MS:MS_COMMENTS the positive and negative ionization modes from Lipid Annotator were merged MS:MS_COMMENTS based on the class of lipid identified. Data exported from MH Quantitative was MS:MS_COMMENTS evaluated using Excel where initial lipid targets are parsed based on the MS:MS_COMMENTS following criteria. Only lipids with relative standard deviations (RSD) less MS:MS_COMMENTS than 30% in QC samples are used for data analysis. Additionally, only lipids MS:MS_COMMENTS with background AUC counts in process blanks that are less than 30% of QC are MS:MS_COMMENTS used for data analysis. The parsed excel data tables are normalized based on the MS:MS_COMMENTS ratio to class-specific internal standards, then to sum prior to statistical MS:MS_COMMENTS analysis. #MS_METABOLITE_DATA MS_METABOLITE_DATA:UNITS pmol lipid per mg tissue MS_METABOLITE_DATA_START Samples WTF 1066-23 1066-4 1074-34 1103-12 1133-1 1143-2 1143-3 1145-2 1152-1 Factors Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:WT | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Genotype:KO | Sample source:heart tissue Cer 38:2;O2 52.521 47.762 64.422 47.815 74.934 31.443 34.143 83.781 54.748 59.428 Cer 40:2;O2 109.699 123.876 154.806 133.717 192.683 90.296 78.160 164.651 141.084 128.692 Cer 38:0;O2 4.846 6.209 4.727 4.388 8.152 148.330 3.283 7.078 19.775 4.456 Cer 38:1;O2 117.906 98.569 128.996 109.743 155.749 86.189 76.822 169.591 123.352 127.963 Cer 41:2;O2 59.384 79.982 72.732 72.800 80.463 56.083 45.980 75.858 82.351 53.751 Cer 42:1;O2 87.504 90.030 92.709 110.544 131.294 100.072 69.008 104.647 110.071 87.711 Cer 42:2;O2 155.278 124.797 161.302 151.016 260.249 130.331 127.141 189.581 238.715 178.978 Cer 18:1;O2/18:0 73.844 82.491 65.598 84.225 90.224 61.955 53.859 80.994 83.547 67.998 Cer 18:1;O2/22:0 223.442 230.738 268.556 274.679 360.987 226.194 182.989 322.554 251.418 275.033 Cer 18:1;O2/25:0 2.205 2.848 2.637 3.189 3.826 6.073 1.984 3.226 2.980 2.047 Cer 18:2;O2/24:1 50.747 46.749 55.894 45.176 85.209 36.104 34.288 58.953 75.867 53.249 Cer 39:1;O2 17.799 30.731 32.133 25.392 35.233 27.231 23.238 36.028 24.999 25.990 Cer 41:1;O2 68.634 86.282 75.371 84.705 88.558 80.370 58.622 82.464 86.717 64.279 PE O-16:1/18:1 21.284 23.924 28.085 21.105 21.142 25.691 28.998 28.469 30.655 22.614 PE O-16:1/18:2 35.336 33.352 32.436 26.222 23.899 37.275 43.636 37.080 36.873 32.052 PE O-16:1/20:4 230.303 249.254 236.358 237.632 218.396 226.208 224.396 245.618 243.289 227.076 PE O-16:1/22:4 19.290 22.235 23.004 27.504 27.419 19.979 22.875 25.039 23.788 20.723 PE O-16:1/22:5 303.264 364.813 353.301 339.105 308.599 300.535 341.618 423.305 404.332 316.926 PE O-16:1/22:6 2453.028 2787.867 2392.561 2475.255 2249.328 2227.698 2318.280 2627.475 2584.530 2320.192 