#METABOLOMICS WORKBENCH jsto1886_20241029_101113 DATATRACK_ID:5323 STUDY_ID:ST003588 ANALYSIS_ID:AN005892 PROJECT_ID:PR002218 VERSION 1 CREATED_ON November 24, 2024, 8:20 pm #PROJECT PR:PROJECT_TITLE Mitochondria complex III is essential for IL-10 secretion in macrophages PR:PROJECT_TITLE independent of respiration PR:PROJECT_SUMMARY Mitochondrial electron transport chain (ETC) function is linked to macrophage PR:PROJECT_SUMMARY function. However, mechanisms underlying mitochondrial ETC control of macrophage PR:PROJECT_SUMMARY immune responses are not fully understood. We used genetic tools to examine the PR:PROJECT_SUMMARY necessity of mitochondrial electron transport chain (ETC)-dependent respiration PR:PROJECT_SUMMARY and the production of reactive oxygen species (mtROS) in macrophage immune PR:PROJECT_SUMMARY responses. Here we report that mitochondrial ETC complex III (CIII)-deficient PR:PROJECT_SUMMARY mouse macrophages, which have impaired macrophage respiration and mtROS PR:PROJECT_SUMMARY production, exhibit increased susceptibility to influenza A virus and PR:PROJECT_SUMMARY LPS-induced endotoxic shock. Mitochondrial CIII-deficient bone marrow-derived PR:PROJECT_SUMMARY macrophages (BMDMs) produced IL-10 but exhibit dampened release following TLR3 PR:PROJECT_SUMMARY or TLR4 stimulation in vitro. Surprisingly, restoring mitochondrial respiration PR:PROJECT_SUMMARY without generating mtROS in mitochondrial CIII-deficient macrophages with Ciona PR:PROJECT_SUMMARY intestinalis alternative oxidase (AOX) is not sufficient to reverse the PR:PROJECT_SUMMARY increased vulnerability to LPS-induced endotoxic shock or rescue IL-10 release PR:PROJECT_SUMMARY in vitro. However, activation of PKA, an mtROS-responsive pathway2, was PR:PROJECT_SUMMARY sufficient to rescue BMDM IL-10 release following LPS stimulation. Additionally, PR:PROJECT_SUMMARY mitochondrial CIII impairment in macrophages does not affect canonical responses PR:PROJECT_SUMMARY to interleukin-4 (IL-4) stimulation. Thus, our results highlight necessity of PR:PROJECT_SUMMARY mitochondrial ROS but not respiration in release of IL-10. PR:INSTITUTE Northwestern University, Feinberg School of Medicine PR:DEPARTMENT Pulmonary PR:LABORATORY Chandel PR:LAST_NAME Stoolman PR:FIRST_NAME Joshua PR:ADDRESS 303 E Superior Street PR:EMAIL joshua.stoolman@northwestern.edu PR:PHONE 7343559440 #STUDY ST:STUDY_TITLE Mitochondria complex III is essential for IL-10 secretion in macrophages ST:STUDY_TITLE independent of respiration ST:STUDY_SUMMARY Mitochondrial electron transport chain (ETC) function is linked to macrophage ST:STUDY_SUMMARY function, however, mechanisms underlying mitochondrial ETC control of macrophage ST:STUDY_SUMMARY immune responses are not fully understood. We used genetic tools to examine the ST:STUDY_SUMMARY necessity of mitochondrial electron transport chain (ETC)-dependent respiration ST:STUDY_SUMMARY and the production of reactive oxygen species (mtROS) in macrophage immune ST:STUDY_SUMMARY responses. Here we report that mitochondrial ETC complex III (CIII)-deficient ST:STUDY_SUMMARY mouse macrophages, which have impaired macrophage respiration and mtROS ST:STUDY_SUMMARY production, exhibit increased susceptibility to influenza A virus and ST:STUDY_SUMMARY LPS-induced endotoxic shock. Mitochondrial CIII-deficient bone marrow-derived ST:STUDY_SUMMARY macrophages (BMDMs) produced IL-10 but exhibit dampened release following TLR3 ST:STUDY_SUMMARY or TLR4 stimulation in vitro. Surprisingly, restoring mitochondrial respiration ST:STUDY_SUMMARY without generating mtROS in mitochondrial CIII-deficient macrophages with Ciona ST:STUDY_SUMMARY intestinalis alternative oxidase (AOX) is not sufficient to reverse the ST:STUDY_SUMMARY increased vulnerability to LPS-induced endotoxic shock or rescue IL-10 release ST:STUDY_SUMMARY in vitro. However, activation of PKA, a mtROS-responsive pathway, was sufficient ST:STUDY_SUMMARY to rescue BMDM IL-10 release following lipopolysaccharide (LPS) stimulation. ST:STUDY_SUMMARY Additionally, mitochondrial CIII impairment in macrophages does not affect ST:STUDY_SUMMARY canonical responses to interleukin-4 (IL-4) stimulation. Thus, our results ST:STUDY_SUMMARY highlight the necessity of mitochondrial ROS but not respiration in the release ST:STUDY_SUMMARY of IL-10. ST:INSTITUTE Northwestern University, Feinberg School of Medicine ST:LAST_NAME Stoolman ST:FIRST_NAME Joshua ST:ADDRESS 303 E Superior Street ST:EMAIL joshua.stoolman@northwestern.edu ST:PHONE 7343559440 ST:NUM_GROUPS 15 ST:TOTAL_SUBJECTS 11 #SUBJECT SU:SUBJECT_TYPE Mammal SU:SUBJECT_SPECIES Mus musculus SU:TAXONOMY_ID 10090 #SUBJECT_SAMPLE_FACTORS: SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Raw file names and additional sample data SUBJECT_SAMPLE_FACTORS QHL1325 Cha-Jos-20231019-01 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-01 SUBJECT_SAMPLE_FACTORS LAQ1052 Cha-Jos-20231019-02 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-02 SUBJECT_SAMPLE_FACTORS LAQ1059 Cha-Jos-20231019-03 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-03 SUBJECT_SAMPLE_FACTORS LAQ1060 Cha-Jos-20231019-04 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-04 SUBJECT_SAMPLE_FACTORS LAQ1073 Cha-Jos-20231019-05 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-05 SUBJECT_SAMPLE_FACTORS LAQ1074 Cha-Jos-20231019-06 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-06 SUBJECT_SAMPLE_FACTORS QHL1325 Cha-Jos-20231019-07 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-07 SUBJECT_SAMPLE_FACTORS LAQ1052 Cha-Jos-20231019-08 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-08 SUBJECT_SAMPLE_FACTORS LAQ1059 Cha-Jos-20231019-09 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-09 SUBJECT_SAMPLE_FACTORS LAQ1060 Cha-Jos-20231019-10 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-10 SUBJECT_SAMPLE_FACTORS LAQ1073 Cha-Jos-20231019-11 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-11 SUBJECT_SAMPLE_FACTORS LAQ1074 Cha-Jos-20231019-12 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-12 SUBJECT_SAMPLE_FACTORS QHL1325 Cha-Jos-20231019-13 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-13 SUBJECT_SAMPLE_FACTORS LAQ1052 Cha-Jos-20231019-14 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-14 SUBJECT_SAMPLE_FACTORS LAQ1059 Cha-Jos-20231019-15 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-15 SUBJECT_SAMPLE_FACTORS LAQ1060 Cha-Jos-20231019-16 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-16 SUBJECT_SAMPLE_FACTORS LAQ1073 Cha-Jos-20231019-17 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-17 SUBJECT_SAMPLE_FACTORS LAQ1074 Cha-Jos-20231019-18 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-18 SUBJECT_SAMPLE_FACTORS QHL1325 Cha-Jos-20231019-19 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-19 SUBJECT_SAMPLE_FACTORS LAQ1052 Cha-Jos-20231019-20 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-20 SUBJECT_SAMPLE_FACTORS LAQ1059 Cha-Jos-20231019-21 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-21 SUBJECT_SAMPLE_FACTORS LAQ1060 Cha-Jos-20231019-22 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-22 SUBJECT_SAMPLE_FACTORS LAQ1073 Cha-Jos-20231019-23 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-23 SUBJECT_SAMPLE_FACTORS LAQ1074 Cha-Jos-20231019-24 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-24 SUBJECT_SAMPLE_FACTORS QHL1325 Cha-Jos-20231019-25 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-25 SUBJECT_SAMPLE_FACTORS LAQ1052 Cha-Jos-20231019-26 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-26 SUBJECT_SAMPLE_FACTORS LAQ1059 Cha-Jos-20231019-27 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-27 SUBJECT_SAMPLE_FACTORS LAQ1060 Cha-Jos-20231019-28 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-28 SUBJECT_SAMPLE_FACTORS LAQ1073 Cha-Jos-20231019-29 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-29 SUBJECT_SAMPLE_FACTORS LAQ1074 Cha-Jos-20231019-30 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-30 SUBJECT_SAMPLE_FACTORS LAQ1067 Cha-Jos-20231019-31 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-31 SUBJECT_SAMPLE_FACTORS LAQ1069 Cha-Jos-20231019-32 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-32 SUBJECT_SAMPLE_FACTORS LAQ1072 Cha-Jos-20231019-33 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-33 SUBJECT_SAMPLE_FACTORS LAQ1068 Cha-Jos-20231019-34 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-34 SUBJECT_SAMPLE_FACTORS LAQ1071 Cha-Jos-20231019-35 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-35 SUBJECT_SAMPLE_FACTORS LAQ1067 Cha-Jos-20231019-36 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-36 SUBJECT_SAMPLE_FACTORS LAQ1069 Cha-Jos-20231019-37 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-37 SUBJECT_SAMPLE_FACTORS LAQ1072 Cha-Jos-20231019-38 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-38 SUBJECT_SAMPLE_FACTORS LAQ1068 Cha-Jos-20231019-39 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-39 SUBJECT_SAMPLE_FACTORS LAQ1071 Cha-Jos-20231019-40 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-40 SUBJECT_SAMPLE_FACTORS LAQ1067 Cha-Jos-20231019-41 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-41 SUBJECT_SAMPLE_FACTORS LAQ1069 Cha-Jos-20231019-42 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-42 SUBJECT_SAMPLE_FACTORS LAQ1072 Cha-Jos-20231019-43 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-43 SUBJECT_SAMPLE_FACTORS LAQ1068 Cha-Jos-20231019-44 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-44 SUBJECT_SAMPLE_FACTORS LAQ1071 Cha-Jos-20231019-45 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-45 SUBJECT_SAMPLE_FACTORS LAQ1067 Cha-Jos-20231019-46 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-46 SUBJECT_SAMPLE_FACTORS LAQ1069 Cha-Jos-20231019-47 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-47 SUBJECT_SAMPLE_FACTORS LAQ1072 Cha-Jos-20231019-48 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-48 SUBJECT_SAMPLE_FACTORS LAQ1068 Cha-Jos-20231019-49 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-49 SUBJECT_SAMPLE_FACTORS LAQ1071 Cha-Jos-20231019-50 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle RAW_FILE_NAME(file name)=Cha-Jos-20231019-50 SUBJECT_SAMPLE_FACTORS LAQ1067 Cha-Jos-20231019-51 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-51 SUBJECT_SAMPLE_FACTORS LAQ1069 Cha-Jos-20231019-52 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-52 SUBJECT_SAMPLE_FACTORS LAQ1072 Cha-Jos-20231019-53 Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-53 SUBJECT_SAMPLE_FACTORS LAQ1068 Cha-Jos-20231019-54 Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-54 SUBJECT_SAMPLE_FACTORS LAQ1071 Cha-Jos-20231019-55 Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS RAW_FILE_NAME(file name)=Cha-Jos-20231019-55 #COLLECTION CO:COLLECTION_SUMMARY After treatment, cells were washed two times with ice-cold saline and scraped CO:COLLECTION_SUMMARY into 1mL ice-cold methanol (80% methanol/20% H2O) and stored at -80C overnight. CO:COLLECTION_SUMMARY Samples were lysed by 3x cycles of freeze thaw in liquid N2 followed by 37C CO:COLLECTION_SUMMARY water bath. Samples were then spun at 16,000xg for 15min. Supernatant was CO:COLLECTION_SUMMARY collected and analyzed as below. CO:SAMPLE_TYPE Bone derived Macrophages (BMDMs) #TREATMENT TR:TREATMENT_SUMMARY Glucose-free RPMI (Fisher) supplemented with 10% FBS and 11mM D-Glucose TR:TREATMENT_SUMMARY (U-¹³C₆) (Cambridge Isotope Laboratories). BMDMs were plated 2e6 cells per TR:TREATMENT_SUMMARY well in 12-well plates and washed with blank Glucose-free RPMI twice prior to TR:TREATMENT_SUMMARY treatment plating in Glucose-free RPMI (Fisher) supplemented with 10% FBS and TR:TREATMENT_SUMMARY 11mM D-Glucose (U-¹³C₆) (Cambridge Isotope Laboratories). heavy-labeled and TR:TREATMENT_SUMMARY treatment with either Lipopolysaccharide (LPS) (100ng/mL, Sigma) or vehicle TR:TREATMENT_SUMMARY control for 0, 1 or 2 hours. After treatment, cells were washed two times with TR:TREATMENT_SUMMARY ice-cold saline and scraped into 1mL ice-cold methanol (80% methanol/20% H2O) TR:TREATMENT_SUMMARY and stored at -80C overnight. Samples were lysed by 3x cycles of freeze thaw in TR:TREATMENT_SUMMARY liquid N2 followed by 37C water bath. Samples were then spun at 16,000xg for TR:TREATMENT_SUMMARY 15min. Supernatant was collected and analyzed as below. #SAMPLEPREP SP:SAMPLEPREP_SUMMARY BMDMs were plated 2e6 cells per well in 12-well plates and washed with blank SP:SAMPLEPREP_SUMMARY Glucose-free RPMI twice prior to plating in Glucose-free RPMI (Fisher) SP:SAMPLEPREP_SUMMARY supplemented with 10% FBS and 11mM D-Glucose (U-¹³C₆) and subsequent SP:SAMPLEPREP_SUMMARY treatment with Lipopolysaccharide LPS (100ng/mL, Sigma) or vehicle control for SP:SAMPLEPREP_SUMMARY times indicated in text. After treatment, cells were washed two times with SP:SAMPLEPREP_SUMMARY ice-cold saline and scraped