RefMet Compound Details

RefMet ID, RefMet name, exact mass and formula
RefMet ID	RM0136090
RefMet name	Glucosamine 6-phosphate
Systematic name	{[(2R,3S,4R,5R,6S)-5-amino-3,4,6-trihydroxyoxan-2-yl]methoxy}phosphonic acid
Synonyms	PubChem Synonyms
Exact mass	259.045707 (neutral)	Calculate m/z: (Choose adduct) [M+H]+ [M+H-H2O]+ [M.]+ [M+2H]2+ [M+3H]3+ [M+4H]4+ [M+K]+ [M+2K]2+ [M+2K-H]+ [M+Na]+ [M+2Na]2+ [M+2Na-H]+ [M+Li]+ [M+2Li]2+ [M+NH4]+ [M.CH3]+ [M+Ag]+ [M+H+CH3OH]+ [M+H+CH3CN]+ [M+H+2CH3CN]+ [M+Na+CH3CN]+ [M.NaFormate+H]+ [M.NH4Formate+H]+ [M.TMSi]+ [M.tBuDMSi]+ [M+H-Hexose]+ [M+H-EtnP]+ [M+H-SerP]+ [M-H]- [M-H-H2O]- [M-CH3]- [M-2H]2- [M-3H]3- [M-4H]4- [M+Cl]- [M+OAc]- [M+Na-2H]- [M+K-2H]- [M.Formate]- [M.NaFormate-H]- [M.NH4Formate-H]- [M.F]- [M-H-Ser]- [M.HF2]- M(neutral)    View other RefMet entries with this exact (neutral) mass:   +/- 0.05 amu   +/- 0.1 amu   +/- 0.2 amu   +/- 0.5 amu
Formula	C6H14NO8P	View other entries in RefMet with this formula
Molecular descriptors
Molfile	37685 (Download molfile/View MW Metabolite Database details)
InChI	InChI=1S/C6H14NO8P/c7-3-5(9)4(8)2(15-6(3)10)1-14-16(11,12)13/h2-6,8-10H,1,7H2,(H2,11,12,13)/t2-,3-,4-,5-,6+/m1/s1
InChIKey	XHMJOUIAFHJHBW-UKFBFLRUSA-N	View other enantiomers/diastereomers of this metabolite in RefMet
SMILES	C([C@@H]1[C@H]([C@@H]([C@H]([C@@H](O)O1)N)O)O)OP(=O)(O)O Run Tanimoto similarity search (with similarity coefficient >=0.6)
Chemical/Biochemical Classification
Super Class	Carbohydrates
Main Class	Monosaccharides
Sub Class	Amino sugars
Distribution of Glucosamine 6-phosphate in NMDR studies
Species	Plot Species distribution
Sample source	Plot Sample source(tissue) distribution
Platform	Platform (MS/NMR) used for detection
Chromatography	Chromatography methods used for detection
Studies	NMDR Studies reporting Glucosamine 6-phosphate
External Links
Pubchem CID	439217
ChEBI ID	15873
KEGG ID	C00352
HMDB ID	HMDB0001254
Chemspider ID	388356
Spectral data for Glucosamine 6-phosphate standards
BMRB ID(NMR)	View NMR spectra
NP-MRD ID(NMR)	View NMR spectra
MassBank(EU)	View MS spectra
Structural annotation level
Annotation level	1   (1:Known structure; 2:Known regiochemistry; 3:Partial structure; 4:Sum-composition)

Table of KEGG reactions in human pathways involving Glucosamine 6-phosphate

Rxn ID	KEGG Reaction	Enzyme
R00765	D-Glucosamine 6-phosphate + H2O <=> D-Fructose 6-phosphate + Ammonia	D-glucosamine-6-phosphate aminohydrolase (ketol isomerizing)
R00768	L-Glutamine + D-Fructose 6-phosphate <=> L-Glutamate + D-Glucosamine 6-phosphate	L-glutamine:D-fructose-6-phosphate isomerase (deaminating)
R01961	ATP + D-Glucosamine <=> ADP + D-Glucosamine 6-phosphate	ATP:D-glucosamine 6-phosphotransferase
R02058	Acetyl-CoA + D-Glucosamine 6-phosphate <=> CoA + N-Acetyl-D-glucosamine 6-phosphate	acetyl-CoA:D-glucosamine-6-phosphate N-acetyltransferase
R02059	N-Acetyl-D-glucosamine 6-phosphate + H2O <=> D-Glucosamine 6-phosphate + Acetate	N-Acetyl-D-glucosamine-6-phosphate amidohydrolase

Table of KEGG human pathways containing Glucosamine 6-phosphate

Pathway ID	Human Pathway	# of reactions
hsa00520	Amino sugar and nucleotide sugar metabolism	5
hsa00250	Alanine, aspartate and glutamate metabolism	1