PE O-18:1/18:1 13.361 8.971 13.852 9.295 15.708 11.229 12.159 13.532 15.989 13.578 PE O-18:1/18:2 90.859 59.958 72.488 51.889 71.367 81.676 96.670 82.294 84.782 77.607 PE O-18:1/20:4 261.763 214.036 265.384 210.259 242.377 232.985 265.116 264.858 267.755 229.726 PE O-18:1/22:4 15.556 15.605 16.678 17.443 22.630 14.269 18.133 19.037 17.911 15.467 PE O-18:1/22:5 169.275 136.254 166.471 133.138 161.704 131.231 154.489 194.250 186.542 175.841 PE O-18:1/22:6 2206.297 1812.605 2112.418 1746.749 1801.156 1844.980 1841.339 2025.651 2168.888 2168.418 PE O-18:2/18:2 9.935 12.293 12.428 10.045 9.989 12.111 14.926 14.810 12.581 10.374 PE O-18:2/22:6 1053.418 1404.278 1484.310 1266.698 1262.588 1102.272 1162.541 1522.919 1470.846 1158.137 PE O-18:3/22:6 992.770 1244.712 1309.550 954.681 1122.819 1173.405 986.493 1371.984 1382.529 1128.033 PE O-38:6 24.882 23.808 25.721 21.924 21.936 22.025 24.854 27.701 25.979 23.474 FA 18:2 10.614 17.676 9.667 11.111 5.016 12.669 14.225 10.718 30.676 6.266 HexCer 18:1;O2/22:0 8.053 5.031 6.029 7.214 6.824 6.352 5.564 6.557 8.669 8.622 HexCer 18:1;O2/24:0 14.052 11.077 10.915 16.024 11.622 10.883 10.740 11.467 14.316 14.129 LPE 18:0 9.047 7.718 7.809 10.352 9.051 6.406 8.193 6.387 6.701 8.148 PE 16:0_18:0 8.738 9.726 9.899 9.822 7.772 9.477 8.746 10.414 11.196 9.105 PE 16:0_18:1 21.658 22.287 28.502 25.059 21.599 25.612 27.853 30.600 35.440 22.650 PE 16:0_18:2 45.681 36.111 40.279 41.348 32.125 38.817 56.293 54.016 55.983 44.127 PE 16:0_20:4 126.468 112.295 119.391 126.692 108.564 94.689 112.066 138.449 122.817 104.042 PE 16:0_22:6 2087.650 1698.402 2105.164 2111.902 1300.006 1744.548 2148.439 2247.877 2246.947 2180.853 PE 16:1_22:6 71.002 72.375 59.634 73.104 53.735 62.809 64.099 62.477 88.126 65.611 PE 17:0_22:6 79.132 102.367 105.516 100.721 93.089 84.842 87.054 92.801 104.973 90.444 PE 18:0_18:1 51.208 45.645 67.808 66.467 56.851 61.437 60.234 61.184 73.109 50.577 PE 18:0_18:2 205.564 144.859 153.378 170.931 136.269 147.121 229.487 188.641 195.607 180.646 PE 18:0_20:2 7.785 6.554 7.565 6.828 7.997 6.143 6.873 8.340 7.613 8.574 PE 18:0_20:3 22.591 24.566 22.419 22.693 22.780 19.980 26.066 26.615 25.679 24.645 PE 18:0_20:4 1777.490 1610.325 1796.520 1872.128 1686.616 1398.976 1448.885 1690.435 1612.948 1600.276 PE 18:0_22:4 21.534 20.884 23.248 36.028 39.141 22.102 21.465 24.449 27.181 23.984 PE 18:0_22:5 236.852 186.168 197.111 252.417 246.959 170.868 180.115 177.662 221.815 191.312 PE 18:0_22:6 5626.069 5470.950 5029.935 5597.159 5379.934 4589.710 4908.227 5220.147 5449.926 5320.052 PE 18:1_18:2 36.463 30.518 40.199 35.884 32.166 32.079 53.758 52.366 62.638 36.843 PE 18:1_20:4 214.966 195.111 266.986 237.352 233.418 182.455 210.738 255.215 250.566 200.919 PE 18:1_22:6 1347.880 1164.211 