into 1mL ice-cold methanol (80% methanol/20% H2O) SP:SAMPLEPREP_SUMMARY and stored at -80C overnight. Samples were lysed by 3x cycles of freeze-thaw in SP:SAMPLEPREP_SUMMARY liquid N2 followed by a 37C water bath. Samples were then spun at 16,000xg for SP:SAMPLEPREP_SUMMARY 15min and supernatants were collected for analysis. #CHROMATOGRAPHY CH:CHROMATOGRAPHY_SUMMARY 15μl aliquot of the sample was used for high-resolution HPLC-tandem mass CH:CHROMATOGRAPHY_SUMMARY spectrometry. High-resolution HPLC-tandem mass spectrometry was performed on a CH:CHROMATOGRAPHY_SUMMARY Q-Exactive (ThermoFisher Scientific) in line with an electrospray source and an CH:CHROMATOGRAPHY_SUMMARY UltiMate 3000 (ThermoFisher Scientific) series HPLC consisting of a binary pump, CH:CHROMATOGRAPHY_SUMMARY degasser and autosampler outfitted with a XBridge Amide column (Waters; 4.6 mm CH:CHROMATOGRAPHY_SUMMARY × 100 mm dimension and a 3.5 μm particle size). Mobile phase A contained water CH:CHROMATOGRAPHY_SUMMARY and acetonitrile (95/5, v/v), 10 mM ammonium hydroxide and 10 mM ammonium CH:CHROMATOGRAPHY_SUMMARY acetate (pH 9.0). Mobile phase B was 100% acetonitrile. The gradient was set to CH:CHROMATOGRAPHY_SUMMARY 0 min, 15% A; 2.5 min, 30% A; 7 min, 43% A; 16 min, 62% A; 16.1–18 min, 75% A; CH:CHROMATOGRAPHY_SUMMARY 18–25 min, 15% A, with a flow rate of 400 μl min–1. The capillary of the CH:CHROMATOGRAPHY_SUMMARY electrospray ionization source was set to 275 °C, with sheath gas at 45 CH:CHROMATOGRAPHY_SUMMARY arbitrary units, auxiliary gas at 5 arbitrary units and the spray voltage at 4.0 CH:CHROMATOGRAPHY_SUMMARY kV. A mass/charge ratio scan ranging from 70 to 850 was used in CH:CHROMATOGRAPHY_SUMMARY positive/negative polarity switching mode. MS1 data were collected at a CH:CHROMATOGRAPHY_SUMMARY resolution The automatic gain control (AGC) target was set at 1 × 106, with a CH:CHROMATOGRAPHY_SUMMARY maximum injection time of 200 ms. The top five precursor ions were fragmented CH:CHROMATOGRAPHY_SUMMARY using the higher-energy collisional dissociation cell with normalized collision CH:CHROMATOGRAPHY_SUMMARY energy of 30% in MS2 at a resolution of 17,500. Data were acquired with Xcalibur CH:CHROMATOGRAPHY_SUMMARY software (v.4.1; ThermoFisher Scientific). CH:CHROMATOGRAPHY_TYPE HILIC CH:INSTRUMENT_NAME Thermo Dionex Ultimate 3000 CH:COLUMN_NAME Waters XBridge Amide (100 x 4.6mm,3.5um) CH:SOLVENT_A 95% water/5% acetonitrile; 10 mM ammonium hydroxide; 10 mM ammonium acetate (pH CH:SOLVENT_A 9.0) CH:SOLVENT_B 100% acetonitrile CH:FLOW_GRADIENT 0 min, 15% A; 2.5 min, 30% A; 7 min, 43% A; 16 min, 62% A; 16.1–18 min, 75% A; CH:FLOW_GRADIENT 18–25 min, 15% A CH:FLOW_RATE 400 uL/min CH:COLUMN_TEMPERATURE 25 CH:INJECTION_TEMPERATURE 275 #ANALYSIS AN:ANALYSIS_TYPE MS #MS MS:INSTRUMENT_NAME Thermo Q Exactive Plus Orbitrap MS:INSTRUMENT_TYPE Orbitrap MS:MS_TYPE ESI MS:ION_MODE UNSPECIFIED MS:MS_COMMENTS A 15μl aliquot of the sample was used for high-resolution HPLC-tandem mass MS:MS_COMMENTS spectrometry. High-resolution HPLC-tandem mass spectrometry was performed on a MS:MS_COMMENTS Q-Exactive (ThermoFisher Scientific) in line with an electrospray source and an MS:MS_COMMENTS UltiMate 3000 (ThermoFisher Scientific) series HPLC consisting of a binary pump, MS:MS_COMMENTS degasser and autosampler outfitted with a Xbridge Amide column (Waters; 3 mm × MS:MS_COMMENTS 100 mm dimension and a 3.5 μm particle size). Mobile phase A contained water MS:MS_COMMENTS and acetonitrile (95/5, v/v), 10 mM ammonium hydroxide and 10 mM ammonium MS:MS_COMMENTS acetate (pH 9.0). Mobile phase B was 100% acetonitrile. The gradient was set to MS:MS_COMMENTS 0 min, 15% A; 2.5 min, 30% A; 7 min, 43% A; 16 min, 62% A; 16.1–18 min, 75% A; MS:MS_COMMENTS 18–25 min, 15% A, with a flow rate of 400 μl min–1. The capillary of the MS:MS_COMMENTS electrospray ionization source was set to 275 °C, with sheath gas at 45 MS:MS_COMMENTS arbitrary units, auxiliary gas at 5 arbitrary units and the spray voltage at 4.0 MS:MS_COMMENTS kV. A mass/charge ratio scan ranging from 70 to 850 was used in MS:MS_COMMENTS positive/negative polarity switching mode. MS1 data were collected at a MS:MS_COMMENTS resolution The automatic gain control (AGC) target was set at 1 × 106, with a MS:MS_COMMENTS maximum injection time of 200 ms. The top five precursor ions were fragmented MS:MS_COMMENTS using the higher-energy collisional dissociation cell with normalized collision MS:MS_COMMENTS energy of 30% in MS2 at a resolution of 17,500. Data were acquired with Xcalibur MS:MS_COMMENTS software (v.4.1; ThermoFisher Scientific). #MS_METABOLITE_DATA MS_METABOLITE_DATA:UNITS Peak Area MS_METABOLITE_DATA_START Samples Cha-Jos-20231019-01 Cha-Jos-20231019-02 Cha-Jos-20231019-03 Cha-Jos-20231019-04 Cha-Jos-20231019-05 Cha-Jos-20231019-06 Cha-Jos-20231019-07 Cha-Jos-20231019-08 Cha-Jos-20231019-09 Cha-Jos-20231019-10 Cha-Jos-20231019-11 Cha-Jos-20231019-12 Cha-Jos-20231019-13 Cha-Jos-20231019-14 Cha-Jos-20231019-15 Cha-Jos-20231019-16 Cha-Jos-20231019-17 Cha-Jos-20231019-18 Cha-Jos-20231019-19 Cha-Jos-20231019-20 Cha-Jos-20231019-21 Cha-Jos-20231019-22 Cha-Jos-20231019-23 Cha-Jos-20231019-24 Cha-Jos-20231019-25 Cha-Jos-20231019-26 Cha-Jos-20231019-27 Cha-Jos-20231019-28 Cha-Jos-20231019-29 Cha-Jos-20231019-30 Cha-Jos-20231019-31 Cha-Jos-20231019-32 Cha-Jos-20231019-33 Cha-Jos-20231019-34 Cha-Jos-20231019-35 Cha-Jos-20231019-36 Cha-Jos-20231019-37 Cha-Jos-20231019-38 Cha-Jos-20231019-39 Cha-Jos-20231019-40 Cha-Jos-20231019-41 Cha-Jos-20231019-42 Cha-Jos-20231019-43 Cha-Jos-20231019-44 Cha-Jos-20231019-45 Cha-Jos-20231019-46 Cha-Jos-20231019-47 Cha-Jos-20231019-48 Cha-Jos-20231019-49 Cha-Jos-20231019-50 Cha-Jos-20231019-51 Cha-Jos-20231019-52 Cha-Jos-20231019-53 Cha-Jos-20231019-54 Cha-Jos-20231019-55 Factors Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:0h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:1h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:Vehicle Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:KO + AOX | Time:2h | Treatment:LPS Sample source:Bone marrow derived macrophages | Genotype:CTRL | Time:2h | Treatment:LPS 1,3-diphosphoglycerate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,3-diphosphoglycerate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 48199 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,3-diphosphoglycerate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,3-diphosphoglycerate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2,3-diphosphoglycerate 45209 16156 15570 0 13793 5687 0 0 8924 0 0 6575 0 6886 6845 0 8168 9050 0 12046 5454 0 0 7055 0 5877 5418 4495 9539 6345 12677 6111 6751 6122 19258 6120 6741 6193 6683 0 0 6609 0 5564 5586 0 0 0 0 10673 0 0 5786 0 5607 2,3-diphosphoglycerate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2,3-diphosphoglycerate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4780 0 0 0 0 0 0 0 2,3-diphosphoglycerate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2/3-phosphoglycerate 486236 399912 324102 390343 882251 126780 19518 105404 84608 63140 139946 44490 228108 320049 30197 172499 340771 168031 217253 353615 124655 87392 344729 152112 392053 1325254 275915 381743 455162 378447 540228 501751 595465 710322 363391 390180 0 44206 175048 200997 563815 762326 343347 647743 522809 301711 301620 272601 423819 389871 324276 801573 153021 678047 444513 2/3-phosphoglycerate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10179 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2/3-phosphoglycerate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8226 6034 0 0 0 0 0 0 0 0 8156 0 0 0 0 0 7807 0 0 0 0 0 0 0 0 0 0 2/3-phosphoglycerate_13C3 0 0 0 0 0 0 0 14100 110898 41970 101997 197143 194933 294781 656160 508328 946312 604415 258735 324819 284626 157286 482409 312177 598232 368063 1195491 1033158 1241092 1005631 0 0 0 0 0 226649 117695 49452 246971 95190 654507 1065631 1004584 1286809 481706 461416 599801 586111 659730 479516 787380 1324413 985088 1167434 702170 2-HG 1088256 548797 2269960 315679 650556 2055227 1233073 738754 1778403 344686 492011 2660149 1468190 746009 2489456 892000 739447 2151254 963450 396545 1434900 448613 463299 1190976 804554 873106 1745088 477853 705053 1929142 75329 1188086 1822175 570669 213181 276744 1721426 1946224 791023 318485 703721 2058135 2515744 1105337 483466 278543 1177067 2040153 537314 80974 199357 2005452 2477066 1329821 293442 2-HG_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2-HG_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2-HG_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2-HG_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2-HG_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3-phospho-serine 21381 0 0 18173 67009 0 0 0 116183 14024 9539 24369 61193 164966 73464 50147 298405 163125 0 28700 26334 29193 95741 91489 219833 186736 199479 285005 304434 244937 0 44496 20594 33357 0 179823 0 0 0 0 344572 358464 281886 424516 91209 148445 177676 18869 225469 88489 304836 236080 0 475543 90706 3-phospho-serine_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3-phospho-serine_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3-phospho-serine_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 16936 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6-phospho-D-gluconate 82450 43806 26521 49887 281722 103395 27411 0 34845 183461 625339 63312 324240 579827 9656 394178 1169187 94765 55029 173079 0 51502 524722 29322 269359 170646 9090 293704 560753 43767 45486 0 0 119391 0 129175 197944 151619 559564 238068 386850 563576 565576 952681 536320 362683 205348 155374 518896 194459 535795 233740 35831 445785 270147 6-phospho-D-gluconate_13C1 0 0 0 6644 0 0 0 0 0 0 55881 0 15175 0 0 44522 145308 0 0 0 5656 0 49814 0 0 0 0 9688 26009 0 0 0 0 0 0 0 0 0 0 0 0 11634 11585 59544 0 12625 0 0 0 0 67515 0 0 13850 9340 6-phospho-D-gluconate_13C2 0 0 0 0 0 0 0 0 0 0 12447 0 0 0 0 0 117188 2829 0 7109 0 0 15612 0 0 0 0 0 8011 0 0 0 0 0 0 0 0 0 0 0 0 0 18843 31273 0 0 0 0 0 0 9145 0 0 8401 0 6-phospho-D-gluconate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6-phospho-D-gluconate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7419 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7028 0 0 0 6534 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6-phospho-D-gluconate_13C5 13697 8796 25448 31017 31846 16975 6893 0 54535 0 60777 59346 9966 41144 85564 5925 315488 107535 0 17897 21024 0 125942 64609 60323 0 64273 65374 125311 80187 0 44299 87105 74327 9593 149783 248251 228745 408325 72624 112926 358948 255462 494528 168767 72367 253883 282156 350516 103131 124550 481261 30697 538316 89355 6-phospho-D-gluconate_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 39825 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 23273 0 0 0 0 4725 0 0 0 0 0 0 0 0 0 0 0 0 0 acetoacetate / succinic semialdehyde 5068074 4565697 4971756 3772117 4746163 9292559 8008299 8231152 6678785 9023351 4061268 3965790 8008098 3507244 4200503 8243575 4493779 4279879 15367817 9314623 10906449 13983200 12928787 9451748 9076523 13318653 9838940 10745744 9303005 9542606 3655479 3883239 3441171 3697110 2479079 5088093 4180246 5547348 3280433 4454780 5843723 2763289 6209975 2610757 2143418 4655654 3264626 6906926 4719644 2959778 2849397 2805760 9505003 2260822 3203998 acetoacetate / succinic semialdehyde_13C1 294405 258344 289991 243117 357946 513814 397782 443346 189454 389764 280527 338853 459621 333015 268091 510175 314491 271212 916106 547497 548148 685634 629049 556224 486633 756442 594262 653712 497130 568080 281497 232925 277662 283533 205622 277000 192881 360523 233299 324373 439209 188553 292025 193349 183184 344959 254273 433032 249732 197109 217334 150204 524895 108806 233350 acetoacetate / succinic semialdehyde_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4974 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2185 0 0 0 0 9306 0 0 0 0 0 0 0 7653 0 0 acetoacetate / succinic semialdehyde_13C3 519949 319233 342571 382301 444021 415349 514381 328598 273312 348713 429019 372487 468298 436478 327856 412942 441045 330065 462972 621163 411262 394415 508165 320765 431999 433513 372273 408250 400972 555520 296584 361077 248565 246268 270740 358503 574657 462797 538013 566832 545558 442857 640548 589740 1056910 378734 440764 599118 869797 924508 546186 686990 1197854 565529 724332 acetoacetate / succinic semialdehyde_13C4 81935 78055 129920 90915 67857 243530 231436 404219 415776 702447 376703 501878 776180 858874 822203 296245 826792 716912 1662822 1498742 1142734 1245389 1010816 1082048 944214 1196032 926349 1075315 971289 1074167 454759 386599 302356 267703 213964 237308 1398603 667488 1165910 1042799 782951 672441 962568 679811 792684 1107649 641030 868319 818923 835264 745332 613444 626450 544635 398124 acetyl-CoA + 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 acetyl-CoA_13C1 + 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 acetyl-CoA_13C2 + 0 0 0 0 0 0 88578 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 aconitic acid - 67197 82219 166939 142754 232846 81898 122480 124197 63676 134650 237601 0 63669 67249 197913 200274 64370 71026 777988 645047 696659 1171102 924857 1168768 1267332 1243322 1089369 1330652 1559824 935949 0 0 0 0 0 75452 93820 173582 158002 181703 53083 142639 428494 70251 150104 0 0 67943 0 0 0 60357 0 0 0 aconitic acid_13C1 - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 13269 0 0 12953 21833 19131 0 0 71278 22871 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 aconitic acid_13C2 - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 adenosine 426634 3304039 6958475 3370676 3690360 4678359 5375017 2303058 2484101 786873 4610019 2288189 3898103 2809193 2422534 1923354 2380155 3734214 1567352 1063983 2680241 891436 2688169 2791275 1075559 673105 5027884 1151954 1225084 1520118 2461785 2040261 1551845 1189152 2530057 1440701 131210476 72887323 87422219 57200007 6769614 32255619 18484592 26108672 13245419 14496253 37470057 24387992 53001756 12565159 12463296 5223729 51225134 24260442 8922599 adenosine_13C10 0 0 0 0 0 0 0 0 8666 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9180 0 0 0 0 0 6834 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8126 adenosine_13C5 0 0 0 0 0 0 0 0 0 8825 0 0 7586 0 5682 0 0 0 7848 0 0 6413 0 0 0 0 42851 9276 9485 26754 6753 9221 0 0 0 0 823934 324912 360606 109767 42990 451387 276528 268527 82140 144570 588575 264031 724228 12681 524822 124201 2024638 938564 259987 adenosine_13C6 0 0 0 0 0 0 0 0 8314 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 14146 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 15429 0 0 adenosine_13C7 562289545 384148159 735738684 976423958 668504599 0 412043306 612141971 1452013955 828564228 1040148513 974268124 0 584174403 420879398 1008409293 616491738 592260681 0 579168481 10452218 0 1952866487 1096453717 371156822 890953432 354615153 848772495 549728371 728399940 587790085 589504032 686487348 379720322 645433043 1248369808 0 701167163 500090369 596771044 1272794981 1828541961 872642356 870322224 481946619 0 1910703653 5186020860 585281542 487585723 1298338826 1712445035 1626026352 2521452813 1090602584 adenosine_13C8 0 0 0 0 6132 0 0 11226 0 0 0 0 0 7524 0 0 0 0 0 0 0 0 0 0 0 6869 0 5367 0 0 0 0 0 0 0 0 0 46065 12877 13882 0 66900 101393 0 0 15594 92114 0 137473 26702 48325 26859 119394 70590 0 adenosine_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 24575 0 14101 0 10264 0 0 0 0 0 0 0 13605 0 ADP / dGDP 9160730 23740135 48544660 39334521 39899029 38964021 16379898 17554422 39210882 23495425 38773055 62218475 16522969 32616155 28030550 20237628 35170139 61748771 23343645 25556148 55281816 26953602 60461462 56870283 35808726 16757250 31941806 39164503 45657077 47529716 16715259 27201784 35896940 27670782 22073089 16613741 52855557 98514403 73864278 59678668 44024702 98835541 114533906 129004182 72541317 73912609 127776464 113483673 136208591 73086014 55799381 75700557 35711764 116753892 64485783 ADP / dGDP_13C1 951862 2458975 5151038 4276193 4117678 4512415 1618693 1675192 4161337 2356767 4103530 6443174 1660728 3292735 3035782 2158622 3551013 6534516 2439626 2740646 5746901 2815034 6407474 6044954 3891292 1870060 3400777 4004511 4810078 4919668 1874185 3027093 3598074 3050894 2358697 1549327 5559654 10145786 7402235 6286418 4620839 10101406 11501755 13141147 7244873 7747144 13412735 11784274 13869747 7348375 6011756 7829507 3662519 11672464 6585298 ADP / dGDP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6020 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ADP / dGDP_13C2 0 99952 468674 569288 287908 502939 82810 180268 471260 132589 235648 783164 0 373566 293574 72676 322368 252109 334732 237444 563795 181830 283024 619976 777291 233447 468152 327085 322448 593223 96724 170688 328166 283022 184147 214268 720469 1592933 883557 1120045 1066634 2236066 2388249 2558047 1152368 1750491 1836817 2234090 2532103 1074581 1295275 1742683 700282 2419620 859940 ADP / dGDP_13C3 0 0 47094 0 0 31252 0 0 54513 0 19401 47700 16046 31379 0 0 0 151146 46132 0 161877 10944 123768 155520 187993 68113 180308 172358 135015 311819 0 0 0 0 0 0 83006 297783 121147 113234 245035 399678 590267 590238 189089 326555 544108 510140 487518 101882 588233 781414 322279 891383 323434 ADP / dGDP_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 19074 0 0 0 0 0 0 0 0 0 0 54532 0 81906 42369 15320 67950 0 0 0 0 0 0 0 33258 0 24842 162925 147958 161005 196933 97795 274043 254919 98313 222131 46530 407153 326085 111406 336639 180828 ADP / dGDP_13C5 0 0 0 0 0 0 0 0 134872 42415 0 86125 0 106018 67770 37527 0 387013 116861 59918 537831 206561 372431 383446 759638 227642 1221851 819412 905099 1402584 0 0 0 0 0 50397 236517 526602 457960 132101 955923 1597219 1703864 1917269 716110 1197528 2367949 1487270 1792957 477096 3171806 3796612 1742222 4362328 1390799 ADP / dGDP_13C6 138387 38186 64550 0 0 35600 13030 0 0 0 0 17180 29415 0 112129 0 63727 8669 0 0 0 0 0 0 0 0 23051 28644 18296 29807 0 0 0 0 7285 0 0 15020 0 0 0 97682 28117 20470 19475 38009 84409 74347 25606 54303 162177 120053 10492 168572 16299 ADP / dGDP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 14161 0 0 0 0 0 0 ADP / dGDP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ADP / dGDP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9262 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AICAR_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a-KG 0 0 0 84320 0 0 0 0 0 0 106536 0 297341 99737 196131 213696 95015 255750 941369 631113 1233982 733562 957026 1045042 1933296 2873583 2822345 1954056 2337906 2442186 103101 88546 0 0 0 94784 102059 129261 601909 231917 86829 652530 1260896 425482 0 97377 316087 326992 108480 0 0 704883 783152 671131 74244 a-KG_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 32219 32363 41902 0 170627 145971 147498 82699 270330 164394 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a-KG_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a-KG_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a-KG_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a-KG_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 alanine 8261277 2995093 11681421 8056704 5876390 6267289 9109245 5518282 5918738 5899262 7409200 5039639 12592258 4182322 6402794 5577562 6795824 6842390 45737665 24540791 45531482 35987777 52552707 68280176 59620611 274953653 61070815 69397619 50390840 34768441 4996416 9818697 3685034 6225723 6822233 38211103 17814738 42610565 37316760 29917042 32203213 41336968 60155606 25434528 23431916 20127016 23019389 28466024 33099383 15733856 15204218 120004142 29130561 51909265 8913685 alanine_13C1 211520 84319 0 265649 47180 100167 402361 0 0 0 308818 0 220197 63642 0 105903 0 90530 1671388 946204 1448103 1278393 1665041 2121965 2113032 7914219 1921797 2139508 1581138 1332295 0 0 0 0 0 1118848 512100 1266827 701851 1000255 812379 670999 1855602 880406 585860 474092 492301 1248660 737791 169394 171918 2649972 1410983 1719756 399761 alanine_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 14609 0 28987 62547 12965 16036 86813 77949 45463 12114 59280 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 alanine_13C3 0 0 0 0 0 0 0 0 0 150034 99604 111389 228279 0 0 0 0 0 1124203 617667 1342215 1386994 2210002 1504400 2536942 1218258 2283680 2492430 2857676 1902245 0 0 0 0 0 152579 201505 118010 0 0 371392 203581 1032985 258152 94422 405639 213335 650690 408370 106603 50080 197670 1073633 207270 0 AMP / dGMP 54759 0 292712 0 97845 462488 165341 0 724835 237889 104547 442163 212610 316473 45467 249799 179913 590426 454139 14352 797235 643144 1030966 1049406 499132 581538 383157 569554 647183 417932 0 15202 0 54991 0 0 2871000 3482646 1595987 1167051 1588525 4050712 3617251 3943270 1615969 1779317 4524233 5902683 5421964 1848076 1553212 1448798 7829445 5261587 1810493 AMP / dGMP_13C1 0 43166 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 58366 0 0 15266 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9055 13499 71433 149006 0 48869 102062 78132 36320 10178 17742 0 694204 36495 0 AMP / dGMP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 50984 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AMP / dGMP_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45913 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AMP / dGMP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 28730 0 0 0 0 0 0 0 44043 0 0 0 0 0 58600 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 39546 0 0 AMP / dGMP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 52035 0 0 75431 0 0 0 97526 47037 0 0 0 0 0 130944 0 AMP / dGMP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6266 0 0 0 0 0 0 0 0 0 0 0 0 0 0 AMP / dGMP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 48931 0 0 0 0 0 AMP / dGMP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 aspartate 54254234 45253031 32219987 41010265 57465286 37748441 50337924 38832787 24716732 31090924 43379171 31571955 56810504 33075690 32783988 36405330 46818455 30682195 41516115 36817677 25144760 34005378 41782105 35287754 30600034 52197394 29874446 35023138 37089352 35036820 23589780 20031464 20227880 23349774 18170087 60294227 35949086 29943551 48102582 33015896 25615391 37623563 29943853 39677284 38473797 27109802 38665721 47813586 39996008 34372279 30646787 51214869 40703822 47847400 26491430 aspartate_13C1 2099075 2215488 1296676 1521215 2132814 1384374 2642526 1927432 1152784 2792305 3935536 1452905 3105335 1734677 1319802 2647763 3545785 1457676 2008233 1776884 1202414 2659181 2935982 1618266 1954421 3022156 1335623 2266809 2838413 1532071 744504 668497 862146 863713 685524 2339808 1729584 1281425 2988224 1527320 1768620 1912851 1321117 2075326 1970985 2061713 1661102 1926568 2079745 1554199 2818619 2466477 1783306 2650977 1441845 aspartate_13C2 0 0 0 0 0 0 0 0 0 0 3153558 145306 2870525 1139304 166861 0 3245403 93060 3605069 605274 0 0 2676083 69768 1241821 0 0 1628246 2315576 0 0 0 0 0 0 353696 225515 322706 1187424 199883 1088744 206305 495701 1022673 642216 800250 285293 312157 936875 0 1828888 349824 0 986493 209968 aspartate_13C3 2099075 2215488 1296676 1521215 2132814 1384374 2642526 1927432 1152784 2792305 3935536 1452905 3105335 1734677 1319802 2647763 3545785 1457676 2008233 1776884 1202414 2659181 2935982 1618266 1954421 3022156 1335623 2266809 2838413 1532071 744504 668497 862146 863713 685524 2339808 1729584 1281425 2988224 1527320 1768620 1912851 1321117 2075326 1970985 2061713 1661102 1926568 2079745 1554199 2818619 2466477 1783306 2650977 1441845 aspartate_13C4 0 0 0 0 0 0 0 0 0 0 76075 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ATP / dGTP 265086477 221916478 260319121 269064057 364618576 308789404 110987181 96266732 188251077 114595688 283590878 264723906 121011148 170584195 303477491 115878323 324846909 257947037 128710676 165945931 240572817 117814596 375588189 250241750 208672236 97146927 252218677 225720079 331419409 234557672 203753076 296496852 313373041 315132787 209722640 150719496 282177000 243861271 305419960 182205839 141891539 169266235 157143530 186156584 127681934 121104514 195728510 160595816 179557802 163852029 159098657 185398440 78134457 210304002 114413381 ATP / dGTP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6208 0 0 0 0 0 0 0 0 0 0 4669 0 0 ATP / dGTP_13C5 0 0 0 0 0 0 274173 243341 963201 477548 1005576 1023132 1116948 1307310 3752829 871936 2351754 2750214 877812 1008291 2478211 1018598 2566545 2038711 4960316 1787385 9152334 5080907 7233839 7946032 0 0 0 0 0 1105729 2288129 1597903 2168267 666913 3265936 3065153 2484850 3096570 1297767 2154557 3804510 2172693 2684872 1264721 9078318 9317075 3832516 8215760 2619041 ATP / dGTP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 9767 127627 0 45531 79380 0 0 39874 0 9224 37787 226283 49251 531383 264522 376886 415574 0 0 2981 0 0 0 14127 30044 40871 0 80021 80678 35785 145061 34811 93179 187180 0 48431 0 559524 570124 208362 446559 95058 ATP / dGTP_13C7 0 0 0 0 0 0 0 0 0 0 0 17002 10825 204 31605 0 0 0 0 0 9154 0 0 0 10467 10921 162254 23038 18305 52853 0 0 0 0 6633 46875 0 0 0 0 12677 0 11147 0 0 15248 11423 12721 0 0 117113 99678 13280 72122 0 ATP / dGTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5633 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 11956 32240 10441 0 0 0 0 21596 11401 7841 0 0 0 0 ATP / dGTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 12336 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6535 0 0 0 0 0 0 0 0 0 0 0 12043 0 0 0 9111 0 0 choline+ 83332051 150721292 134911490 148281365 143909645 5103498 38167826 127345557 151368500 138434929 206649420 209781447 79160497 263541088 35024278 102581210 197667119 271330908 275535598 380923408 354975266 281251091 560110933 466239806 468866062 336686806 482727981 656411516 492881744 475244523 137997009 183080946 246640291 179612819 