1529.114 1566.818 1457.023 1248.476 1484.023 1571.846 1662.143 1341.532 PE 18:2_18:2 41.120 28.697 39.042 33.523 28.000 42.816 59.112 59.940 75.455 35.273 PE 18:2_20:4 41.103 36.922 45.151 35.510 29.134 35.705 42.987 46.709 39.951 31.604 PE 18:2_22:5 35.515 35.145 42.362 33.655 29.072 38.089 33.368 39.690 41.175 37.553 PE 18:2_22:6 593.229 572.910 574.532 565.072 464.198 540.364 572.323 597.064 543.322 498.844 PE 18:3_22:6 23.070 24.467 24.757 23.575 15.691 22.881 21.351 24.831 21.276 19.006 PE 19:0_20:4 12.652 16.220 20.425 12.479 15.111 14.784 12.697 16.725 16.286 14.822 PE 19:0_22:6 47.273 64.733 68.978 51.066 57.894 55.852 54.256 57.176 69.538 54.307 PE 20:0_22:6 17.774 12.315 16.105 14.522 17.687 11.641 12.781 16.070 18.455 16.446 PE 20:1_22:6 19.023 6.958 15.426 9.839 18.543 9.748 10.028 14.806 14.020 17.578 PE 20:2_22:6 10.088 12.442 10.920 11.459 15.382 8.611 8.536 10.706 10.714 10.604 PE 20:3_22:6 22.097 25.822 20.315 25.217 28.775 19.556 18.796 22.024 18.608 15.194 PE 20:4_22:6 13.034 13.426 11.789 14.882 12.136 12.227 10.321 11.275 8.524 6.588 PE 22:6_22:6 8.154 6.540 5.775 8.170 5.496 5.463 4.049 4.804 5.105 4.717 PE 38:5 65.977 54.719 59.013 56.458 56.549 50.118 54.117 65.576 67.615 59.741 PG 16:0_18:1 194.167 210.599 228.669 242.452 252.691 220.983 186.919 236.082 273.577 201.502 PG 16:0_18:2 29.676 23.993 30.112 28.868 24.918 34.342 34.523 35.614 37.849 26.024 PG 18:0_18:1 8.018 7.505 8.271 8.655 9.782 7.938 7.562 8.971 10.920 7.915 PG 18:0_22:6 4.217 4.606 5.108 4.516 2.683 3.967 4.201 4.466 7.766 5.237 PG 18:1_18:2 3.284 7.542 8.755 4.208 7.111 6.291 6.401 9.025 22.339 6.136 PG 18:1_22:6 3.867 3.598 4.078 3.341 3.723 3.988 2.780 3.016 3.915 3.339 PG 18:2_18:2 2.038 4.866 5.365 2.209 2.680 3.544 3.813 5.290 8.534 3.985 PG 18:2_20:4 0.760 1.513 1.282 0.924 1.062 1.300 0.968 1.140 1.582 0.950 PG 18:2_22:6 12.697 16.357 17.357 11.783 8.074 15.324 9.507 11.289 12.878 15.123 PG 20:4_22:6 13.346 14.737 11.503 15.225 10.016 14.957 6.433 7.181 9.912 9.989 PG 22:6_22:6 58.697 33.263 32.476 44.844 17.508 34.867 18.286 15.071 19.455 41.962 PG 38:7 1.817 2.222 2.224 1.872 1.142 2.072 1.672 1.572 2.794 2.072 PI 18:0_22:6 4.276 4.806 3.504 3.292 5.663 3.565 2.508 3.171 4.245 4.678 PS 18:0_22:6 74.384 75.577 60.043 50.638 92.423 78.799 54.593 60.182 55.542 100.309 MS_METABOLITE_DATA_END #METABOLITES METABOLITES_START metabolite_name Formula m/z Retention time Cer 38:2;O2 C38H73NO3 636.5567 8.968 Cer 40:2;O2 C40H77NO3 664.5876 9.857 Cer 38:0;O2 C38H77NO3 640.5875 10.012 Cer 38:1;O2 C38H75NO3 638.5721 9.719 Cer 41:2;O2 C41H79NO3 678.6028 10.257 Cer 42:1;O2 C42H83NO3 694.6343 11.355 Cer 42:2;O2 C42H81NO3 692.6191 10.529 Cer 18:1;O2/18:0 C36H71NO3 566.5512 8.827 Cer 18:1;O2/22:0 C40H79NO3 666.6044 10.566 Cer 