208975258 520814268 249554766 310847382 1630957199 251992942 139239720 118027703 274511668 133810734 82878279 122093621 130796878 150464342 153780368 154141900 164046958 128685768 156712073 129596978 117128024 choline_13C1+ 3745799 7528881 6519361 7207446 6991725 95128 1690237 6360225 7391884 6996236 10067771 10454138 3557510 12863158 1478036 4846982 9913104 14100568 14044279 19303919 18551012 14151980 29944145 24517020 23835235 17575195 25308534 32074859 25329694 25116128 7217654 8968244 12991999 9124016 10365306 26451193 12325147 15635730 12304987 12388193 6824127 5758797 14430461 6191209 4335265 6492275 5899666 6126101 7235033 6954296 7291874 5652794 7419276 5595048 5704151 choline_13C2+ 74984 655152 51939 69932 72633 NaN 11219 72479 59321 96963 193455 95748 53253 171728 39530 33391 108929 167107 253369 290277 305535 166419 385908 2569786 421746 216250 347809 305435 289206 370318 78329 95183 183565 103322 131683 452097 156714 266217 1504216 104667 11226 NaN 113643 NaN 20123 78922 NaN 25326 73959 118757 72655 NaN 70059 NaN NaN choline_13C3+ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 68286 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 choline_13C4+ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 choline_13C5+ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 citrate(iso)/citrate 210798814 164591243 56253470 143079347 275808573 69364714 77341105 71986662 209183193 84866867 208567644 123425902 134414608 204370984 100807860 76118457 270815171 122788783 104432324 141706692 75101396 75571285 366282839 101764381 234741146 108602745 100183099 158097061 281000739 83980913 96075068 144687388 134127865 218104653 107485283 176850637 216623227 167192044 291541198 180916785 282572602 337239114 269706671 517482523 280270158 159409721 234580589 201780806 370422879 210222231 200466060 397446585 71784379 475005389 157917017 citrate(iso)/citrate_13C1 12298895 9273097 3227326 8143674 16165429 3940756 5591614 5077947 12879669 8561462 23942073 9089530 10795807 16826345 7261373 8669693 30763036 9592933 7604565 10238210 5280803 7763649 42395086 7996057 21636964 8929314 7337634 17135724 32342425 6968354 5658343 8602453 7754535 13066610 6353078 12528537 16564044 12922615 28839282 12879318 27069919 29577548 23910408 52005002 23340154 14967882 19181414 15457024 33458505 15026424 23196084 32621769 6062509 46560864 12708380 citrate(iso)/citrate_13C2 0 0 0 0 0 0 4362726 4054524 2995452 15706246 50332332 9724768 23099771 29187087 8217553 25014190 96197902 16457868 8634019 10221782 3968348 14978132 93167711 9120175 30628143 10874578 6174655 38018977 78507133 8404460 309105 156062 85913 8125 0 6340517 16229743 15734231 46291306 8329916 38842503 50984831 43828675 100298557 29938613 15926554 21877079 15237496 43641980 10411273 34028130 34016189 7196147 69368395 11780360 citrate(iso)/citrate_13C3 0 0 0 0 0 0 181037 40222 178669 2656066 8611829 997529 2129350 2735954 1063865 3962527 15016054 2080717 872251 952963 603807 2374191 14858204 1255537 4432597 1358858 1263047 6874721 14200837 1441456 0 30266 0 0 0 641755 1853773 1611878 6510305 597243 5954392 6259767 5133030 13994206 3380252 2628770 3533834 2371695 6491747 1501913 8033515 6322747 1176258 11767533 1749041 citrate(iso)/citrate_13C4 8566 9435 0 0 0 0 10182 18143 6996 1753207 5263993 342259 1195038 1284829 271749 2888299 11398678 1186711 171902 242033 134824 1346791 8694012 542330 1994735 412550 259333 4451629 9058518 523574 18688 0 0 0 0 129598 674340 644299 3593805 87161 2929424 3186345 2531651 8201146 1375026 1195353 1599012 787714 2939602 264203 4011089 3070572 303120 6028036 480718 citrate(iso)/citrate_13C5 0 13735 0 11977 0 0 50725 64687 12519 388912 1158678 13319 216120 64070 16803 817504 2734601 50214 86160 20261 0 424365 1981821 70333 262151 180924 60023 1058746 2410576 89341 20401 26703 47855 36657 0 0 63032 62652 523277 5958 464742 355369 330278 1562673 101395 170216 247546 140665 491007 56196 1049258 623544 141870 1366660 80291 citrate(iso)/citrate_13C6 0 0 0 0 0 0 0 0 0 0 9694 0 0 0 0 0 0 0 7747 0 0 0 42702 0 5930 0 0 33135 67615 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10072 0 0 0 0 0 0 10340 0 0 9966 0 CMP 99593 96360 36660 130283 74324 0 0 90640 281245 52802 56905 493002 35128 417672 8321 0 18831 366958 478700 593781 724505 212223 647096 495709 893358 524051 696525 530551 443533 662978 0 47665 229158 47036 81145 299573 1350820 1895889 1530054 1411483 25687695 11078786 17048588 14606895 23899557 19255162 14322804 11252706 14269451 8803668 10318122 18212144 1358214 12073753 19392852 CMP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 11790 0 0 0 0 9769 0 9933 0 0 0 0 0 0 0 0 0 0 12828 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CMP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10101 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CMP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8053 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CMP_13C8 114793 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 11216 0 0 CMP_13C9 0 0 0 0 0 0 0 0 27679 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Crotonyl-CoA 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CTP 31420687 27293316 15242353 16965607 23704086 16136250 13747983 11048424 11452845 7065038 16180518 15071244 17886259 29706737 27492693 10016798 25458060 22075790 8388696 13837413 14209590 5436208 14001222 10917575 21934215 9642049 20016733 16696960 24145326 18519753 21997910 19077020 16440498 19373757 18390703 16815517 18302231 13847438 18717406 15731168 19840816 16640951 13340850 15944838 16135131 12467902 10605351 10266955 9506100 11471318 18138426 13506762 5555980 14050296 10418546 CTP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CTP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CTP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 cystathionine 492571 373528 482582 472838 609554 528659 196359 166261 339537 191780 383524 454835 216422 334172 520199 231841 833256 507126 210619 283835 516363 135063 477264 384849 416811 254201 485555 411572 531151 504651 141483 245658 159843 393747 76912 1143477 385136 342239 419234 344996 327371 634102 547523 748761 558011 308443 731649 468161 701463 436459 371409 1297487 292929 879698 435297 cystathionine_13C1 0 0 0 0 0 0 0 0 0 0 9883 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9179 0 0 0 0 0 0 cysteine 0 0 0 0 0 0 0 17235 64636 0 40754 12131 0 47860 0 0 100624 43153 458808 509603 546532 168475 637946 731781 426926 655575 487191 509595 363690 431992 0 0 0 0 0 1499604 541954 1627243 1512309 833261 5156586 2831557 10612426 4288132 3333015 4212891 5707019 5762189 7080144 4208073 3525523 3677044 4033077 6233460 2523480 cysteine_13C1 0 0 0 0 0 0 0 0 41262 0 0 0 9450 0 0 0 0 0 12873 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8032 0 0 14403 0 70629 0 0 0 0 0 0 0 cysteine_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 cysteine_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 32132 0 12212 0 0 0 0 19205 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP 15812 0 20543 0 17372 0 0 9011 14687 0 0 0 0 0 0 0 15820 13788 0 10637 12697 0 17319 0 0 0 32162 0 15954 32059 0 15362 21379 18766 0 13047 136347 131112 202458 112708 10022 13792 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6277 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP_13C5 0 0 0 0 9397 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8181 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6091 dATP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dATP_13C9 0 0 0 0 0 0 0 0 0 6942 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8698 0 0 0 0 10603 0 0 dCTP 1351052 946444 657469 624470 915842 727157 397976 308707 409950 297750 722640 686129 597323 674055 979600 323911 1042772 764052 435710 452435 545322 201184 795606 546923 926974 265086 710858 540771 993150 706989 632218 718880 971326 769728 670846 460318 734926 705351 642642 574099 596959 587737 579686 566573 539432 341346 470587 529758 429257 487632 580286 563868 215276 632160 433005 dCTP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7573 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 11076 0 9489 0 0 0 0 0 0 0 0 0 dCTP_13C6 0 0 6771 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 11620 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dCTP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dCTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8217 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dCTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 deoxyguanosine 2232532 1310249 2427783 2869443 5692550 1938763 6391563 4138780 5593678 3998332 8302911 7602647 13268074 9604198 7596843 5133435 9552002 5859646 2886560 3018179 2887603 1886125 2204285 6725343 2937615 2926228 7215480 6073931 5665804 7192248 17590821 11894443 6323847 14404425 9493232 6509999 17573505 16939516 29680791 20644306 4821826 19068331 8616844 20745098 24088759 10231314 18372586 14645966 20723516 20310943 20166621 16329421 16241253 30836028 18386880 deoxyguanosine_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6834 0 0 0 0 0 0 0 0 32378 0 0 0 0 0 30767 0 0 0 0 0 8126 deoxyguanosine_13C5 0 0 0 0 10265 0 0 0 0 7362 0 0 0 0 5682 11181 0 0 0 0 0 10781 4813 0 9002 5318 0 81089 26037 23321 17239 0 0 6557 0 0 0 0 0 0 0 0 0 0 39163 26749 14679 20681 11628 27346 10888 10659 399316 0 429750 deoxyguanosine_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38488 31019 4550 0 0 21053 5606 60488 41567 0 20029 64141 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10738 0 0 deoxyguanosine_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20624 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 deoxyguanosine_13C8 0 0 0 0 0 0 0 6717 0 0 0 0 0 7524 0 4957 0 0 8507 15997 0 5848 0 24648 0 0 0 24123 37516 0 0 0 0 0 0 20054 0 0 56222 69463 7010 83359 101431 296807 35896 90003 45837 273489 261108 335545 314817 181491 71272 2306340 97516 deoxyguanosine_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 14672 32220 0 0 270969 207620 82376 141987 229891 32616 105946 118567 282847 56102 216923 69492 D-galactosamine/glucosamine-1/6-phosphate 161739 255413 167301 174717 420703 84298 42599 22218 391022 0 64049 48590 17857 8713 18434 8229 29699 55435 8727 8508 0 0 29562 10212 51104 32082 28892 10088 48813 0 0 27420 20378 24331 22697 0 36174 22270 10252 0 44822 22745 12303 10720 8183 9687 22953 0 9267 19540 62850 40410 0 34582 4641 D-galactosamine/glucosamine-1/6-phosphate_13C6 0 0 0 0 0 10230 0 0 714 0 0 7639 0 6838 8759 0 25931 117822 0 0 0 0 0 0 0 0 22143 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 31504 16007 18623 0 D-ribose-1/5-phosphate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 53033 0 0 0 0 0 0 0 0 0 0 0 0 0 18854 0 16336 14081 0 0 0 0 0 0 26303 80192 42811 0 18174 D-ribose-1/5-phosphate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 D-ribose-1/5-phosphate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 D-ribose-1/5-phosphate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 63391 51300 0 0 0 0 0 0 0 0 0 0 0 D-ribose-1/5-phosphate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 D-ribose-1/5-phosphate_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 D-sedoheptulose-7-phosphate 191039 153506 229453 263640 357671 406335 26439 36689 173790 29016 247267 286834 52624 23284 331331 85951 259171 269130 10786 97985 220455 47438 277565 261367 156589 305263 366901 128814 291309 274050 226021 472527 684136 638860 127608 10371 380055 417125 420767 53339 24915 677298 512651 728833 197799 90282 478586 462318 448538 72246 50624 609441 351049 923157 167663 D-sedoheptulose-7-phosphate_13C1 0 0 0 0 14113 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9293 0 0 0 0 0 7396 0 0 14188 0 0 0 0 0 0 0 0 0 25634 0 0 0 0 0 0 0 0 10636 0 10867 0 D-sedoheptulose-7-phosphate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10072 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 12912 0 0 0 0 0 0 0 0 0 0 0 0 0 D-sedoheptulose-7-phosphate_13C3 0 0 0 0 0 0 0 0 0 0 9044 0 0 0 0 0 0 0 0 8670 0 0 0 0 0 0 64791 0 11482 6355 0 0 0 0 0 0 15550 11957 13352 0 0 13116 12425 0 9508 0 15027 9540 9119 0 0 50148 50528 13714 0 D-sedoheptulose-7-phosphate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9710 0 0 22021 0 8345 31730 0 0 0 0 0 0 10181 14212 0 0 0 12960 19030 0 0 0 16746 29485 9749 0 0 98561 21513 58316 0 D-sedoheptulose-7-phosphate_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9538 9422 0 0 0 11066 0 0 0 D-sedoheptulose-7-phosphate_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 22071 0 0 0 0 0 0 0 0 50130 0 0 66595 0 0 0 0 0 0 0 0 0 0 0 0 42709 15615 0 8221 8973 0 12693 0 0 63878 65343 22648 0 D-sedoheptulose-7-phosphate_13C7 0 0 0 0 0 0 0 0 54374 0 19823 63087 29068 103882 173175 54235 90395 342926 11908 0 150720 0 54174 158719 10199 14896 879315 229696 396524 686772 0 0 0 0 0 0 144255 191863 126222 0 17893 373968 518218 391853 0 7721 500846 315267 205866 0 36974 1204980 