18:1;O2/25:0 C43H85NO3 664.6601 11.709 Cer 18:2;O2/24:1 C42H79NO3 646.6139 9.802 Cer 39:1;O2 C39H77NO3 652.5869 10.154 Cer 41:1;O2 C41H81NO3 680.6185 10.969 PE O-16:1/18:1 C39H76NO7P 700.5278 8.507 PE O-16:1/18:2 C39H74NO7P 698.5129 7.795 PE O-16:1/20:4 C41H74NO7P 722.5144 7.676 PE O-16:1/22:4 C43H78NO7P 750.5439 8.298 PE O-16:1/22:5 C43H76NO7P 748.5298 7.724 PE O-16:1/22:6 C43H74NO7P 746.5163 7.412 PE O-18:1/18:1 C41H80NO7P 728.5583 9.364 PE O-18:1/18:2 C41H78NO7P 726.5448 8.689 PE O-18:1/20:4 C43H78NO7P 750.5454 8.535 PE O-18:1/22:4 C45H82NO7P 778.5722 9.138 PE O-18:1/22:5 C45H80NO7P 776.5607 8.566 PE O-18:1/22:6 C45H78NO7P 774.5475 8.294 PE O-18:2/18:2 C41H76NO7P 724.5276 7.955 PE O-18:2/22:6 C45H76NO7P 772.5314 7.495 PE O-18:3/22:6 C45H74NO7P 770.5154 6.871 PE O-38:6 C43H76NO7P 748.5275 8.002 FA 18:2 C18H32O2 279.2327 4.039 HexCer 18:1;O2/22:0 C46H89NO8 828.6544 9.753 HexCer 18:1;O2/24:0 C48H93NO8 856.686 10.549 LPE 18:0 C23H48NO7P 480.3086 3.602 PE 16:0_18:0 C39H78NO8P 718.5378 8.823 PE 16:0_18:1 C39H76NO8P 716.5231 8.052 PE 16:0_18:2 C39H74NO8P 714.5077 7.381 PE 16:0_20:4 C41H74NO8P 738.509 7.251 PE 16:0_22:6 C43H74NO8P 762.5113 7.025 PE 16:1_22:6 C43H72NO8P 760.4925 6.27 PE 17:0_22:6 C44H76NO8P 778.5416 7.428 PE 18:0_18:1 C41H80NO8P 744.5542 8.911 PE 18:0_18:2 C41H78NO8P 742.5405 8.268 PE 18:0_20:2 C43H82NO8P 770.5675 9.01 PE 18:0_20:3 C43H80NO8P 768.5532 8.48 PE 18:0_20:4 C43H78NO8P 766.5425 8.13 PE 18:0_22:4 C45H82NO8P 794.5665 8.684 PE 18:0_22:5 C45H80NO8P 794.5739 8.128 PE 18:0_22:6 C45H78NO8P 790.5426 7.928 PE 18:1_18:2 C41H76NO8P 740.5231 7.477 PE 18:1_20:4 C43H76NO8P 764.5254 7.321 PE 18:1_22:6 C45H76NO8P 788.5264 7.114 PE 18:2_18:2 C41H74NO8P 738.5075 6.861 PE 18:2_20:4 C43H74NO8P 762.5069 6.691 PE 18:2_22:5 C45H76NO8P 788.524 6.735 PE 18:2_22:6 C45H74NO8P 786.5104 6.455 PE 18:3_22:6 C45H72NO8P 784.4911 5.923 PE 19:0_20:4 C44H80NO8P 780.5552 8.55 PE 19:0_22:6 C46H80NO8P 804.557 8.317 PE 20:0_22:6 C47H82NO8P 818.5715 8.72 PE 20:1_22:6 C47H80NO8P 816.5539 7.962 PE 20:2_22:6 C47H78NO8P 814.5379 7.244 PE 20:3_22:6 C47H76NO8P 812.5245 6.67 PE 20:4_22:6 C47H74NO8P 810.507 6.284 PE 22:6_22:6 C49H74NO8P 836.5331 6.084 PE 38:5 C43H76NO8P 764.5233 7.601 PG 16:0_18:1 C40H77O10P 747.521 7.128 PG 16:0_18:2 C40H75O10P 745.5031 6.538 PG 18:0_18:1 C42H81O10P 775.5492 7.981 PG 18:0_22:6 C46H79O10P 821.5331 7.019 PG 18:1_18:2 C42H77O10P 771.5171 6.094 PG 18:1_22:6 C46H77O10P 819.5164 5.826 PG 18:2_18:2 C42H75O10P 769.501 5.561 PG 18:2_20:4 C44H75O10P 793.5011 5.48 PG 18:2_22:6 C46H75O10P 817.5023 5.318 PG 20:4_22:6 C48H75O10P 841.5024 5.224 PG 22:6_22:6 C50H75O10P 865.5034 5.175 PG 38:7 C44H73O10P 791.4854 5.183 PI 18:0_22:6 C49H83O13P 909.5491 6.845 PS 18:0_22:6 C46H78NO10P 836.5503 6.913 METABOLITES_END #END