1153342 1088177 37299 dTTP 0 21599 24058 14284 29671 8444 10995 0 17450 10146 60263 20092 14461 0 9006 17391 71059 26881 0 9548 24633 10062 77098 23404 32654 0 25100 26129 31075 36613 28426 19288 11323 48271 8416 0 47931 11733 49705 7612 37121 14493 6905 37923 7442 7575 7990 0 8097 6499 23122 28036 0 32112 0 dTTP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8281 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9539 0 0 0 0 0 dTTP_13C5 13199 0 0 0 0 0 0 0 0 0 0 0 10117 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9712 0 0 0 0 0 7668 0 0 0 0 0 0 8378 0 0 0 dTTP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8399 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dTTP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5396 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5546 0 0 0 0 0 0 0 0 0 0 dTTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10317 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8168 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dTTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7112 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10056 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 7229 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dUTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 F-1,6/2,6-P 2073640 2299521 2162522 2320710 2984465 3190280 1124198 945026 1599089 943049 1347150 1469018 960105 1196350 1987757 1018744 1408633 1238643 502040 1024664 1126391 595373 1347020 1013674 1209757 554639 1208320 1308228 1720837 1292673 1839849 2269961 1875195 2696867 1972074 1410063 1636718 1978542 2431375 2011685 1325426 1840473 1324904 3004200 1481226 1066388 1394185 1534689 2175123 1734225 1108740 2454211 1075445 2540154 1559384 F-1,6/2,6-P_13C1 16306 6722 56028 16741 65729 12859 0 5198 13472 4612 12863 7297 0 5387 12215 0 23142 25354 0 6124 5444 9749 5062 0 11593 3483 21277 0 5829 4263 22361 31790 46625 75675 11220 4911 13133 24053 63325 36327 15954 17254 33955 42431 0 10669 35194 22337 22336 0 9438 31680 9891 52956 20056 F-1,6/2,6-P_13C2 0 0 0 15495 11988 6806 0 0 0 0 8235 766 11030 18724 44936 5769 21629 37600 4569 16710 17301 7779 39638 5093 29163 14487 54200 4284 53365 53300 19083 11118 30924 16932 12136 36094 5655 0 5076 4163 24730 21025 68379 57385 27895 37698 17577 0 5512 8720 40018 57593 9832 58920 25649 F-1,6/2,6-P_13C3 0 0 0 0 0 0 0 7670 63101 19305 69838 239015 46175 330212 1878230 426194 1875693 1310569 43312 221780 300278 70068 323318 48107 753856 351754 1034147 1099756 1509249 1936121 50340 0 4791 0 0 50016 73923 22713 55386 6976 295523 2022628 2295359 1817832 890929 579424 947851 1000823 860474 781804 1399832 2935067 1423965 3092814 1228032 F-1,6/2,6-P_13C4 0 0 0 0 0 0 0 5289 0 5638 0 5115 0 0 47947 0 9573 34364 0 0 0 0 6714 0 5111 5016 5454 5713 32065 32439 0 0 0 0 0 0 0 0 0 0 0 43319 96777 54362 0 5602 18209 12538 4812 0 7064 58576 37314 177305 4564 F-1,6/2,6-P_13C5 6993 0 0 0 0 0 0 3716 6244 11755 5750 38030 0 32777 492639 10375 422548 475700 0 18577 53985 10838 25283 27731 101206 8428 325513 241517 578754 786086 22278 5459 0 0 0 4176 4545 10262 17661 0 21097 594298 642375 829776 150012 91371 326687 277405 222105 95284 284064 1081857 681188 1093472 352254 F-1,6/2,6-P_13C6 0 0 0 0 0 0 0 5930 646041 222251 612460 1252294 778116 1633879 3617193 1572847 3566575 4034088 589693 805564 1189937 454269 1299966 575329 2204282 1507959 2625886 3209257 3541493 4761537 424270 39129 0 0 0 318056 591637 480404 1030050 53940 1307056 5979121 7407919 5116058 2191885 1776259 3319819 3338724 2280301 1823523 2678702 8935620 5767108 7785669 3970895 F6P/G1P/G6P 3610872 2606270 2875908 3583790 5440353 3207530 1287521 1255104 3830290 1886337 2632109 2788732 1572573 2351666 3122468 2238402 3333478 3282078 2092921 3324826 2420194 1490128 3296922 2740372 4095871 4732831 3679411 2994142 2944291 3198712 4778166 5079940 5484154 5427059 2962467 2303291 4801290 4877069 4809005 5109863 3289343 6435759 5492129 7092954 5025444 3981243 6751243 6234349 5814068 5881181 4502495 10416856 4231245 9846186 5943579 F6P/G1P/G6P_13C1 56156 10102 23091 56888 141720 9141 0 11885 154822 14360 54045 56776 9558 28539 23716 25195 79982 40357 0 106695 52368 38201 66595 70734 135192 143811 94267 64134 51035 102978 163458 70164 234090 192144 34952 15705 235720 183718 166262 221830 67221 251793 178731 326424 126800 190889 298229 282866 209700 161615 113059 498625 107100 431528 233197 F6P/G1P/G6P_13C2 0 0 0 0 8480 0 0 0 0 0 9281 0 0 0 0 0 0 0 0 0 0 0 6600 15360 0 0 8008 0 818 0 0 5509 7635 0 0 0 14828 21815 10529 17134 6763 7059 17713 13108 8322 65428 0 16350 10334 9901 27339 16150 11033 0 27953 F6P/G1P/G6P_13C3 0 0 0 0 0 0 0 0 29969 0 134276 42963 0 0 61071 0 37831 80278 11638 7614 33417 10528 95163 24863 26684 0 309307 25040 106459 196277 0 0 0 0 0 16332 245954 267560 290489 143821 11270 225610 444785 135494 13135 146628 122683 121461 56207 29762 30782 365852 428369 219000 13812 F6P/G1P/G6P_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5949 0 0 0 0 0 0 0 0 44842 18218 19088 0 0 0 0 0 0 9112 0 0 17475 0 0 12127 0 13765 0 F6P/G1P/G6P_13C5 0 0 0 0 0 0 0 0 0 0 14073 7678 10678 0 46893 24095 66764 86834 8572 0 0 12778 47119 49425 6938 0 214775 23502 47422 68780 0 0 0 0 0 19654 586180 404469 545674 314104 0 58766 222097 141903 11498 52888 88205 89645 65079 66080 45707 395770 268016 248918 17774 F6P/G1P/G6P_13C6 0 0 0 0 0 0 243243 212643 741923 495983 1290822 1027447 565505 740455 1938174 889709 2443909 2374225 321944 565076 959683 430227 1385453 1503460 919759 462388 4112574 1586039 2134474 2780528 0 0 0 0 0 396675 9919276 7056466 9994687 5376668 1358737 3381903 4595069 3702574 1302771 1160402 2809493 2616383 2586762 1410427 1835362 5470362 4484021 4799933 2040640 fructose / mannose 34984197 25448398 19923408 18588339 22239448 9259519 20093485 12901096 41356680 28192806 25210254 24543878 47176403 27697656 38591417 23819064 88254145 26565964 19019831 23835458 11026252 10864227 23629286 28971932 18677786 37422274 26551799 16764060 21481704 16422327 21521901 18590486 12922494 18450465 12196291 221940201 47970062 16727753 54415641 38460385 52261407 43322860 29101254 53789838 49525422 14441805 23991225 22354299 11352887 20651580 12091217 91043721 15124917 23361315 21527738 fumarate 849589 785889 1221137 644896 625062 1033993 842189 588115 820925 658347 501827 829587 1224937 511839 1543427 922483 840978 1236805 3634751 1750914 1821016 1719831 3774032 2306946 4250784 4197165 3375488 2478724 4592770 3002208 220371 682148 1023563 696127 317904 234783 1159735 1455442 1131010 537284 323452 1346402 2078391 1476828 941100 446778 1620103 2338542 1562003 1265891 714427 1868966 3424864 2610185 1474514 fumarate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43199 0 0 107800 48419 0 26891 154348 0 242768 158623 39669 135779 231532 0 0 0 60002 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 128671 0 59619 0 fumarate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 fumarate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 24774 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 fumarate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 galactose / glucose 158624204 189450879 149878341 222751472 188239667 45477250 14467985 57584030 44281421 27820197 64345781 32060916 65918187 32318601 29939638 33680182 59087227 31602547 22992324 25605989 16179698 10587450 20036015 21574551 19996042 811321090 38056584 19107270 16872110 22319207 147244360 83664883 36728433 110346252 52981322 1337422544 78861113 37166978 74739494 116381863 80041849 280216782 48864092 186868684 190976396 20806464 40672362 37012089 29362632 45370037 20608129 1092988176 37247213 275371175 27840545 glucose_13C6 0 0 0 0 0 0 92655276 75706557 166945073 100985155 123970212 135122830 326787372 191825538 281252527 217821104 889415490 125053151 197076563 244923221 116416064 91718080 190765509 158401682 170043784 179062684 247719074 148310812 165678847 117925254 4310682 0 0 0 0 2507530605 370309020 131080079 387395466 280860273 506136362 346773792 295362854 355152563 711447889 123958675 211958091 176437478 90437004 249894950 100070399 154274836 135771765 111171395 132626637 GAP / DHAP 0 0 0 0 73699 0 0 0 0 0 0 0 15010 0 0 72539 0 0 0 5388 9937 7062 10008 22587 24575 0 13593 24751 0 13394 6397 15201 35013 0 0 0 0 72483 0 14270 29755 0 13903 26018 3121 18206 12972 79786 30885 0 24554 60339 69589 2481 23512 GAP / DHAP_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GAP / DHAP_13C2 0 0 0 18033 0 0 0 0 11101 0 0 0 13152 79266 16470 0 35252 0 10030 0 0 0 12089 0 21297 0 0 0 12684 0 0 14255 0 15182 0 0 0 0 13272 12931 44703 49227 78850 160217 125026 64960 12725 23159 144384 49754 79541 37209 0 128895 70268 GAP / DHAP_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 166765 0 11287 80101 0 0 0 0 0 0 93498 175870 103534 0 0 68049 171349 159435 0 0 0 56583 0 0 0 648769 932189 553486 0 glutamate 143591118 96683793 131569505 111323970 140080681 132833229 125190077 76432931 88652580 87185176 97802632 99017658 148891164 83153763 147828640 125124664 127433878 118116132 159480238 99555061 112858014 116558208 123898964 113123111 138157925 179587789 158781049 132877099 158495181 149376410 68742529 88182454 91920690 85416115 59060609 91959285 114813923 113041201 114492504 83261833 91902695 169947390 145226410 152754765 128936614 90630598 150481266 191283573 143478519 118791307 138035135 242416028 227394995 243094172 113485869 glutamate_13C1 7551683 4653368 6882790 5181918 7039178 7029090 8219454 4725063 4964299 9004946 9759229 5921432 11157499 6418176 8459033 11175267 11761860 7217884 10620733 6399092 6774337 10083737 11094008 6701834 10429112 14115012 9243561 11834628 15001316 9143052 3482067 4177905 4683723 4246076 2931680 6249879 7223665 6671644 9302791 5124810 7873861 11007958 8960005 11531160 9005719 7692907 9473922 11183601 9923397 7351395 13490926 14980246 14778827 17899536 8055921 glutamate_13C2 0 0 0 0 0 0 7492403 7549433 2462745 19469908 15424227 3546803 20042948 7946089 5504563 33602963 22052917 5168366 15120137 4707539 2026053 16296344 15594407 2769637 10153035 14422046 3776034 17531217 22706375 4253453 0 0 0 0 0 2304491 4847717 4329395 9586511 2261822 9078204 9250766 7315917 13959194 8066175 5178100 5221381 5440824 7846435 3731850 14700611 8565215 13164221 15250160 5453268 glutamate_13C3 0 0 0 0 0 0 346630 1195380 82402 2286385 2524931 85705 1533660 312645 247780 3997431 3343458 394218 1037721 110447 56823 2198107 2183526 80878 1193413 1662059 287811 2752554 3548913 231122 0 0 0 0 0 539344 0 396269 1183961 0 1058656 363713 516891 1693094 447505 581897 295450 468950 670574 82348 2758231 1163582 1341162 1967081 338603 glutamate_13C4 0 0 0 0 0 0 0 0 0 1077460 1252603 0 445912 95294 0 1823579 1652394 0 71667 0 0 804320 1151676 0 339907 353214 0 1434077 2184227 0 0 0 0 0 0 0 0 0 428463 0 258605 86486 137605 870769 0 0 68560 149904 66595 0 1287231 428805 220753 1314122 0 glutamate_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 364503 0 0 0 0 0 0 289544 0 0 352440 0 619772 732887 246578 445461 409749 0 0 486266 0 0 0 558825 0 glutamine 24997859 20824076 18444646 19214997 21043816 18939426 19622811 17916979 17880717 16110206 23985243 17415544 33501985 20818106 27763113 24404900 44327566 22167331 35422625 24281030 21163564 21603824 35009139 25022953 25916225 77674484 31006376 27862053 37767740 26576306 10535716 13361568 13760198 15775282 10599607 108432787 28273045 27789018 37445368 25652594 31007376 31749067 36061220 37555432 33627951 14849479 26197367 26389199 24862662 19381893 17985657 60628791 25701067 31562787 15482871 glutamine_13C1 673954 601451 475045 594945 407631 422648 899150 548139 583141 375637 800816 381227 1013987 495667 1072566 831488 2267670 739368 1322500 258782 792542 675784 1554626 814360 866143 3703044 1058223 1047688 1312007 909278 0 383038 267857 405521 0 5280770 693311 1143213 1538675 1013572 1626604 817761 1306866 1732302 1178904 116336 626290 1227150 1050639 384035 577565 3097463 1089815 915606 149006 glutamine_13C2 0 0 0 0 0 0 0 0 0 93406 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 91990 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 71202 0 0 0 0 0 0 0 glutamine_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 81147 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutamine_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutamine_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutathione 4509338 3625560 6163220 4356758 5748760 5335702 3629707 2232293 691987 2242230 4649904 3024978 1860369 1920764 4068001 1819469 1850133 3901744 5301240 3894235 5908115 5741798 9579018 7264336 5307676 1372371 8278163 5429252 9809732 7589306 1513434 4569828 4200542 4194850 1770437 0 7277302 8241086 8217110 4304874 4799651 11083531 13544165 10794298 6663154 4998213 11523469 13240562 10988712 6854793 5598858 8085184 11002945 11557741 5714488 glutathione_13C1 298741 118256 347420 0 0 112844 0 0 0 0 0 0 0 0 0 0 0 0 179791 0 419182 466347 1110083 223188 126103 0 591135 218295 822470 168990 0 140323 360677 149767 0 0 290297 676032 415907 150483 274316 740224 1311398 891244 135804 229585 584637 1396141 593190 256032 90403 386209 619302 1053156 363634 glutathione_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 233338 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutathione_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutathione_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutathione_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glutathione disulfide 35341327 34287813 28403426 39760732 47666989 50139674 13006859 13206382 55362570 25375387 40318060 58763593 30875000 34958677 71209031 34729978 85162205 56436988 25386970 25302610 40534927 17095562 49129875 39400818 30668067 22366587 42681881 49561149 46031078 42124958 26748157 40036651 44295583 47965307 30931373 14035010 31019709 12894189 18342438 20541105 4188313 9523858 6537518 9126016 3993217 2292858 6398438 6356168 8701975 4302884 2693845 18463537 6736515 11311473 4330714 glutathione disulfide_13C1 8125852 7841860 6639942 9218173 11077021 11672630 3036943 3116976 12535883 5935371 9394248 13708331 7280569 8360051 17030772 8180482 20542390 13353919 6128786 6017987 9395999 4149991 12202544 8985211 7388460 5295212 10255165 12286727 11340350 10007284 6128005 9266237 10218227 10849133 6989692 3395697 7088519 2955793 4243439 4839878 1028516 2145044 1657623 2184307 977694 540730 1534092 1517681 2147690 977043 609815 4385747 1620393 2864135 1075875 glutathione disulfide_13C2 0 0 0 0 0 0 0 0 0 8048 0 0 0 0 0 0 0 0 0 9482 0 5800 9788 0 0 36410 10207 2432154 194602 11527 0 0 0 0 0 0 0 0 0 12836 0 0 0 0 0 26389 0 10268 0 45518 78219 0 20953 148097 0 glutathione disulfide_13C3 14704 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 87201 0 0 0 0 0 264306 225003 0 0 0 0 0 0 0 0 0 0 0 0 7386 0 0 0 10199 6545 0 0 22589 15604 8457 0 35223 9496 glutathione disulfide_13C4 0 0 0 0 0 0 0 0 0 22175 0 0 0 0 0 0 0 0 0 16073 0 6579 0 0 0 0 0 6540 111937 0 0 0 0 0 0 0 8528 0 0 0 0 0 0 0 0 0 6677 0 0 0 0 0 0 13758 0 glutathione disulfide_13C5 0 0 0 0 0 0 0 0 0 0 9540 0 0 0 0 0 0 0 0 0 0 7852 7173 0 0 0 0 21366 46027 0 0 0 0 7755 0 0 0 9869 0 0 0 0 0 0 0 0 0 0 12166 0 0 0 0 0 0 glycerate 68099603 46501607 32357219 25395316 21788265 9053916 12538868 14282644 17349696 13855601 14947636 13757576 13052030 14379332 13455813 11273226 13388557 12436802 9499267 10984385 6125263 7810971 7002762 11250149 9684235 11501524 9608999 11017327 9077721 11041865 12309637 10508272 11756232 10577180 11981890 25745083 13171722 10567105 14698920 13461369 23990103 20778838 17047753 18607799 17848482 14544712 16329525 17277018 15737713 14422596 14228502 14297465 12510841 13697323 12882481 glycerate_13C1 1925369 1132646 721067 431742 423960 34447 154310 95725 128556 71716 60763 110265 88102 24253 59619 21164 29470 21893 91970 35583 27922 0 22783 141300 94074 113154 60909 120158 88441 103576 81700 28680 18872 43400 60562 376046 92362 12606 177926 65951 414516 150691 156988 117982 46762 118860 155708 134146 113737 109273 31702 83984 135735 88080 105743 glycerate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 glycerate_13C3 53545 39150 37132 12897 44782 42537 47635 124622 222152 336002 419748 489092 537264 507788 626888 662651 600898 862650 357383 669383 382035 728782 535502 628011 734204 538962 857506 774211 644708 913093 944280 577901 331038 473849 282183 572967 1839775 986726 1211462 1347531 1084725 1591589 969219 1803294 2060393 1243647 2221472 1502664 1921340 1458709 1928719 825531 3213083 1530514 1368325 glycerol-2/3-phosphate 914867 250565 15411026 631222 1626883 14276863 506649 258612 8216052 775637 769571 6341746 1117634 407818 12354322 1188840 1270091 9856705 634552 541933 6449836 688162 1195845 6286626 634017 653256 9324357 817833 1229720 9406607 1024792 6543948 10023707 2143968 418501 648710 7130981 7849810 2579537 970670 689411 7567257 11449988 2578880 368854 1285600 6216788 11378691 2496538 1054576 1899542 6630147 13896363 3175332 538226 glycerol-2/3-phosphate_13C2 0 0 0 0 0 0 0 0 45256 0 0 0 0 0 140363 0 0 70141 0 0 0 0 0 0 0 0 140791 0 0 86057 0 0 0 0 0 0 0 0 0 0 0 0 146244 0 0 0 0 0 0 0 0 74042 648704 0 0 glycerol-2/3-phosphate_13C3 0 0 0 0 0 0 0 0 7020922 209600 225323 5641021 130586 0 15158017 628051 801284 12150879 232188 68834 6910110 640639 705501 6458253 241923 0 15277060 927511 1260766 13117532 0 0 0 0 0 0 5498039 7759836 1266585 0 54653 9263528 14060371 2463288 0 705190 8300575 12891569 2543134 462148 1654062 11658998 23510376 4022020 395173 glycine 8377145 7052173 6631986 7490828 8363448 8129291 8789142 6039366 7265854 6746543 8251640 6760062 7622723 6725034 9529156 9691026 14058413 6639180 12762552 7212200 8413178 9200769 17215597 13140253 8877090 11994144 9801740 14545317 13295208 8417412 7194942 8020147 6796967 7217635 5264718 16200277 13300628 10246779 13592618 9683838 12877089 14776221 13701605 15384422 11940622 7805575 12428890 11392018 15522776 8098911 8799128 20008441 9070674 17912146 7916320 glycine_13C1 0 0 0 0 35749 0 0 0 0 33712 0 0 39457 0 0 0 0 0 36935 0 0 52933 46127 0 0 43813 0 0 42289 0 0 0 0 0 0 0 0 0 0 0 0 97576 0 59290 0 0 38508 0 0 0 58686 46313 32655 103599 37228 glycine_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GMP 866616 763881 2431589 732693 842302 1835006 519147 682315 2067404 801937 841190 3364710 413655 1157963 914017 646417 1374629 2090531 773540 852288 2622491 1247504 1352426 2753155 1758483 289246 1365487 1804441 728547 2105867 623674 824514 1069477 918732 811450 666909 6829778 9910440 6282699 3842612 4007347 10042937 10451097 11219177 4326876 5365749 11263754 7645894 12694138 3121967 3605691 3257078 9095927 8550517 3119362 GMP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 14052 0 0 GMP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 33590 10305 0 11033 0 0 0 0 0 0 31782 121961 92942 0 13197 231771 269289 277380 0 42157 289061 95739 258825 0 185848 117845 843155 656998 10591 GMP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 13069 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GMP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 91206 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GMP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 12634 0 0 0 0 GMP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GTP 49631439 37395629 48509781 45671582 64391250 59794763 19048000 14768180 31716184 17043770 45150541 46162764 23014836 39122669 64592691 21900763 59592998 62389935 14688458 24470742 38583145 16158344 48309916 39399118 41879368 14638884 49519796 36467828 59221470 48705095 35169804 44684791 46961047 42477943 31571647 17300912 47754691 41401616 48701773 29443348 26573119 32462607 28626933 32335316 22347971 15888738 28162582 26657324 24995970 23761095 27653351 27789839 16608050 31703954 18784460 GTP_13C10 0 0 15012 0 0 0 5764 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7921 0 0 0 0 9467 0 0 0 0 0 6193 0 GTP_13C5 0 0 0 0 0 8702 0 24816 195646 67951 162398 157919 254384 490737 1239674 239200 705130 924802 96922 147383 523613 189715 419321 337205 1418237 424843 3815993 1822467 2743108 3087774 0 0 0 0 0 0 574496 391045 637909 36546 478780 964065 749041 1021226 228738 319357 845804 505729 656091 258321 1773067 2598576 1475787 2683399 600511 GTP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 22983 0 104205 66897 58674 149798 0 8273 0 0 0 0 0 12385 0 13674 0 0 0 0 0 0 17502 0 13828 0 85356 0 30997 40579 8250 GTP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8922 21961 0 0 10151 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 NaN 0 0 NaN 0 0 0 0 0 0 0 0 NaN 0 0 0 NaN NaN 16377 17893 NaN 16589 21734 19842 9738 0 0 0 0 NaN 18107 GTP_13C9 0 0 0 0 8969 0 0 0 7545 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10319 0 0 23694 72404 26653 9852 NaN 15044 0 18128 8259 7909 0 0 33836 0 guanosine 284142 425782 389500 434691 503006 40793 105101 344129 359318 363401 856733 625450 310786 659895 245393 428487 790479 726142 359968 441196 303071 381211 681995 672278 497001 365585 694864 755150 757038 764382 132253 240913 273207 255753 214570 158498 15518575 16255584 29216084 11088114 2801074 8229723 4488497 9874507 4617069 3738081 10449155 5374788 10717069 4208575 4283504 2873717 3285612 10052387 2768799 guanosine_13C10 0 0 0 8360 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 guanosine_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 guanosine_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 guanosine_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 guanosine_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 guanosine_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP 24834 45657 0 31912 54086 0 0 0 0 0 10639 0 34779 0 0 0 37916 0 0 0 0 0 0 0 0 0 0 0 9558 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 12579 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7908 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10366 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IDP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IMP 0 0 0 0 0 0 0 0 13671 0 0 0 0 0 0 0 0 58150 0 0 0 0 0 59235 0 0 15793 0 0 0 0 0 0 0 0 0 0 43982 0 0 0 0 16923 0 0 0 0 0 0 0 0 0 0 0 0 IMP_13C10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IMP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IMP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IMP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 29039 30032 25550 55176 0 0 21757 0 0 25110 0 0 48832 0 0 0 IMP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 IMP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 itaconic acid 85511668 52556893 44563458 58509773 92708330 51153010 90660208 53315650 35400325 61537118 80850965 43313601 98281978 49760768 55800613 74980200 85709102 41083170 343003272 75931079 73127196 234384905 632427264 195829037 437345278 292654975 84364089 299931919 549488040 76283778 7109433 36134494 32684150 51282736 24996611 10968027 40240973 108579702 63388505 35078286 17536060 33092464 102414093 48230191 26167866 11200629 23267635 32450934 38290802 16946688 4969351 24074143 35828922 36091114 16265703 itaconic acid_13C1 4077179 2840393 1905966 2830376 4240572 2060082 5199162 3307861 2416452 6514322 8075965 2600217 6581899 3403743 3590619 7579286 8863662 2848058 29231614 6118756 5283736 41306593 115341498 19086285 46984442 31280632 8258429 55354169 103337289 6691077 70723 1843294 1684955 2604831 994796 602703 2622064 7257066 5443215 2076691 1157656 2480193 7347317 4426820 2006511 966063 2182571 2945707 4618251 1209735 396356 2345880 3421286 4806288 1371405 itaconic acid_13C2 0 0 0 0 0 0 0 0 0 1039107 1479323 0 493410 0 0 1353486 1531116 0 3694862 0 0 11945028 35140261 1150331 8761449 5465701 377810 15842769 30551708 1033890 0 0 0 0 0 0 0 0 424821 0 0 0 698357 0 0 0 0 360516 798605 0 0 0 469331 743150 0 lactate 7445075382 6316711995 6353775917 5932158178 6229072155 2641956834 4864947976 3100417007 3754061323 3069983887 3837000083 4813265294 6028192424 5099729528 5596354201 5370938001 6168341539 3751599941 2052084643 2223224943 1451443407 1795043682 852779103 2751728705 1901200978 2446365092 2359853615 3064114655 2697441118 2534312001 5926059372 6249884760 5753346199 5495091686 4919393976 6310555108 5835228455 2717017465 6178675085 3486284489 2281187981 6376326332 2401033696 5046210987 5170815738 2411975999 2730275679 2756608378 2394883732 2650927556 2388192977 13415636677 2460311925 5965454170 2995308253 lactate_13C1 270744488 229529625 231711787 217745049 227242474 94040176 180646477 113359846 118419910 115399674 182831342 177090119 227661449 186299386 203662814 199181345 224848995 140196328 77175591 81782143 53620302 65246321 32345100 99849450 73342154 93300955 90531538 110124194 102483354 97326140 217628748 229556599 206673190 200957782 183386834 221533174 213880160 128352613 221925420 130969556 91886050 229594789 97932363 181510137 185008416 81122901 100833939 99275890 90005950 102601982 90842327 475515196 95153177 213659389 102214067 lactate_13C2 5195435 4512272 3869598 4099617 4374403 2482579 4551545 2664345 10642861 5671530 9256070 8972538 8518587 7564556 20691366 14257950 23994721 16274418 5703945 4753786 5879619 8461582 8708966 11149390 14064715 6459906 32215324 19046412 28503992 30825039 7258418 6387452 5537404 5894294 5287144 19387726 11048929 11583385 16307696 8366993 9162880 23402036 27638019 15598531 13911417 3388935 16560977 19250414 10564545 10667152 10085616 26595535 25690298 28936853 5355612 lactate_13C3 30539719 28697360 29617252 28391556 29639579 12045680 55365345 27017581 217395937 94325740 161519509 164171206 179325890 131482969 447772007 333563212 570894335 432364639 186891187 168541102 185646372 215522986 191593234 249989025 284882216 153722567 792860264 466346653 709574260 745961864 111175405 88551974 74120712 85996432 72223988 569551344 336633718 256483313 355217395 153943249 186149004 543663488 493193136 550044321 328019194 116274841 235599595 322337432 232583642 225327385 194440599 609505862 590478631 695852743 204371504 leucine / leucine(iso) 430855064 536966846 141512269 510921533 473878414 105875095 300685419 211999005 361067179 156124401 672189796 285579098 504153422 522977298 411396064 465356879 1157148632 487107273 600121773 694927202 414636747 313230041 435565287 977577658 821932448 1858985761 1157983449 1153497356 1100710049 794865082 186942015 413715894 288922849 392567744 266385912 5363495370 1655962116 1833622480 2768540408 1764336038 1417884310 1883873526 1826699960 1884017989 1629426049 853525040 1493657233 1184917690 1615936244 1165878752 960262637 3454240009 901848425 1923754159 708528077 leucine / leucine(iso)_13C1 21657887 33389908 30128313 34870115 32691262 6483032 19436880 24047732 21054863 12102699 43709136 30950551 32588325 34072200 27323878 29499843 81191655 37419350 41596929 46792720 18459090 21224884 29631900 66111658 55968466 125869690 78259010 78301130 74182970 53975570 22657086 16100445 27185138 25708250 17508422 362907823 110498859 123089990 170479131 120941767 93437565 125267090 122195203 128702124 107621419 59228940 100111037 81249680 109195838 76536933 64281077 229017972 63101960 126631814 48402939 leucine / leucine(iso)_13C2 584921 655554 496736 501811 600673 380561 419805 429952 711422 695137 882436 479145 659620 593032 495651 547315 1393775 652852 1069204 1109124 592735 794936 743212 1498948 1279963 2362068 1742162 1679255 1472073 1270973 493320 483998 558458 386284 446968 7540736 2045182 2609068 3807005 2569252 2048101 2619585 2608233 2922086 2245430 1297511 2259006 1819491 2466572 1537566 1557624 4781844 1291812 2494417 1114607 leucine / leucine(iso)_13C3 0 7825 7300 0 7785 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 leucine / leucine(iso)_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 malate 19907237 16361587 24729273 13543284 19396511 27066208 13921871 9141469 16000845 9845049 11273208 19835798 19023465 14669817 36483504 17594180 22129339 32096611 26718081 21634839 22383178 15674379 19759031 24788066 28106229 32968204 38068283 24274158 34350881 42696129 5021562 15479527 20397457 14337576 8354155 5401425 22785920 24891131 17292390 9990979 7291762 33095074 38377211 29564158 22731426 7925918 30827330 45439229 29545708 23825162 12554519 42052564 62001586 55490338 24214669 malate_13C1 815793 250655 756440 333139 452021 732492 406791 323371 449967 379361 703374 582548 574320 386217 1109857 1079448 1156647 970555 884767 588938 593325 716434 939574 528709 1033723 1286172 1226982 1396360 1910424 1647970 0 322339 544005 208972 0 104132 659037 767262 791227 200653 129732 998697 1376832 1398249 887426 145811 1018493 1471415 1033673 647297 607314 1629270 2041889 2334768 776024 malate_13C2 0 0 0 0 0 0 0 0 0 600356 534901 0 517690 149293 230849 1645697 1168185 185374 496316 0 0 338679 590434 48681 287399 468586 81057 809038 1223642 89258 0 0 0 0 0 0 0 0 351068 0 68932 297071 375068 645618 242907 0 0 0 61871 0 87272 325925 833046 955419 0 malate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 487752 145628 99926 90318 0 0 0 0 0 82926 0 55635 516419 127368 441056 650478 0 0 0 0 0 0 0 0 0 0 0 77288 320067 243164 0 0 0 67217 0 0 0 153112 612803 509599 0 malate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 mevalonate_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-acetyl-glucosamine-1/6-phosphate 0 0 71837 0 0 55404 38584 37216 89207 70094 13183 0 0 7104 44453 0 0 40922 0 19234 0 20996 79397 44257 11664 103483 16981 9171 8400 0 0 11255 12032 11555 0 0 65210 28867 220940 46290 65167 112061 100002 49035 0 84185 47973 128136 136495 47058 11551 58047 13592 32512 102186 N-acetyl-glucosamine-1/6-phosphate_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 12537 12070 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-acetyl-glucosamine-1/6-phosphate_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8883 0 0 0 0 0 0 0 0 8413 0 0 0 0 0 0 0 NAD+ 0 0 0 0 0 0 0 86011 0 0 0 0 0 0 0 0 0 0 0 0 0 0 98032 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 102722 0 77789 0 0 0 0 89983 0 0 NADH 0 0 0 0 0 0 0 0 0 0 0 63610 0 0 0 0 0 0 0 0 0 0 0 48257 0 43670 0 0 0 57634 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 61871 0 0 0 0 49377 0 0 0 NADP+ 5473558 5224494 5205224 5228660 4883373 4166623 2637836 2395845 4103659 2043654 5334193 5122246 3358494 5717637 7553385 3080782 6522572 6231056 2110756 4025075 3687526 1792601 4538692 3615042 4507785 2478588 3715113 2839335 6172824 4515652 5061060 5943985 4469027 4753585 4585418 2699335 2056582 2003134 2487015 1693080 5470826 7306192 6340536 6828708 6024033 2991365 5585325 4413000 4951839 4822506 3333900 4429111 1933471 4899055 3956383 NADPH 2430628 1823252 0 326298 1856951 1467269 304487 551874 52425 195329 0 534232 1817547 2860602 1255754 623370 2854876 1823577 1108904 355190 467190 205522 1155345 0 678524 147308 0 1258737 32321 83983 0 453151 1085249 1414433 246803 1560728 28790 0 0 0 547953 18105 29131 23306 484951 805082 29205 17623 0 65011 520107 0 0 23115 0 N-carbamoyl-L-aspartate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-carbamoyl-L-aspartate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-carbamoyl-L-aspartate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 112824 0 0 N-carbamoyl-L-aspartate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-carbamoyl-L-aspartate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-carbamoyl-L-aspartate_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oxaloacetate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oxaloacetate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oxaloacetate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oxaloacetate_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oxaloacetate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 phosphoenolpyruvate 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 19684 0 0 0 0 14924 348083 0 0 21357 0 0 0 0 0 0 0 0 0 0 0 0 27477 0 23177 17201 0 0 0 0 0 0 102257 0 15075 0 phosphoenolpyruvate_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 phosphoenolpyruvate_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9733 0 0 9308 0 0 0 9194 0 0 0 12247 0 0 8925 9204 0 0 0 9633 0 0 0 7575 11418 0 0 11507 0 phosphoenolpyruvate_13C3 0 0 0 0 0 0 0 0 0 0 19196 0 0 0 0 0 0 0 0 16302 0 0 0 60492 13112 17997 159391 0 141654 115832 0 0 0 0 0 0 0 0 0 0 52217 91830 145783 169774 11211 28034 26911 29362 51460 0 29356 216424 25703 111886 33021 PRPP 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5776 0 0 0 0 0 0 5508 0 0 0 0 0 0 0 0 4216 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PRPP_13C1 0 0 0 0 0 0 0 0 0 0 0 5288 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5364 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PRPP_13C2 0 6676 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5038 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PRPP_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PRPP_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5031 0 0 0 0 0 0 0 4823 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5482 0 0 0 PRPP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5534 0 0 0 7866 0 0 0 0 4837 0 4881 0 pyruvate 65512311 247966659 37119543 37969711 26982150 19033522 10509302 29877454 24418594 19053238 21588204 20641303 14578861 24353301 15992246 23500927 15451495 22442262 20916177 20365689 22886247 17820885 20307542 85062698 22423328 145104569 33777671 87880822 56181503 22693317 19643531 43964115 55761187 19488887 23577755 554451500 53308940 43090348 47364454 58541209 34138556 33698920 24498701 78288390 46903659 17335566 15843703 26974304 14700209 13325480 13200977 792317753 12896282 110663476 23855902 pyruvate_13C1 1461456 6955168 1008399 1053556 793529 461003 290258 801571 776512 592878 634040 625701 193816 690612 392270 741416 521685 618098 583675 529266 980352 567630 740134 2345681 646667 3860449 972646 2419167 1600878 743247 716438 1240264 1457848 726434 608567 16766762 1600924 1214473 1588210 1551034 1108179 1023068 751736 2383508 1434910 586319 749565 880690 458479 372381 553713 25208331 374013 3183297 714882 pyruvate_13C2 0 0 0 0 0 0 0 322644 0 130765 0 0 57494 0 0 124403 0 0 196990 0 0 0 0 0 0 96411 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 730418 0 0 0 0 0 0 0 pyruvate_13C3 0 0 0 0 0 0 0 0 1460821 592200 636877 582033 428695 613182 698555 854290 530030 990811 626263 1004289 653561 1229177 902105 1390344 2785793 1374009 8176420 3414918 4236534 3769649 0 0 0 0 0 1472681 2626041 3576715 5427512 1577508 6495816 7399211 8775176 9921142 3148071 3211359 4362796 3988625 4656779 2715602 4414705 5477776 6997994 9025160 3132596 S-adenosyl-L-homoCysteine 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 S-adenosyl-L-homoCysteine_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 S-adenosyl-L-methionine 17890523 12966001 16325900 15912419 22318161 20790870 7306027 5056866 11792760 7308894 14595915 15075284 8954776 11146346 23105427 8435301 23899766 17760799 11612339 11981294 14780187 7562771 24822168 16280464 19819813 6647848 17078011 18745555 23788859 17246111 9638548 15171563 14211197 17975926 11344383 6891475 15994794 12892943 15316876 10250781 11558772 16641096 14275814 17415057 12004115 11955083 19240450 14952960 18618486 14835974 14639669 15572321 6677547 19982946 12339757 S-adenosyl-L-methionine_13C1 2819679 2011097 2412172 2334047 3294830 3143112 1143999 824872 1759418 1140773 2265855 2277954 1363555 1656658 3459878 1241507 3647607 2745525 1826726 1878659 2137092 1110820 3641031 2467052 2915405 996967 2675246 2872959 3699184 2485809 1484536 2313608 2192825 2852925 1733368 1030147 2503962 1971094 2322875 1614107 1642593 2513429 2221981 2678626 1752015 1798297 2949627 2244210 2789348 2127479 2329041 2388836 1031814 3129542 1804155 S-adenosyl-L-methionine_13C2 123141 30142 104000 127939 141286 158541 7615 30706 81597 27707 67650 85394 11036 83103 203267 16332 226705 114814 62072 92388 112475 17664 256938 134379 240944 8846 160372 154332 168173 141663 36511 76985 64668 122178 25792 12286 90579 55790 136197 59790 49723 83529 114072 135227 63754 88157 195367 111452 173893 66128 142679 217054 48129 185388 62992 S-adenosyl-L-methionine_13C3 0 7879 0 0 0 0 0 0 0 0 0 0 0 0 10280 0 0 7596 7816 0 0 6639 0 6738 35566 0 64911 22166 24780 32226 0 0 0 0 0 0 0 7746 0 0 8516 8958 0 7168 0 6921 12302 11853 8648 0 9252 55488 16226 32759 10294 S-adenosyl-L-methionine_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 18840 0 16438 0 17774 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8014 0 0 7398 0 21621 8234 0 17002 0 S-adenosyl-L-methionine_13C5 0 0 0 0 0 0 0 0 9391 0 0 0 0 19618 74784 0 33594 26597 11634 7921 104885 31691 120653 46666 228518 25560 430713 301641 339049 387237 0 0 0 0 0 0 19027 10241 11595 0 91370 64186 27713 94488 21846 88198 279354 107694 192404 0 509856 523702 245134 580895 105990 S-adenosyl-L-methionine_13C6 0 9484 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7114 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 32656 6455 7482 0 S-adenosyl-L-methionine_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 S-adenosyl-L-methionine_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8533 0 0 0 0 4636 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 S-adenosyl-L-methionine_13C9 61273 36228 66351 111870 77095 62066 24427 39056 42550 27219 69847 83659 24434 36739 85133 37652 86748 94328 31478 92289 73842 22275 20706 67582 93743 53898 26752 110493 21614 59752 86221 116310 127229 116035 101186 76386 93575 125823 22144 79432 76092 36982 46753 27946 50470 52696 34039 32347 2569 23596 29691 51657 10974 30676 60751 serine 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 149319 0 581649 1052151 73226 0 81362 1086941 125167 0 0 0 0 0 0 1353422 431180 151071 158850 0 87275 560270 735519 1096996 186483 0 399795 77166 303518 0 191412 1370906 70254 866162 69197 serine_13C1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 serine_13C2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 serine_13C3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 sorbitol / galactitol / L-iditol / manitol 25797264 26487783 28732464 26044994 27302100 10249910 15929364 9860069 17578763 9579511 16965247 20266547 38289584 17043022 52328950 41668382 106383821 17106788 12778251 13954104 7971403 9295243 13325513 12203275 11768523 21197288 15688590 12507379 7673346 13313494 35643460 45192445 23362993 35348478 12238212 124542593 59930607 6794527 29662818 12179282 23036449 80228569 20344567 39540814 118990567 7716642 22771905 12472505 15042774 22668123 10555890 135073488 12708768 56182953 17468689 sorbitol / galactitol / L-iditol / manitol_13C6 0 0 0 0 0 0 0 0 114414 0 41286 59725 0 0 506405 159222 30353 255003 0 18528 18746 0 0 21067 26409 30938 545522 71937 69061 521227 0 0 0 0 0 0 388182 0 0 0 0 689452 68599 266581 45930 18312 29579 145210 0 25999 0 2001178 673683 1127566 105543 succinate 5910751 5281259 15435727 7016072 15488012 10048701 7565027 6686974 10446671 7833344 10103355 9433833 17102046 5382349 26914113 11978891 18100359 16972061 29260514 1294053 7807948 13358946 22689421 23950781 7267611 12217530 24023012 3020500 17028909 15661371 2315807 7153672 11334253 6820073 3616074 9325534 6972250 14117217 6916898 5001484 3542556 9858134 20734466 13224809 5588193 2908444 8668710 14461384 6524595 5585955 1490001 15091035 21319838 11128904 3007098 succinate_13C1 766944 566341 892291 668437 938299 798433 371856 640797 840929 470438 1173408 577954 551707 524905 1304840 1829484 2237462 963239 582310 923327 967791 1293242 2456235 1136173 1079134 326658 1068459 1143869 1358639 1049068 185344 783306 454389 907220 114480 535751 1124724 1182793 962874 550073 342025 792960 1381985 1015520 527885 441781 886196 789478 610300 270126 145475 1006122 853193 577219 325847 succinate_13C2 0 0 0 0 0 0 0 0 0 1016796 1059391 0 394844 0 0 1221372 1586124 0 324711 89409 0 459069 1158291 0 54415 36158 58214 362261 1019497 0 0 0 0 0 0 0 158041 124032 588886 0 0 212705 222532 296135 51049 0 59583 53558 70575 54958 0 212194 364398 264788 52289 succinate_13C3 0 0 0 0 0 0 0 0 0 92572 195963 0 40877 0 65499 349314 217149 0 0 0 0 53485 168174 0 0 0 0 105791 201658 119374 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 62152 101316 0 0 succinate_13C4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 130569 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 51462 0 51405 0 0 35031 0 0 48903 0 0 0 0 42264 thiamine diphosphate+ 7638270 5999659 6555920 7061622 9734314 7547522 2662286 2137661 4406542 3041585 6432849 6435959 3378927 4691243 7885161 2992329 8996976 6592445 2746248 3597621 4840405 2493147 7300963 4600615 5265290 1964958 5858663 6622717 8616316 5874488 4046711 5951960 5934380 7409820 4212155 3100475 5378753 5290152 6822707 3397686 4177635 6172037 6066579 6923125 4135276 3279332 6212090 5852970 6328917 4276909 4017788 5384797 1984761 6377624 3844856 thiamine phosphate+ 156966 88717 200897 214067 448814 121980 7774 7295 31116 13528 140012 93340 0 45014 150805 16119 219866 148312 21691 39507 78173 5736 110932 113893 58854 8641 204697 120183 295007 162554 62432 118939 143880 175080 27553 0 3027211 2250031 1927064 1096520 504770 1496303 1608930 1427677 507896 480864 1405912 1338278 1920712 473820 405937 671208 1006464 2457724 419522 thiamine+ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 486380 0 0 0 UDP-N-acetyl-galactosamine/glucosamine 109677 50822 0 62081 109138 127435 639856 423742 0 280030 44009 0 586112 279113 49386 276850 153223 64834 618437 470173 0 398741 179985 165070 240406 753248 62278 94003 52370 111322 74352 78195 53270 1296 189263 180458 115406 255294 206572 75608 95665 254026 253950 140887 196175 191129 117533 523452 340044 309207 131802 294225 576711 314255 257380 UDP-N-acetyl-galactosamine/glucosamine_13C13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 UDP-N-acetyl-galactosamine/glucosamine_13C6 0 0 0 0 0 0 0 0 0 0 0 0 9972 0 0 9223 0 0 0 0 0 0 0 0 0 0 4215 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2542 0 0 1348 0 4882 0 UDP-N-acetyl-galactosamine/glucosamine_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9673 0 0 0 0 0 UMP 0 0 0 0 0 0 0 0 0 39779 0 0 52555 0 0 45843 0 0 0 36006 48914 38348 0 0 0 0 0 0 0 0 0 0 0 0 0 53747 1063870 1204395 1430153 659268 0 430568 368335 554412 109864 49168 55469 338614 185678 0 122272 0 1662249 780741 0 UMP_13C5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 UMP_13C6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 UMP_13C7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 UMP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 41820 0 0 UMP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 15551 0 0 12316 0 0 0 0 0 0 0 10880 UTP 38387633 38939282 15733993 17315050 23747504 19030748 18045376 19046991 15846295 9530182 20835348 23743731 29400515 59445906 38703404 14434932 39703175 30938631 11895188 21862925 16954080 6602919 23805378 14934384 37137427 13959334 28296476 24523183 30747443 23563574 45307856 32122285 26661838 32781195 36500415 37915469 39142734 29349286 41069316 42665336 51441948 37285856 30611649 31587282 37591120 21930169 19473014 19580899 19312815 22843915 41957997 29132426 11917291 32161148 24088352 UTP_13C5 0 0 0 0 0 0 0 0 0 0 0 6467 0 0 65057 9181 106242 61937 0 0 54905 0 116131 59380 35406 0 349592 239860 418423 315885 0 0 0 0 0 0 22014 29050 15064 0 0 55798 67198 58719 0 14162 106864 109029 113184 6252 133004 286781 121737 450420 33407 UTP_13C6 8180 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6369 0 0 0 0 11591 13967 0 0 0 8551 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6598 0 UTP_13C7 0 0 0 0 0 5560 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 8369 0 UTP_13C8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5833 0 0 0 0 0 UTP_13C9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4261 0 0 0 0 0 0 0 0 4844 0 0 0 0 xylitol / arabitol / ribito 86261758 53267044 37004411 37771212 34766248 2491554 11727536 16133347 21037245 21647289 20520377 15400304 9544869 19990753 16172188 11306711 19448949 20697602 12152159 21933489 8831514 16962378 16519508 14072115 19124595 17783501 16786310 14481123 22175229 16180498 11351176 11614847 14754956 11746391 11534112 28856751 8085244 15664874 11781639 9257339 4224621 6043990 7902834 5241559 3475629 2304717 4540003 7801969 5940190 5998480 3868679 5127323 7377079 5670801 3259489 xylitol / arabitol / ribito_13C5 0 0 0 0 0 0 0 0 36346 0 0 0 0 0 0 25851 0 171492 17932 0 186435 90679 176470 263590 98461 53490 638262 318270 463365 591688 0 0 0 0 0 0 51885 157759 0 0 0 25395 314030 46375 0 11336 200756 210608 222555 14359 13060 55861 687380 340782 15116 MS_METABOLITE_DATA_END #METABOLITES METABOLITES_START metabolite_name KEGG ID 1,3-diphosphoglycerate C00236 1,3-diphosphoglycerate_13C1 1,3-diphosphoglycerate_13C2 1,3-diphosphoglycerate_13C3 2,3-diphosphoglycerate C01159 2,3-diphosphoglycerate_13C1 2,3-diphosphoglycerate_13C2 2,3-diphosphoglycerate_13C3 2/3-phosphoglycerate C00631 / C00197 2/3-phosphoglycerate_13C1 2/3-phosphoglycerate_13C2 2/3-phosphoglycerate_13C3 2-HG C02630 2-HG_13C1 2-HG_13C2 2-HG_13C3 2-HG_13C4 2-HG_13C5 3-phospho-serine C01005 3-phospho-serine_13C1 3-phospho-serine_13C2 3-phospho-serine_13C3 6-phospho-D-gluconate C00345 6-phospho-D-gluconate_13C1 6-phospho-D-gluconate_13C2 6-phospho-D-gluconate_13C3 6-phospho-D-gluconate_13C4 6-phospho-D-gluconate_13C5 6-phospho-D-gluconate_13C6 acetoacetate / succinic semialdehyde C00164 / C00232 acetoacetate / succinic semialdehyde_13C1 acetoacetate / succinic semialdehyde_13C2 acetoacetate / succinic semialdehyde_13C3 acetoacetate / succinic semialdehyde_13C4 acetyl-CoA + C00024 acetyl-CoA_13C1 + acetyl-CoA_13C2 + aconitic acid - C6H6O6 aconitic acid_13C1 - aconitic acid_13C2 - adenosine C00212 adenosine_13C10 adenosine_13C5 adenosine_13C6 adenosine_13C7 adenosine_13C8 adenosine_13C9 ADP / dGDP C00008 / C00361 ADP / dGDP_13C1 ADP / dGDP_13C10 ADP / dGDP_13C2 ADP / dGDP_13C3 ADP / dGDP_13C4 ADP / dGDP_13C5 ADP / dGDP_13C6 ADP / dGDP_13C7 ADP / dGDP_13C8 ADP / dGDP_13C9 AICAR C04677 AICAR_13C5 AICAR_13C6 AICAR_13C7 AICAR_13C8 AICAR_13C9 a-KG C00026 a-KG_13C1 a-KG_13C2 a-KG_13C3 a-KG_13C4 a-KG_13C5 alanine C00041-C00133 alanine_13C1 alanine_13C2 alanine_13C3 AMP / dGMP C00020 / C00362 AMP / dGMP_13C1 AMP / dGMP_13C10 AMP / dGMP_13C2 AMP / dGMP_13C5 AMP / dGMP_13C6 AMP / dGMP_13C7 AMP / dGMP_13C8 AMP / dGMP_13C9 aspartate C16433-C00049 aspartate_13C1 aspartate_13C2 aspartate_13C3 aspartate_13C4 ATP / dGTP C00002 / C00286 ATP / dGTP_13C10 ATP / dGTP_13C5 ATP / dGTP_13C6 ATP / dGTP_13C7 ATP / dGTP_13C8 ATP / dGTP_13C9 choline+ C00114 choline_13C1+ choline_13C2+ choline_13C3+ choline_13C4+ choline_13C5+ citrate(iso)/citrate C00311 / C00063 citrate(iso)/citrate_13C1 citrate(iso)/citrate_13C2 citrate(iso)/citrate_13C3 citrate(iso)/citrate_13C4 citrate(iso)/citrate_13C5 citrate(iso)/citrate_13C6 CMP C00055 CMP_13C5 CMP_13C6 CMP_13C7 CMP_13C8 CMP_13C9 Crotonyl-CoA C00877 CTP C00063 CTP_13C5 CTP_13C6 CTP_13C7 CTP_13C8 CTP_13C9 cystathionine C00542 cystathionine_13C1 cysteine C00736-C00097 cysteine_13C1 cysteine_13C2 cysteine_13C3 dATP C00131 dATP_13C10 dATP_13C5 dATP_13C6 dATP_13C7 dATP_13C8 dATP_13C9 dCTP C00458 dCTP_13C5 dCTP_13C6 dCTP_13C7 dCTP_13C8 dCTP_13C9 deoxyguanosine C00330 deoxyguanosine_13C10 deoxyguanosine_13C5 deoxyguanosine_13C6 deoxyguanosine_13C7 deoxyguanosine_13C8 deoxyguanosine_13C9 D-galactosamine/glucosamine-1/6-phosphate C03783 / C00352 / C06156 / C00352 D-galactosamine/glucosamine-1/6-phosphate_13C6 D-ribose-1/5-phosphate C00620 / C00117 D-ribose-1/5-phosphate_13C1 D-ribose-1/5-phosphate_13C2 D-ribose-1/5-phosphate_13C3 D-ribose-1/5-phosphate_13C4 D-ribose-1/5-phosphate_13C5 D-sedoheptulose-7-phosphate C05382 D-sedoheptulose-7-phosphate_13C1 D-sedoheptulose-7-phosphate_13C2 D-sedoheptulose-7-phosphate_13C3 D-sedoheptulose-7-phosphate_13C4 D-sedoheptulose-7-phosphate_13C5 D-sedoheptulose-7-phosphate_13C6 D-sedoheptulose-7-phosphate_13C7 dTTP C00459 dTTP_13C10 dTTP_13C5 dTTP_13C6 dTTP_13C7 dTTP_13C8 dTTP_13C9 dUTP C00460 dUTP_13C5 dUTP_13C6 dUTP_13C7 dUTP_13C8 dUTP_13C9 F-1,6/2,6-P C00354 / C00665 F-1,6/2,6-P_13C1 F-1,6/2,6-P_13C2 F-1,6/2,6-P_13C3 F-1,6/2,6-P_13C4 F-1,6/2,6-P_13C5 F-1,6/2,6-P_13C6 F6P/G1P/G6P C00085 / C00103 / C00092 F6P/G1P/G6P_13C1 F6P/G1P/G6P_13C2 F6P/G1P/G6P_13C3 F6P/G1P/G6P_13C4 F6P/G1P/G6P_13C5 F6P/G1P/G6P_13C6 fructose / mannose C00095 / C00159 fumarate C00122 fumarate_13C1 fumarate_13C2 fumarate_13C3 fumarate_13C4 galactose / glucose C00124 / C00267 glucose_13C6 GAP / DHAP C00118 / C00111 GAP / DHAP_13C1 GAP / DHAP_13C2 GAP / DHAP_13C3 glutamate C00302-C00025 glutamate_13C1 glutamate_13C2 glutamate_13C3 glutamate_13C4 glutamate_13C5 glutamine C00303-C00064 glutamine_13C1 glutamine_13C2 glutamine_13C3 glutamine_13C4 glutamine_13C5 glutathione C00051 glutathione_13C1 glutathione_13C2 glutathione_13C3 glutathione_13C4 glutathione_13C5 glutathione disulfide C00127 glutathione disulfide_13C1 glutathione disulfide_13C2 glutathione disulfide_13C3 glutathione disulfide_13C4 glutathione disulfide_13C5 glycerate C00258 glycerate_13C1 glycerate_13C2 glycerate_13C3 glycerol-2/3-phosphate C02979 / C00093 glycerol-2/3-phosphate_13C2 glycerol-2/3-phosphate_13C3 glycine C00037 glycine_13C1 glycine_13C2 GMP C00144 GMP_13C10 GMP_13C5 GMP_13C6 GMP_13C7 GMP_13C8 GMP_13C9 GTP C00044 GTP_13C10 GTP_13C5 GTP_13C6 GTP_13C7 GTP_13C8 GTP_13C9 guanosine C00387 guanosine_13C10 guanosine_13C5 guanosine_13C6 guanosine_13C7 guanosine_13C8 guanosine_13C9 IDP C00104 IDP_13C10 IDP_13C5 IDP_13C6 IDP_13C7 IDP_13C8 IDP_13C9 IMP C00130 IMP_13C10 IMP_13C5 IMP_13C6 IMP_13C7 IMP_13C8 IMP_13C9 itaconic acid C00490 itaconic acid_13C1 itaconic acid_13C2 lactate C01432-C00186 lactate_13C1 lactate_13C2 lactate_13C3 leucine / leucine(iso) C16439-C00123 / C16434-C00407 leucine / leucine(iso)_13C1 leucine / leucine(iso)_13C2 leucine / leucine(iso)_13C3 leucine / leucine(iso)_13C6 malate C00711-C00149 malate_13C1 malate_13C2 malate_13C3 malate_13C4 mevalonate C00418 mevalonate_13C1 mevalonate_13C2 mevalonate_13C3 mevalonate_13C4 mevalonate_13C5 mevalonate_13C6 N-acetyl-glucosamine-1/6-phosphate C04256 / C00357 N-acetyl-glucosamine-1/6-phosphate_13C6 N-acetyl-glucosamine-1/6-phosphate_13C8 NAD+ C00003 NADH C00004 NADP+ C00006 NADPH C00005 N-carbamoyl-L-aspartate C00438 N-carbamoyl-L-aspartate_13C1 N-carbamoyl-L-aspartate_13C2 N-carbamoyl-L-aspartate_13C3 N-carbamoyl-L-aspartate_13C4 N-carbamoyl-L-aspartate_13C5 oxaloacetate C00036 oxaloacetate_13C1 oxaloacetate_13C2 oxaloacetate_13C3 oxaloacetate_13C4 phosphoenolpyruvate C00074 phosphoenolpyruvate_13C1 phosphoenolpyruvate_13C2 phosphoenolpyruvate_13C3 PRPP C00119 PRPP_13C1 PRPP_13C2 PRPP_13C3 PRPP_13C4 PRPP_13C5 pyruvate C00022 pyruvate_13C1 pyruvate_13C2 pyruvate_13C3 S-adenosyl-L-homoCysteine C00021 S-adenosyl-L-homoCysteine_13C1 S-adenosyl-L-methionine C00019 S-adenosyl-L-methionine_13C1 S-adenosyl-L-methionine_13C2 S-adenosyl-L-methionine_13C3 S-adenosyl-L-methionine_13C4 S-adenosyl-L-methionine_13C5 S-adenosyl-L-methionine_13C6 S-adenosyl-L-methionine_13C7 S-adenosyl-L-methionine_13C8 S-adenosyl-L-methionine_13C9 serine C00716-C00065 serine_13C1 serine_13C2 serine_13C3 sorbitol / galactitol / L-iditol / manitol C00794 / C01697 / C01507 / C00392 sorbitol / galactitol / L-iditol / manitol_13C6 succinate C00042 succinate_13C1 succinate_13C2 succinate_13C3 succinate_13C4 thiamine diphosphate+ C00068 thiamine phosphate+ C01081 thiamine+ C00378 UDP-N-acetyl-galactosamine/glucosamine C00203 / C00043 UDP-N-acetyl-galactosamine/glucosamine_13C13 UDP-N-acetyl-galactosamine/glucosamine_13C6 UDP-N-acetyl-galactosamine/glucosamine_13C8 UMP C00105 UMP_13C5 UMP_13C6 UMP_13C7 UMP_13C8 UMP_13C9 UTP C00075 UTP_13C5 UTP_13C6 UTP_13C7 UTP_13C8 UTP_13C9 xylitol / arabitol / ribito C00379/ C01904 / C00532 / C00474 xylitol / arabitol / ribito_13C5 METABOLITES_END #END